journal article·2023-02Open access

Selective oxidation of aluminium in Mo(Al,Si)2

Zhaoying Ding, Johannes C. Brouwer, Cees Kwakernaak, Marcel J.M. Hermans, Vera Popovich, Willem J. Quadakkers, Willem G. Sloof

Corrosion Science· Volume 211

Abstract

Mo(AlxSi1-x)2 alloy with x in the range of 0.35–0.65 were prepared by a one-step spark plasma sintering. To study the exclusive formation of an α-Al2O3 scale, oxidation experiments were conducted in low and high oxygen partial pressure ambient at 1373 K; viz.: 10−14 and 0.21 atm. The oxidation kinetics follows a parabolic rate law after a transient period. A counter-diffusion process of O and Al along grain boundaries of Al2O3 scale is responsible for the equiaxed and columnar grain growth based on a two-layered microstructure. The formation of a dense equiaxed α-Al2O3 layer contributes to excellent oxidation resistance.
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Research context

OpenAlex topics: Intermetallics and Advanced Alloy Properties · High-Temperature Coating Behaviors · Advanced ceramic materials synthesis

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