journal article·2023-12

Revealing the oxidation mechanism of high vanadium high-speed steel using multi-scale characterization

Yujie Wang, Bo Mao, Shuangjie Chu, Lin He, Yuqian Wang, Hui Xing, Genqi Tian, Haiyan Zhao, Shuyang Wang, Jiao Zhang, Baode Sun

Corrosion Science· Volume 225
Publisher page

Abstract

The microstructure evolution of the oxide scales formed in high vanadium high-speed steel after exposure to 500 °C and 700 °C for up to 120 min was investigated using multi-scale characterization. The oxide scale showed a triplex structure consisting of internal oxide layer, inner oxide layer, and outer oxide layer. The internal and outer oxides formed were Cr 2O 3 and Fe 3O 4 , respectively. The progressive increase in oxygen partial pressure resulted in the conversion of Cr 2O 3 to FeCr 2O 4 in the inner oxide layer with nanocavities. The “available space model” and the “internal oxidation model” were identified as controlling oxidation mechanisms.
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Research context

OpenAlex topics: High-Temperature Coating Behaviors · Metal Alloys Wear and Properties · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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