journal article·2022-12

Evolution of oxide film of a new martensitic steel 9Cr3W3Co in supercritical water

C.G. Shang, Z.G. Zhou, F. Wang, Y.H. Lu

Corrosion Science· Volume 209
Publisher page

Abstract

The oxide evolution of 9Cr3W3Co martensitic steel in the supercritical water environment at 650 °C and 30 MPa was studied. The results indicated that a double-layer oxide film, composed of a columnar Fe 3O 4 outer layer and a fine grain FeCr 2O 4/Fe 3O 4 spinel mixed inner one, that thicknesses followed a sub-parabolic law, was formed. The FeCr 2O 4 first grew along various boundaries, then grew into lath along subgrain boundary, dislocation line or by bulk diffusion. After a continuous Cr-rich oxide layer was formed at the inner oxide layer/matrix interface, the inner layer was gradually completely oxidized, which significantly slowed down the oxide rate.
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Research context

OpenAlex topics: High-Temperature Coating Behaviors · Microstructure and Mechanical Properties of Steels · Metal Alloys Wear and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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