journal article·2024-07

Visualizing and quantifying the influence of N-Mo synergy on corrosion resistance of stainless steel by dissolution-diffusion-deposition model

Hao Feng, Jing Dai, Huabing Li, Xuzhi Cao, Hongchun Zhu, Shucai Zhang, Tong He, Zhouhua Jiang, Tao Zhang

Corrosion Science· Volume 235
Publisher page

Abstract

This work employed the “dissolution-diffusion-deposition” model to quantitatively describe the effect of N-Mo synergism on passivation process. The model was optimized by calibrating the ion concentration, calculating the equilibrium between H + and OH − , as well as calculating the formation amount of passive film components. Through modelling studies, we visualized and quantified how N-Mo synergy promoted passivation process. Results demonstrate that N-Mo synergy enhanced corrosion resistance by suppressing acidification of solution, increasing Cr 2O 3 content and improving cation-selectivity of passive film. The mutual promotion between hydrolysis of NH 3 and transpassive dissolution of Mo oxides played a critical role in improving corrosion resistance.
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Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Corrosion Behavior and Inhibition · High-Temperature Coating Behaviors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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