journal article·2024-02

Effect of Al and Si addition on passivation of stainless steels in H2SO4 solution

Akihiro Fujimura, Masatoshi Abe, Akinori Kawano, Mana Iwai, Sho Kitano, Hiroki Habazaki, Koji Fushimi

Corrosion Science· Volume 227
Publisher page

Abstract

The dissolved masses of Fe, Cr, Al, and Si in H 2SO 4 solution during the polarization of Cr-containing steels were quantified by online ICP-OES. The active dissolution current on 11Cr-2Al/-2Si was smaller than that on 11Cr due to the enrichment of Al/Si on the steel. The Cr dissolution from 11Cr2Al was suppressed in passive state, while that from 11Cr2Si was decreased in active-passive transition because accumulated Al or Si products have different physicochemical effects on the Cr-enrichment of the surface. Roles of Al/Si in corrosion process, especially passivation, were discussed based on quantitative analysis of dissolution products detected by ICP-OES.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals · High-Temperature Coating Behaviors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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