journal article·2025-04

Effect of temperature gradient on the formed corrosion products films of 70/30 Cu-Ni alloy immersed in 3.5 % NaCl solution

Yonghui Cui, Rui Liu, Yu Cui, Fuhui Wang, Li Liu

Corrosion Science· Volume 245
Publisher page

Abstract

The effect of temperature gradients on the structures and chemical compositions of corrosion products films on 70/30 Cu-Ni alloy in 3.5 % NaCl solution has been investigated. A novel dissolution-deposition model with convection parameters has been proposed. Zero gradient of temperature (ZGT) promoted a protective Cu 2O layer with minimal Cu 2(OH) 3Cl. Negative gradient of temperature (NGT) resulted in a thinner Cu 2O layer and a non-protective Cu 2(OH) 3Cl two-layer structure with worst corrosion resistance, while positive gradient of temperature (PGT) solely formed a thicker and more protective Cu 2O layer. Additionally, the effect of temperature gradients on Ni enrichment has been analyzed.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · High-Temperature Coating Behaviors · Metal and Thin Film Mechanics

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