journal article·2023-08

Compositional dependence of high temperature oxidation resistance in the L12-strengthened high-thermostability copper alloys

Y.Y. Shao, J.H. Yuan, X.N. Li, Z.M. Li, Y.L. Hu, Z.L. Cheng, R.W. Liu, R. Zheng, Y.D. Hou, M. Li, Y.H. Zheng, C. Dong

Corrosion Science· Volume 220
Publisher page

Abstract

Oxidation resistance determines the applicability in high temperature atmospheric environment of the novel heat-resisting cuboidal L1 2 -γ` phase coherent precipitation strengthened Cu-Ni-Al alloys, and it needs to be systematically evaluated in a wide composition range. The results indicate that the oxidation behavior of the Cu 1-x(Ni 3/4Al 1/4) x alloys exhibits a strong composition dependence, displaying excellent oxidation resistance at 850 °C when x is higher than 25 at%. From multi-aspects of atom-phase-alloy, combining the microstructural investigation and first principles calculation, the formation of Al 2O 3 protective layer and the synergistic effect of the basic components are crucial factors for the oxidation resistance of the alloys.
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Research context

OpenAlex topics: High-Temperature Coating Behaviors · Advanced ceramic materials synthesis · Advanced materials and composites

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