journal article·2024-08

Suppressing hydrogen embrittlement of a CrCoNi medium-entropy alloy by triggering co-segregation of carbon, boron, and Cr

C.D. Ding, Z.B. Jiao, J.H. Luan, B.B. Xu, R. Li, B.X. Cao, C.S. Zhou, W.H. Liu

Corrosion Science· Volume 236
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Abstract

The CrCoNi medium-entropy alloy has drawn extensive attention due to its outstanding mechanical properties, yet it suffers severe gaseous hydrogen embrittlement (HE). Here we report that co-doping of carbon and boron could greatly suppress such embrittlement, resulting in a significant reduction in ductility loss from 71 % to merely 16 %. The minor doping has no significant influence on the phase structure, grain size, and grain-boundary character. However, the co-segregation of carbon, boron, and Cr was triggered, which not only improves the grain-boundary cohesive strength but also hinders the diffusion and accumulation of hydrogen at GBs, thereby leading to improved HE resistance.
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Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Hydrogen embrittlement and corrosion behaviors in metals

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (55)

Show source-provided references
1. Hydrogen energy10.1098/rsta.2006.1965 ↗
2. Hydrogen: the future energy carrier10.1098/rsta.2010.0113 ↗
3. Hydrogen embrittlement understood10.1007/s11661-015-2836-1 ↗
4. Hydrogen induced grain boundary fracture in high purity nickel and its alloys—enhanced hydrogen diffusion along grain boundaries10.1016/0001-6160(88)90109-5 ↗
5. Hydrogen trapping and embrittlement in high-strength Al alloys10.1038/s41586-021-04343-z ↗
6. Hydrogen embrittlement in different materials: a review10.1016/j.ijhydene.2018.09.201 ↗
7. Hydrogen embrittlement resistance of precipitation-hardened FeCoNiCr high entropy alloys10.1016/j.intermet.2022.107800 ↗
8. Enumeration of the hydrogen-enhanced localized plasticity mechanism for hydrogen embrittlement in structural materials10.1016/j.actamat.2018.12.014 ↗
9. Hydrogen diffusivity and tensile-ductility loss of solution-treated austenitic stainless steels with external and internal hydrogen10.1016/j.ijhydene.2017.04.055 ↗
10. K. Scott, P. Mendez, S. Seetharaman, The Influence of Hydrogen on the Elastic Modulus of 316L and XM-19 Austenitic Stainless Steels, in: Pressure Vessels and Piping Conference, American Society of Mechanical Engineers, 2022, pp. V04BT06A032.10.1115/PVP2022-84717 ↗
11. Corrosion-induced hydrogen embrittlement in aluminum alloy 202410.1016/j.corsci.2005.05.015 ↗
12. A fracture-resistant high-entropy alloy for cryogenic applications10.1126/science.1254581 ↗
13. A nano-sized NbC precipitation strengthened FeCoCrNi high entropy alloy with superior hydrogen embrittlement resistance10.1016/j.corsci.2022.110636 ↗
14. Enhanced resistance to hydrogen embrittlement in a CrCoNi-based medium-entropy alloy via grain-boundary decoration of boron10.1080/21663831.2022.2033865 ↗
15. Defeating hydrogen-induced grain-boundary embrittlement via triggering unusual interfacial segregation in FeCrCoNi-type high-entropy alloys10.1016/j.actamat.2022.118410 ↗
16. A strong and ductile medium-entropy alloy resists hydrogen embrittlement and corrosion
17. Hydrogen embrittlement of the equi-molar FeNiCoCr alloy10.1016/j.actamat.2018.07.032 ↗
18. Hydrogen resistance of a 1 GPa strong equiatomic CoCrNi medium entropy alloy10.1016/j.corsci.2020.108510 ↗
19. Effect of Mo doping on the gaseous hydrogen embrittlement of a CoCrNi medium-entropy alloy10.1016/j.corsci.2021.109628 ↗
20. The influence of hydrogen on the plastic deformation ductility, and fracture of nickel in tension10.1016/0001-6160(63)90209-8 ↗
21. Effects of precipitation phases on the hydrogen embrittlement sensitivity of Inconel 71810.1016/S1468-6996(02)00039-6 ↗
22. Ab initio study on plane defects in zirconium–hydrogen solid solution and zirconium hydride10.1016/j.actamat.2010.03.034 ↗
23. Hydrogen, as an alloying element, enables a greater strength-ductility balance in an Fe-Cr-Ni-based, stable austenitic stainless steel10.1016/j.actamat.2020.08.024 ↗
24. The role of localized deformation in hydrogen-assisted crack propagation in 21Cr–6Ni–9Mn stainless steel10.1016/j.actamat.2009.04.027 ↗
25. Grain refinement effect on hydrogen embrittlement resistance of an equiatomic CoCrFeMnNi high-entropy alloy10.1016/j.ijhydene.2019.04.280 ↗
26. Grain boundary segregations and hydrogen embrittlement
27. Hydrogen embrittlement controlled by reaction of dislocation with grain boundary in alpha-iron10.1016/j.ijplas.2018.08.013 ↗
28. Effect of boron on the hydrogen-induced grain boundary embrittlement in α-Fe10.1016/j.ijhydene.2017.11.083 ↗
29. First-principles study on the grain boundary embrittlement of metals by solute segregation: part I. Iron (Fe)-Solute (B, C, P, and S) systems10.1007/s11661-010-0381-5 ↗
30. Microstructural evolution of a Ni-based superalloy (617B) at 700°C studied by electron microscopy and atom probe tomography10.1016/j.actamat.2011.11.020 ↗
31. Effect of grain boundary segregation of carbon on critical grain boundary strength of ferritic steel10.1016/j.scriptamat.2019.05.001 ↗
32. Hydrogen embrittlement micromechanisms and direct observations of hydrogen transportation by dislocations during deformation in a carbon-doped medium entropy alloy10.1016/j.jmrt.2022.07.061 ↗
33. Effect of carbon and nitrogen on the hydrogen embrittlement of 15Cr-15Mn-4Ni-based stable Austenitic stainless steels10.1007/s11837-020-04108-5 ↗
34. Hydrogen embrittlement of a carbon segregated Σ5(310)[001] symmetrical tilt grain boundary in α-Fe10.1016/j.msea.2014.06.071 ↗
35. Hydrogen diffusivity in boron-doped polycrystalline Ni3Al10.1016/0956-716X(94)90209-7 ↗
36. Gas-phase hydrogen permeation and diffusion in carbon steels as a function of carbon content from 500 to 900 K10.1007/BF02833976 ↗
37. Effect of boron addition on hydrogen embrittlement sensitivity in Fe–Ni based alloys10.1016/j.msea.2010.06.073 ↗
38. Atomic-scale evidence for the intergranular corrosion mechanism induced by co-segregation of low-chromium ferritic stainless steel10.1016/j.corsci.2021.109588 ↗
39. Irradiation-induced grain boundary chromium microchemistry in high alloy ferritic steels10.1016/j.scriptamat.2008.01.004 ↗
40. First-principles study of the Σ3(112) grain boundary in Fe-rich Fe-Cr alloys10.1016/j.scriptamat.2020.02.029 ↗
41. Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element10.2320/matertrans.46.2817 ↗
42. Atomic scale study of grain boundary segregation before carbide nucleation in Ni–Cr–Fe Alloys10.1016/j.jnucmat.2013.03.067 ↗
43. C–Cr segregation at grain boundary before the carbide nucleation in Alloy 69010.1016/j.matchar.2012.02.008 ↗
44. Effects of Cr, Mn on the cohesion of the γ-iron grain boundary10.1016/S1359-6454(00)00382-7 ↗
45. First-principles investigation into the effect of Cr on the segregation of multi-H at the Fe Σ3 (111) grain boundary10.1016/j.jnucmat.2013.06.015 ↗
46. First-principles localized cluster expansion study of the kinetics of hydrogen diffusion in homogeneous and heterogeneous Fe-Cr alloys10.1103/PhysRevB.99.014110 ↗
47. Enhanced hydrogen embrittlement resistance via Cr segregation in nanocrystalline Fe–Cr alloys10.1007/s40195-023-01603-x ↗
48. Hydrogen-enhanced localized plasticity—a mechanism for hydrogen-related fracture10.1016/0921-5093(94)90975-X ↗
49. Recent progress in the CoCrNi alloy system10.1016/j.mtla.2022.101476 ↗
50. The evolution of the deformation substructure in a Ni-Co-Cr equiatomic solid solution alloy10.1016/j.actamat.2017.04.033 ↗
51. A comparative study on the corrosion behavior of CoCrNi medium-entropy alloy and 316L stainless steel in simulated marine environment10.1016/j.intermet.2021.107370 ↗
52. Corrosion behavior of FeCrNi medium-entropy alloy fabricated by laser powder bed fusion
53. Influence of carbon on the corrosion behaviour of interstitial equiatomic CoCrFeMnNi high-entropy alloys in a chlorinated concrete solution10.1016/j.corsci.2019.108287 ↗
54. Corrosion behavior of an equiatomic CoCrFeMnNi high-entropy alloy compared with 304 stainless steel in sulfuric acid solution10.1016/j.corsci.2018.02.031 ↗
55. Segregation enabled outstanding combination of mechanical and corrosion properties in a FeCrNi medium entropy alloy manufactured by selective laser melting10.1016/j.jmst.2021.05.018 ↗