Comparative study on the effect of Nb/Mo alloying on the oxidation behavior of Ti42Al5Mn alloy
Source abstract
Abstract
The oxidation behavior of Ti42Al5Mn0.5Nb, Ti42Al5Mn0.8Nb, Ti42Al5Mn0.5Mo, and Ti42Al5Mn0.8Mo alloys (in at%) was investigated at 800 °C. In the Nb-containing alloys, the oxide scale exhibits a multi-layered structure with TiO 2 layer/Al 2 O 3 layer/TiO 2 -rich layer from the outside to the inside, and the intermediate layer at the oxide-substrate interface remained composed of Laves/Z phase until 1000 h of oxidation. The oxide scale of the Mo-containing alloys was incorporated with a thick mixed layer and is highly susceptible to cracking, the intermediate layer changed from Laves/Z phase to Laves/Z/β o phase with prolonged oxidation. While Nb increases the oxidation resistance of the alloy, a higher Mo content led to an increased oxidation mass gain and exfoliation of the oxide scale.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Intermetallics and Advanced Alloy Properties · Titanium Alloys Microstructure and Properties · MXene and MAX Phase Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (44)
Show source-provided references
1. O. Genc, R. Unal, Development of gamma titanium aluminide (γ-TiAl) alloys: a review, 929 (2022) 167262. https://doi.org/10.1016/j.jallcom.2022.167262.10.1016/j.jallcom.2022.167262 ↗
2. Advances in gammalloy materials–processes–application technology: successes
3. H. Clemens, S. MayerDesign, processing, microstructure, properties, and applications of advanced intermetallic TiAl alloys2013, , 191–215, 10.1002/adem.201200231..10.1002/adem.201200231 ↗
4. T. Tetsui, K. Shindo, S. Kobayashi, M. Takeyama, A newly developed hot worked TiAl alloy for blades and structural components, 47 (2002) 399-403. https://doi.org/10.1016/S1359-6462(02)00158-6.10.1016/S1359-6462(02)00158-6 ↗
5. T. Tetsui, K. Shindo, S. Kaji, S. Kobayashi, M. Takeyama, Fabrication of TiAl components by means of hot forging and machining, 13 (2005) 971-978. https://doi.org/10.1016/j.intermet.2004.12.012.10.1016/j.intermet.2004.12.012 ↗
6. H. Xu, X.B. Li, W.W. Xing, L. Shu, Y.C. Ma, K. Liu, Phase transformation behavior of a Mn containing β-solidifying γ-TiAl alloy during continuous cooling, 99 (2018) 51-58. https://doi.org/10.1016/j.intermet.2018.05.004.10.1016/j.intermet.2018.05.004 ↗
7. X.B. Li, H.J. Tang, W.W. Xing, P.X. Zhao, B. Chen, Y.C. Ma, K. Liu, Microstructural stability, phase evolution and mechanical properties of a forged W-modified high-Mn β-γ-TiAl alloy, 136 (2021) 107230. https://doi.org/10.1016/j.intermet.2021.107230.10.1016/j.intermet.2021.107230 ↗
8. T. Izumi, T. Yoshioka, S. Hayashi, T. Narita, Oxidation behavior of sulfidation processed TiAl–2at%X (X=Si, Mn, Ni, Ge, Y, Zr, La, and Ta) alloys at 1173K in air, 13 (2005) 694-703. https://doi.org/10.1016/j.intermet.2004.10.014.10.1016/j.intermet.2004.10.014 ↗
9. K. Zhang, L. Xin, T. Ma, H. Chang, Y. Lu, C. Feng, S. Zhu, F. Wang, Investigation of the role of silicon in TiAlSiN coating deposited on TiAl alloys during long-term oxidation, 204 (2022) 110394. https://doi.org/10.1016/j.corsci.2022.110394.10.1016/j.corsci.2022.110394 ↗
10. A. Rahmel, M. Schütze, W.J. Quadakkers, Fundamentals of TiAl oxidation – a critical review, 46 (1995) 271-285. https://doi.org/10.1002/maco.19950460503.10.1002/maco.19950460503 ↗
11. M. Naveed, A.F. Renteria, S. Weiß, Role of alloying elements during thermocyclic oxidation of β/γ-TiAl alloys at high temperatures, 691 (2017) 489-497. https://doi.org/10.1016/j.jallcom.2016.08.259.10.1016/j.jallcom.2016.08.259 ↗
12. T. Sun, Z. Guo, J. Cao, Y. Liang, J. Lin, Isothermal oxidation behavior of high-Nb-containing TiAl alloys doped with W, B, Y, and C/Si, 213 (2023) 110980. https://doi.org/10.1016/j.corsci.2023.110980.10.1016/j.corsci.2023.110980 ↗
13. C. Leyens, Oxidation of orthorhombic titanium aluminide Tl-22AL-25NB in air between 650 and 1000 °C, 10 (2001) 225-230. https://doi.org/10.1361/105994901770345259.10.1361/105994901770345259 ↗
14. J.M. Xiang, G.B. Mi, S.J. Qu, X. Huang, Z. Chen, A.H. Feng, J. Shen, D.L. Chen, Thermodynamic and microstructural study of Ti2AlNb oxides at 800 °C, 8 (2018) 12761. https://doi.org/10.1038/s41598-018-31196-w.10.1038/s41598-018-31196-w ↗
15. N.S. Neelam, B. S, A. Bhattacharjee, N.R. Gvs, M.A. Zafir, Comparison of the isothermal and cyclic oxidation behavior of Cr and Mo containing γ-TiAlNb alloys, 163 (2020) 108300. https://doi.org/10.1016/j.corsci.2019.108300.10.1016/j.corsci.2019.108300 ↗
16. R. Pflumm, A. Donchev, S. Mayer, H. Clemens, M. Schütze, High-temperature oxidation behavior of multi-phase Mo-containing γ-TiAl-based alloys, 53 (2014) 45-55. https://doi.org/10.1016/j.intermet.2014.04.010.10.1016/j.intermet.2014.04.010 ↗
17. T. Izumi, T. Yoshioka, S. Hayashi, T. Narita, Oxidation behavior of sulfidation processed TiAl–2 at% X (X=V, Fe, Co, Cu, Nb, Mo, Ag and W) alloys at 1173 K in air, 9 (2001) 547-558. https://doi.org/10.1016/S0966-9795(01)00023-1.10.1016/S0966-9795(01)00023-1 ↗
18. H.J. Tang, W.W. Xing, X.B. Li, B. Chen, P.X. Zhao, L. Shu, M.S. Zhang, Y.C. Ma, K. Liu, Insights into the gradient-characteristic precipitation behaviors of laves phase induced by Fe/W/Mo addition in Ti42Al5Mn alloy, 128 (2020) 107022. https://doi.org/10.1016/j.intermet.2020.107022.10.1016/j.intermet.2020.107022 ↗
19. P.X. Zhao, H. Ma, X.B. Li, M. Gao, Y.C. Ma, K. Liu, Insights into the role of W/B alloying on high-temperature oxidation behavior of Ti42Al5Mn alloy, 178 (2024) 188-200. https://doi.org/10.1016/j.jmst.2023.09.011.10.1016/j.jmst.2023.09.011 ↗
20. J.P. Perdew, K. Burke, M. Ernzerhof, Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)], 78 (1997) 1396-1396. https://doi.org/10.1103/PhysRevLett.78.1396.10.1103/PhysRevLett.78.1396 ↗
21. G. Kresse, J. Furthmüller, Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set, 54 (1996) 11169-11186. https://doi.org/10.1103/PhysRevB.54.11169.10.1103/PhysRevB.54.11169 ↗
22. G. Kresse, Ab initio molecular dynamics for liquid metals, 192-193 (1995) 222-229. https://doi.org/10.1016/0022-3093(95)00355-X.10.1016/0022-3093(95)00355-X ↗
23. P.E. Blöchl, Projector augmented-wave method, 50 (1994) 17953-17979. https://doi.org/10.1103/PhysRevB.50.17953.10.1103/PhysRevB.50.17953 ↗
24. Jr · 1998
25. G. Graf, M. Seyffertitz, P. Spoerk-Erdely, H. Clemens, A. Stark, L. Hatzenbichler, D. Holec, M. Burtscher, D. Kiener, X. Li, K. Liu, On the stability of Ti(Mn,Al)2 C14 Laves phase in an intermetallic Ti–42Al–5Mn alloy, 161 (2023) 107962. https://doi.org/10.1016/j.intermet.2023.107962.10.1016/j.intermet.2023.107962 ↗
26. P.X. Zhao, X.B. Li, H.J. Tang, Y.C. Ma, B. Chen, W.W. Xing, K. Liu, J. Yu, Improved High-Temperature Oxidation Properties for Mn-Containing Beta-Gamma TiAl with W Addition, 93 (2020) 433-448. https://doi.org/10.1007/s11085-020-09964-9.10.1007/s11085-020-09964-9 ↗
27. F. Dettenwanger, E. Schumann, M. Ruhle, J. Rakowski, G.H. Meier, Microstructural Study of Oxidized γ-TiAl, 50 (1998) 269-307. https://doi.org/10.1023/A:1018892422121.10.1023/A:1018892422121 ↗
28. Effects of water vapor and nitrogen on oxidation of TNM alloy at 650 degrees C10.1016/j.corsci.2019.07.006 ↗
29. P. Schaaf, W.J. Quadakkers, N. Zheng, E. Wallura, A. Gil, Beneficial and detrimental Effects of Nitrogen on the oxidation behaviour of TiAl-based intermetallics, 48 (1997) 28-34. https://doi.org/10.1002/maco.19970480106.10.1002/maco.19970480106 ↗
30. H.J. Tang, X.B. Li, Y.C. Ma, B. Chen, W.W. Xing, P.X. Zhao, L. Shu, M.S. Zhang, K. Liu, Multistep evolution of βo phase during isothermal annealing of Ti-42Al-5Mn alloy: Formation of Laves phase, 126 (2020) 106932. https://doi.org/10.1016/j.intermet.2020.106932.10.1016/j.intermet.2020.106932 ↗
31. N. Zheng, W. Fischer, H. Grübmeier, V. Shemet, W.J. Quadakkers, The significance of sub-surface depletion layer composition for the oxidation behaviour of γ-titanium aluminides, 33 (1995) 47-53. https://doi.org/10.1016/0956-716X(95)00155-O.10.1016/0956-716X(95)00155-O ↗
32. E.H. Copland, B. Gleeson, D.J. Young, Formation of Z-Ti50Al30O20 in the sub-oxide zones of γ-TiAl-based alloys during oxidation at 1000°C, 47 (1999) 2937-2949. https://doi.org/10.1016/S1359-6454(99)00169-X.10.1016/S1359-6454(99)00169-X ↗
33. J.P. Lin, L.L. Zhao, G.Y. Li, L.Q. Zhang, X.P. Song, F. Ye, G.L. Chen, Effect of Nb on oxidation behavior of high Nb containing TiAl alloys, 19 (2011) 131-136. https://doi.org/10.1016/j.intermet.2010.08.029.10.1016/j.intermet.2010.08.029 ↗
34. C. Liu, Y. Wang, W. Han, T. Ma, D. Ma, Y. Zhang, Achieving Superior High-Temperature Strength and Oxidation Resistance of TiAl Nanocomposite through In Situ Semicoherent MAX Phase Precipitation, 14 (2022) 8394-8403. https://doi.org/10.1021/acsami.1c21719.10.1021/acsami.1c21719 ↗
35. A. Donchev, L. Mengis, A. Couret, S. Mayer, H. Clemens, M. Galetz, Effects of tungsten alloying and fluorination on the oxidation behavior of intermetallic titanium aluminides for aerospace applications, 139 (2021) 107270. https://doi.org/10.1016/j.intermet.2021.107270.10.1016/j.intermet.2021.107270 ↗
36. J.G. Wang, L.M. Hsiung, T.G. Nieh, Microstructural instability in a crept fully lamellar TiAl alloy, 7 (1999) 757-763. https://doi.org/10.1016/S0966-9795(98)00125-3.10.1016/S0966-9795(98)00125-3 ↗
37. T. Klein, L. Usategui, B. Rashkova, M.L. Nó, J. San Juan, H. Clemens, S. Mayer, Mechanical behavior and related microstructural aspects of a nano-lamellar TiAl alloy at elevated temperatures, 128 (2017) 440-450. https://doi.org/10.1016/j.actamat.2017.02.050.10.1016/j.actamat.2017.02.050 ↗
38. FANG Lu, D.I.N.G.Xianfei, ZHANG Laiqi, H.A.O.Guojian, L. Junpin., Microstructure stability in a fully lamellar high nb-tial alloy after long-term thermal cycling, 49 (2013) 1416-1422.10.3724/SP.J.1037.2013.00495 ↗
39. Y. Mishin, C. Herzig, Diffusion in the Ti–Al system, 48 (2000) 589-623. https://doi.org/10.1016/S1359-6454(99)00400-0.10.1016/S1359-6454(99)00400-0 ↗
40. V. Shemet, H. Hoven, W.J. Quadakkers, Oxygen uptake and depletion layer formation during oxidation of γ-TiAl based alloys, 5 (1997) 311-320. https://doi.org/10.1016/S0966-9795(96)00093-3.10.1016/S0966-9795(96)00093-3 ↗
41. Z.W. Huang, T. Cong, Microstructural instability and embrittlement behaviour of an Al-lean, high-Nb γ-TiAl-based alloy subjected to a long-term thermal exposure in air, 18 (2010) 161-172. https://doi.org/10.1016/j.intermet.2009.07.007.10.1016/j.intermet.2009.07.007 ↗
42. S.L. Draper, D. Isheim, Environmental embrittlement of a third generation γ TiAl alloy, 22 (2012) 77-83. https://doi.org/10.1016/j.intermet.2011.10.006.10.1016/j.intermet.2011.10.006 ↗
43. G.R. Smolik, D.A. Petti, K.A. McCarthy, S.T. Schuetz, Oxidation, volatilization, and redistribution of molybdenum from TZM alloy in air, in, United States, 2000.10.2172/752007 ↗
44. Y. Shida, H. Anada, Role of W, Mo, Nb and Si on Oxidation of TiAl in Air at High Temperatures, 35 (1994) 623-631. https://doi.org/10.2320/matertrans1989.35.623.10.2320/matertrans1989.35.623 ↗