Ablation behavior of ZrC-SiHfOC-MoSi2 coating for carbon/carbon composites under Ar-O2 plasma flame
Source abstract
Abstract
To improve ablation resistance of ZrC-SiMOC-based (M = transition metal) coatings, a ZrC-SiHfOC-MoSi 2 coating was investigated. The results showed that the MoSi 2 shell limits the decomposition of SiC under SAPS and decreases pores of the coating. ZrC-SiHfOC coating showed large-area peeling after an Ar-O 2 plasma flame ablation for 90 s. In contrast, ZrC-SiHfOC-MoSi 2 coating revealed low ablation rates after ablation for 360 s, with the mass and linear ablation rates of −0.05 mg/s and 0.14 μm/s, respectively. MoSi 2 provides rich SiO 2 to form ZrSiO 4 to reduce the damage by plasma flame, thereby improving the ablation resistance of ZrC-based coatings.
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Research context
OpenAlex topics: Advanced ceramic materials synthesis · Diamond and Carbon-based Materials Research · Energetic Materials and Combustion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (61)
Show source-provided references
1. Advanced sandwich structures for thermal protection systems in hypersonic vehicles: a review10.1016/j.compositesb.2021.109301 ↗
2. A systematic approach for horizontal and vertical scale up of sintered ultra-high temperature ceramic matrix composites for aerospace-advances and perspectives10.1016/j.compositesb.2022.109709 ↗
3. Advances in ablative composites of carbon based materials: a review10.1021/acs.iecr.9b04625 ↗
4. Aero-thermo-chemical characterization of ultra-high-temperature ceramics for aerospace applications10.1016/j.jeurceramsoc.2017.12.043 ↗
5. Simulation and application of a new multiphase flow ablation test system for thermal protection materials based on liquid rocket engine10.3390/aerospace9110701 ↗
6. Effects of thermal and thermomechanical induced mechanical changes of C/C composites10.1016/j.carbon.2010.04.040 ↗
7. Influence of material and process parameters on microstructure evolution during the fabrication of carbon-carbon composites: a review10.1007/s10853-021-06401-3 ↗
8. Oxidation-resistant carbon-carbon composites up to 1700 °C10.1016/0008-6223(94)00173-W ↗
9. Evaluation of ablation resistant ZrC-SiC multilayer coating for SiC coated carbon/carbon composites under oxyacetylene and laser conditions10.1016/j.corsci.2022.110427 ↗
10. Discussion on structural parameters of the multilayer ZrC/TaC coatings based on stress analysis and ablation behaviors10.1016/j.surfcoat.2022.128243 ↗
11. Ablation behavior of SiC/ZrB2 ultra-high temperature ceramic coatings by solid shielding shrouded plasma spray for high-temperature applications (temperature above 2000 °C)10.1016/j.surfcoat.2020.126271 ↗
12. Hafnium carbide protective layer coatings on carbon/carbon composites deposited with a vacuum plasma spray coating method10.1016/j.jeurceramsoc.2016.01.032 ↗
13. Micro/nano multiscale reinforcing strategies toward extreme high-temperature applications: Take carbon/carbon composites and their coatings as the examples10.1016/j.jmst.2021.03.076 ↗
14. Improved damage tolerance and oxidation resistance of (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)B2-SiC by introducing chopped carbon fibers10.26599/JAC.2024.9220844 ↗
15. Ablation behavior under oxyacetylene torch of ZrC coating modified by SiC/TaC nanocomposites10.1016/j.corsci.2022.110423 ↗
16. Ablation resistance of supersonic-atmosphere-plasma-spraying ZrC coating doped with ZrO2 for SiC-coated carbon/carbon composites10.1016/j.corsci.2017.03.019 ↗
17. Modeling oxidation kinetics of SiC-containing refractory diborides10.1111/j.1551-2916.2011.04927.x ↗
18. Ablation behavior of ultra-high temperature composite ceramic matrix composites10.15541/jim20210182 ↗
19. Ablation behavior of single and alternate multilayered ZrC-SiC coatings under oxyacetylene torch10.1016/j.jeurceramsoc.2021.11.008 ↗
20. Ablation resistant ZrC coating modified by polymer-derived SiC/TiC nanocomposites for ultra-high temperature application10.1016/j.jeurceramsoc.2021.09.057 ↗
21. Ablation resistance of SiC-modified ZrC coating prepared by SAPS for SiC-coated carbon/carbon composites10.1111/ijac.12645 ↗
22. Long time ablation behaviors of designed ZrC-SiC-TiC ternary coatings for environments above 2000 °C10.1016/j.corsci.2020.108645 ↗
23. Investigation on the ablation performance and mechanism of HfC coating modified with TaC10.1016/j.corsci.2020.108649 ↗
24. Thermoablative resistance of ZrB2-SiC-WC ceramics at 2400 °C10.1016/j.actamat.2017.05.033 ↗
25. M. Cinibulk, Oxidation transitions for SiC Part I. Active-to-passive transitions
26. High-temperature oxidation of silicon carbide in simulated atmospheric re-entry conditions10.1007/BF01116013 ↗
27. Ablation behavior and mechanism of SiO2f/SiO2, SiO2f/BN and Si3N4f/BN radar wave transparent composites10.1016/j.corsci.2018.05.006 ↗
28. High-temperature protective coatings on carbon composites10.3103/S1068798X19090132 ↗
29. Ablation mechanism of HfC-HfO2 protective coating for SiC-coated C/C composites in an oxyacetylene torch environment10.1016/j.jmst.2016.11.010 ↗
30. Ablation mechanism and properties of SiO2 modified ZrB2-SiC coatings fabricated on C/C composites via plasma spraying technology, Surface and Coatings
31. The fate and role of in situ formed carbon in polymer-derived ceramics, Progress Material
32. Additive manufacturing of polymer-derived ceramics10.1126/science.aad2688 ↗
33. Single-source precursor derived high-entropy metal-carbide nanowires: microstructure and growth evolution10.26599/JAC.2023.9220806 ↗
34. Microstructure and phase evolution of polymer-derived SiHfOC ceramic microspheres10.1111/jace.18682 ↗
35. Ablation resistance of ZrC coating modified by polymer-derived SiHfOC ceramic microspheres at ultrahigh temperature10.1016/j.jmst.2023.09.031 ↗
36. MoSi2 addition for high ablation resistance of dense ZrB2-based composite coating prepared by very low-pressure plasma spraying10.1016/j.corsci.2022.110800 ↗
37. Recent progress on synthesis of ceramics core/shell nanostructures10.2298/PAC1302045S ↗
38. Fabrication of monodispersed α-Fe2O3@SiO2 core-shell nanospheres and investigation of their dielectric behavior10.1016/j.jallcom.2018.08.250 ↗
39. A novel SiCN@TiO2 core-shell ceramic microspheres derived from a polymeric precursor10.1016/j.ceramint.2016.01.102 ↗
40. Melting index of plasma sprayed molybdenum silicide characterized by constitutions and its effect on oxidation kinetics10.1016/j.jallcom.2018.06.296 ↗
41. Silicon carbide coating to protect carbon/carbon composites against oxidation10.1016/j.scriptamat.2004.12.029 ↗
42. Mechanical properties and ablation resistance of La2O3-modified HfC-SiC coating for SiC-coated C/C composites10.1016/j.corsci.2021.109259 ↗
43. The electrical double layer and the theory of electrocapillarity10.1021/cr60130a002 ↗
44. Silanization mechanism of silica nanoparticles in bitumen using 3-aminopropyl triethoxysilane (APTES) and 3-glycidyloxypropyl trimethoxysilane (GPTMS)10.1021/acssuschemeng.9b06741 ↗
45. Preparation and characterization of surface-functionalization of silica-coated magnetite nanoparticles for drug delivery10.1142/S1793292014500428 ↗
46. Surface modification of silicon carbide with silane coupling agent and hexadecyl iodiele10.1016/j.apsusc.2016.10.102 ↗
47. Surface chemical functionalization of starch nanocrystals modified by 3-aminopropyl triethoxysilane10.1016/j.ijbiomac.2018.12.200 ↗
48. Liquid-phase plasma-assisted in situ synthesis of amino-rich nanocarbon for transition metal ion adsorption10.1021/acsanm.9b01915 ↗
49. NIST X-ray photoelectron spectroscopy database, National Institute of Standards and Technology
50. MoSi2- and WSi2-based embedded ceramic composite thermocouples for high-temperature and harsh-environment sensing10.1016/j.sna.2018.01.047 ↗
51. Graphite carbon-supported Mo2C nanocomposites by a single-step solid state reaction for electrochemical oxygen reduction10.1371/journal.pone.0138330 ↗
52. Oxidation and ablation protection of plasma sprayed LaB6-MoSi2-ZrB2 coating for carbon/carbon composites10.1016/j.corsci.2019.01.043 ↗
53. MoSi2-HfC/TaC-HfC multi-phase coatings synthesized by supersonic atmospheric plasma spraying for C/C composites against ablation10.1016/j.corsci.2021.109884 ↗
54. Ablation behaviors of ZrC-20 vol%MoSi2 composite coating under different heat fluxes10.4028/www.scientific.net/SSP.281.516 ↗
55. Ablation resistance of ZrC-MoSi2/ZrC-SiC double-layered coating in a plasma flame10.1016/j.corsci.2018.10.006 ↗
56. MoSi2 modified HfC coating for the ablation protection of SiC-coated C/C composites: ablation resistance and behavior10.1016/j.corsci.2022.110418 ↗
57. Cyclic ablation behavior of C/C-ZrC-SiC-ZrB2 composites under oxyacetylene torch with two heat fluxes at the temperatures above 2000 ºC10.1016/j.corsci.2020.109202 ↗
58. Ablation behaviour and mechanism of Mg-modified ZrC-SiC composite in plasma ablation flame10.1016/j.corsci.2022.110523 ↗
59. Microstructure and ablation resistance of ZrCxNy-modified ZrC-SiC composite coating for carbon/carbon composites10.1016/j.jeurceramsoc.2018.05.043 ↗
60. Thermal stability of zircon (ZrSiO4)10.1016/j.jeurceramsoc.2007.12.040 ↗
61. High temperature oxidation resistance of La2O3-modified ZrB2-SiC coating for SiC-coated carbon/carbon composites10.1016/j.jallcom.2018.06.230 ↗