journal article·2022-12Open access

Grain boundary transport through thermally grown alumina scales on NiAl

Talia L. Barth, Peter K. Weber, Tian Liu, Fei Xue, Thomas C. Valenza, Lavina Backman, Elizabeth Opila, Emmanuelle A. Marquis

Corrosion Science· Volume 209

Abstract

The oxidation resistance of Ni-based alloys is typically improved by additions of elements segregating to grain boundaries, contributing to reducing scale growth, and improving scale adherence. To develop a mechanistic understanding of doping, outward Al and inward O fluxes through the scale formed on β-NiAl with Ti, Y, and Ti+Y additions were characterized for oxidation at 1200 °C and times up to 100 h. Doped alloys exhibited varying reductions in oxidation rates and Al and O fluxes affecting scale grain morphologies. Ti+Y co-doping further reduced the outward Al and inward O transport compared to doping with Ti or Y alone.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: High-Temperature Coating Behaviors · Catalytic Processes in Materials Science · Intermetallics and Advanced Alloy Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (79)

Show source-provided references
1. Long-term oxidation of superalloys10.1007/BF00610842 ↗
2. Microstructural and compositional design of Ni-based single crystalline superalloys– A review10.1016/j.jallcom.2018.01.224 ↗
3. Oxidation of Ni-Cr-Al alloys between 1000 and 1200C10.1149/1.2407837 ↗
4. Introduction to the high-temperature
5. Optimization of reactive-element additions to improve oxidation performance of alumina-forming alloys10.1111/j.1151-2916.2003.tb03358.x ↗
6. The reactive element effect in high-temperature corrosion10.1016/0921-5093(89)90730-2 ↗
7. B.A. Pint, Progress in Understanding the Reactive Element Effect Since the Whittle and Stringer LIterature Review, Proceedings of the John Stringer Symposium on High Temperature Corrosion. 5–8 (2001) 9–19.
8. Impurity effects on alumina scale growth10.1111/j.1151-2916.2003.tb03355.x ↗
9. Current thoughts on reactive element effects in alumina-forming systems: in memory of john stringer10.1007/s11085-016-9625-0 ↗
10. Microstructure, adhesion and growth kinetics of protective scales on metals and alloys10.1007/BF00656571 ↗
11. The effect of yttrium on the growth process and microstructure of a-Al2O3 on FeCrAl10.1023/A:1018803113093 ↗
12. 18O tracer studies of Al2O3 scale formation on NiCrAl Alloys10.1007/BF00742122 ↗
13. 18O/SIMS characterization of the growth mechanism of doped and undoped a-Al2O310.1007/BF00665610 ↗
14. Oxidation mechanisms of B-NiAl+Zr determined by SIMS10.1016/0010-938X(95)00034-H ↗
15. Quantification of aluminum outward diffusion during oxidation of FeCrAl alloys10.1007/s11085-005-4391-4 ↗
16. Segregation studies of oxidized Y and Zr doped NiAl10.1002/maco.19950460405 ↗
17. Grain boundary segregation of cation dopants in a-Al2O3 scales10.1149/1.1838563 ↗
18. Ionic segregation on grain boundaries in thermally grown alumina scales10.3184/096034012X13343209167745 ↗
19. Segregation of Y to grain boundaries in the Al2O3 scale formed on an ODS alloy10.1149/1.2100376 ↗
20. High-temperature oxidation behavior of a Ni-Cr-Al-Fe-Y Alloy10.1007/BF00665187 ↗
21. Oxidation behavior of platinum-aluminum alloys and the effect of Zr doping10.1557/JMR.1999.0615 ↗
22. The effect of lanthanum on the scales developed on thin foils of Fe-20Cr-5Al at very high temperatures10.1023/A:1018891211160 ↗
23. The use of two reactive elements to optimize oxidation performance of alumina-forming alloys10.1179/mht.2003.044 ↗
24. Effect of co-doping of two reactive elements on alumina scale growth of B-NiAl at 1200C10.1016/j.corsci.2014.07.036 ↗
25. Differences in growth mechanisms of oxide scales formed on ODS and conventional wrought alloys10.1007/BF00665269 ↗
26. Batch to batch variations in the oxidation behaviour of alumina forming Fe-based alloys10.1002/(SICI)1521-4176(200005)51:5<350::AID-MACO350>3.0.CO;2-7 ↗
27. Influences of superalloy composition and Pt content on the oxidation behavior of gamma-gamma prime NiPtAl bond coatings10.1007/s11085-016-9646-8 ↗
28. Effect of superalloy substrate composition on the performance of a thermal barrier coating system10.1023/A:1025992502450 ↗
29. Oxidation behavior of a single-crystal Ni-base superalloy in air at 900, 1000 and 1100C10.1007/s11085-006-9016-z ↗
30. The influence of oxides on the performance of advanced gas turbines10.1016/j.jeurceramsoc.2007.12.023 ↗
31. Microstructural study of the theta-alpha transformation in alumina scales formed on nickel-aluminides10.1179/mht.2000.011 ↗
32. Effect of quaternary additions on the oxidation behavior of Hf-doped NiAl10.1023/A:1023087926788 ↗
33. Correlation between the microstructure, and growth kinetics of alumina scales on a FeCrAlY alloy10.1007/s11661-007-9342-z ↗
34. Oxygen permeability and grain-boundary diffusion applied to alumina scales
35. The effect of yttrium on densification and grain growth in a-alumina10.1016/S1359-6454(02)00159-3 ↗
36. High-temperature creep resistance in rare-earth-doped, fine-grained Al2O310.1557/JMR.1998.0362 ↗
37. Role of segregating dopants on the improved creep resistance of aluminum oxide10.1016/S1359-6454(99)00278-5 ↗
38. Experimental observations in support of the dynamic-segregation theory to explain the reactive-element effect10.1007/BF01046818 ↗
39. Influence of yttrium-alloying addition on the oxidation of alumina formers at 1173K10.1023/A:1020511304401 ↗
40. The role of yttrium in high-temperature oxidation behavior of Ni-Cr-Al Alloys10.1007/BF00612046 ↗
41. G.J. Santoro, D.L. Deadmore, C.E. Lowell, Oxidation of Alloys in Nickel-Aluminum System with Third-Element Additions of Chromium, Silicon, and Titanium at 1100C, NASA Technical Note. D-6414 (1971) 1–28.
42. C.E. Lowell, G.J. Santoro, The 1200C Cyclic Oxidation Behavior of Two Nickel-Aluminum Alloys (Ni3Al and NiAl) with Additions of Chromium, Silicon, and Titanium, Nasa Technical Note. (1972) 1–17.
43. The influence of Y, Zr or Ti additions on the high temperature oxidation resistance of Fe-Ni-Cr-Al Alloys of Variable Purity10.1016/0010-938X(84)90078-7 ↗
44. Modification of alumina scale formation on FeCrAlY alloys by minor additions of group IVa elements10.1007/s10853-008-2639-5 ↗
45. Effect of Si and Ti additions on alumina scale formation on NiCrAlY-Alloys
46. Grain boundary chemistry and transport through alumina scales on NiAl alloys10.1007/s11085-016-9697-x ↗
47. On aliovalent cations control of α-alumina growth on doped and undoped NiAl10.1016/j.actamat.2021.116809 ↗
48. Structural and electron diffraction data for sapphire (a-Al2O3)10.1002/jemt.1060020309 ↗
49. SiC Depletion in ZrB2–30 vol% SiC at Ultrahigh Temperatures10.1111/jace.13519 ↗
50. Oxygen diffusion mechanisms during high-temperature oxidation of ZrB2-SiC10.1111/jace.15298 ↗
51. NanoSIP: NanoSIMS applications for microbial biology10.1007/978-1-61779-827-6_13 ↗
52. Subnanometer scale study of segregation at grain boundaries in an Fe(Si) alloy10.1016/S1359-6454(98)00262-6 ↗
53. Characterization of the alumina scale formed on coated and uncoated doped superalloys10.1016/j.surfcoat.2011.07.044 ↗
54. Effect of titanium addition on alumina growth mechanism on yttria-containing FeCrAl-base alloy10.1007/s11085-018-9861-6 ↗
55. Composition and growth mechanisms of alumina scales on FeCrAl-based alloys determined by SIMS10.1016/0169-4332(91)90069-V ↗
56. Yttrium doping effect on oxygen grain boundary diffusion in a-Al2O310.1016/j.actamat.2007.08.016 ↗
57. Self-diffusion in a-Al2O3. IV. Oxygen grain-boundary self-diffusion in undoped and yttria-doped alumina polycrystals10.1080/01418619608243697 ↗
58. The effect of yttrium on oxygen grain-boundary transport in polycrystalline alumina measured using Ni marker particles10.1111/j.1551-2916.2008.02391.x ↗
59. Aluminum-26 grain boundary diffusion in pure and Y-doped polycrystalline a-Al2O310.1016/j.actamat.2017.01.005 ↗
60. Oxygen diffusion in sapphire10.1111/j.1151-2916.1982.tb09944.x ↗
61. Effect of environment on the scale formed on oxide dispersion strengthened FeCrAl at 1050°C and 1100°C10.3184/096034012X13317275660176 ↗
62. The oxidation mechanism of Ni3Al containing yttrium10.1007/BF00612170 ↗
63. Cyclic oxidation behavior of Hf/Zr co-doped EB-PVD B-NiAl coatings at 1200C10.1016/j.surfcoat.2015.05.039 ↗
64. Influence of yttrium doping on grain misorientation in aluminum oxide10.1111/j.1151-2916.1998.tb02726.x ↗
65. On the growth of Al2O3 scales10.1016/j.actamat.2013.07.024 ↗
66. Understanding slow-growing alumina scale mediated by reactive elements: perspective via local metal-oxygen bonding strength10.1016/j.scriptamat.2018.03.002 ↗
67. A study of the growth of a-Al2O3 scales using high-resolution imaging secondary mass spectrometry10.5006/1.3293495 ↗
68. Isotope exchange studies of oxidation mechanisms in nickel-base superalloys using FIB-SIMS techniques10.1016/j.surfcoat.2006.07.243 ↗
69. The role of oxide microstructure and growth stresses in the high-temperature scaling of nickel10.1007/BF02642020 ↗
70. Stress development in alumina scales formed upon oxidation of (111) NiAl single crystals10.1016/S0010-938X(97)83344-6 ↗
71. Growth stress-microstructure relationships for alumina scales
72. Competition between stress generation and relaxation during oxidation of an Fe-Cr-Al-Y Alloy10.1023/A:1018828619028 ↗
73. Stress development and relaxation in Al2O3 during early stage oxidation of B-NiAl10.3184/096034005782744146 ↗
74. Microstructural changes during heat treatment of sintered Al2O310.1111/j.1151-2916.1973.tb12502.x ↗
75. Sintering and grain growth of ultrapure alumina10.1007/BF00351254 ↗
76. Sintering and grain growth of alumina10.1111/j.1151-2916.1954.tb13993.x ↗
77. Structure and grain coarsening during the sintering of alumina10.1111/j.1151-2916.1986.tb04711.x ↗
78. Microstructure of alumina scales formed on NiCoCrAl alloys with and without yttrium10.1016/0921-5093(89)90733-8 ↗
79. The effect of Ti on the early stages of oxidation of an alumina-forming NiCrAl alloy10.1007/s11085-019-09911-3 ↗