Corrosion performance of the biocompatible β-Ti12Mo6Zr2Fe alloy submitted to laser and plasma-nitriding surface modifications
Source abstract
Abstract
The corrosion behaviour of laser and plasma nitrided β-Ti12Mo6Zr2Fe biomaterial was evaluated. Polarisation curves and electrochemical impedance spectroscopy were performed in simulated body fluid (SBF) at 37 °C. Both treatments formed titanium-nitride at the alloy’s surface, and significantly improved the corrosion performance of the alloy. At anodic potentials of the order of 1.0 V, the titanium-nitride layer seems to oxidise, independent of the nitriding process. Nanometric fissures formed on the plasma titanium-nitride layer seems to govern the impedance response at low frequencies, exposing the substrate to the electrolyte. Laser titanium-nitride layer is thicker and lead to a better corrosion performance.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal and Thin Film Mechanics · Titanium Alloys Microstructure and Properties · Bone Tissue Engineering Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (59)
Show source-provided references
1. Titanium alloys for aerospace structures and engines
2. Titanium alloys – type Ti-6Al-4V
3. Ti based biomaterials, the ultimate choice for orthopaedic implants – a review10.1016/j.pmatsci.2008.06.004 ↗
4. Problem of stress shielding and improvement to the hip implant designs: a review10.3923/jms.2007.460.467 ↗
5. Ti-6Al-4V ion solution inhibition of osteogenic cell phenotype as a function of differentiation timecourse in vitro10.1016/0142-9612(96)00009-9 ↗
6. Vanadium ionic species from degradation of Ti-6Al-4V metallic implants: In vitro cytotoxicity and speciation evaluation10.1016/j.msec.2018.11.090 ↗
7. Biocompatible Nb2O5 thin films prepared by means of the sol–gel process
8. Surface modification of titanium, titanium alloys, and related materials for biomedical applications10.1016/j.mser.2004.11.001 ↗
9. Bone graft and bone graft substitutes: a review of current technology and applications10.1002/jab.770020307 ↗
10. Calcium phosphates as substitution of bone tissues10.1016/j.progsolidstchem.2004.07.001 ↗
11. Hydroxyapatite growth on anodic TiO2 nanotubes10.1002/jbm.a.30677 ↗
12. Surface engineering for bone implants: a trend from passive to active surfaces10.3390/coatings2030095 ↗
13. Advances in the surface modification techniques of bone-related implants for last 10 years10.1093/rb/rbu007 ↗
14. Hard coatings based on metal nitrides, metal carbides and nanocomposite materials: PVD process and properties
15. Titanium-nitride coating of orthopaedic implants: a review of the literature10.1155/2015/485975 ↗
16. The effect of surface laser texturing on the corrosion performance of the biocompatible β-Ti12Mo6Zr2Fe alloy
17. ASTM F1813–06 Specification, standard specification for wrought titanium–12 molybdenum–6 zirconium–2 iron alloy for surgical implant (UNS R58120), ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428–2959. United States. 2015 〈https://doi.org/10.1520/F1813–21〉.10.1520/F1813-21 ↗
18. The role of hydrogen in plasma nitriding: Hydrogen behavior in the titanium nitride layer10.1016/S1288-3255(00)00108-8 ↗
19. Influence of laser nitriding on the surface and corrosion properties of Ti-20Nb-13Zr alloy in artificial saliva for dental applications10.1007/s11665-018-3569-2 ↗
20. Corrosion properties of TIN prepared by laser gas alloying of Ti and Ti6Al4V10.1016/S0010-938X(98)00046-8 ↗
21. Influence of nitrogen gas over microstructural, vibrational and mechanical properties of CVD Titanium nitride (TiN) thin film coating10.1016/j.ceramint.2021.02.254 ↗
22. A Raman-scattering study on the interface structure of nanolayered TiAlN/TiN and TiN/NbN multilayer thin films grown by reactive dc magnetron sputtering10.1063/1.1946193 ↗
23. Raman scattering, superconductivity, and phonon density of states of stoichiometric and nonstoichiometric TiN10.1103/PhysRevB.17.1095 ↗
24. On the intrinsic coupling between constant-phase element parameters alpha and Q in electrochemical impedance spectroscopy10.1016/j.electacta.2012.04.020 ↗
25. The analysis of electrode impedances complicated by the presence of a constant phase element10.1016/S0022-0728(84)80324-1 ↗
26. Technical Note: concerning the conversion of the constant phase element parameter Y0 into a capacitance10.5006/1.3280607 ↗
27. Electrochemical impedance analysis of TiO2 nanotube porous layers based on an alternative representation of impedance data10.1016/j.jelechem.2014.06.034 ↗
28. Surface modification of titanium by chemical and thermal methods – electrochemical impedance spectroscopic studies10.1179/147842209X12590591256936 ↗
29. Corrosion behaviour of Ti–6Al–7Nb and Ti–6Al–4V ELI alloys in the simulated body fluid solution by electrochemical impedance spectroscopy10.1016/j.electacta.2006.06.018 ↗
30. In vitro corrosion and bioactivity performance of surface-treated Ti-20Nb-13Zr alloys for orthopedic applications10.3390/coatings9050344 ↗
31. The effect of heat treatment on the electrochemical corrosion behavior of reactive plasma-sprayed TiN coatings10.1016/j.apsusc.2011.06.143 ↗
32. Tribological and electrochemical performances of Cr/CrN and Cr/CrN/CrAlN multilayer coatings deposited by RF magnetron sputtering10.1016/j.triboint.2014.03.018 ↗
33. Effect of thermomechanical processing on the corrosion resistance of Ti6Al4V alloys in biofluids10.1016/j.corsci.2009.08.014 ↗
34. Corrosion behaviour of glow discharge nitrided titanium alloys10.1016/S0010-938X(02)00139-7 ↗
35. Corrosion resistance of Ti–6Al–4V alloy with nitride coatings in Ringer’s solution10.1016/j.corsci.2012.10.005 ↗
36. Improving corrosion resistance of Ti–6Al–4V alloy through plasma-assisted PVD deposited nitride coatings10.1016/j.corsci.2014.07.047 ↗
37. Tribological, electrochemical and tribo-electrochemical characterization of bare and nitrided Ti6Al4V in simulated body fluid solution10.1016/j.corsci.2011.01.057 ↗
38. Electrochemical impedance spectroscopy study of the passive oxide film on titanium for implant application10.1016/0013-4686(95)00465-3 ↗
39. Study of the corrosion behavior of titanium and some of its alloys for biomedical and dental implant applications10.1016/S0022-0728(99)00260-0 ↗
40. A study of histological responses from Ti-6Al-7Nb alloy dental implants with and without plasma-sprayed hydroxyapatite coating in dogs
41. Chapter 3 - Tissue renewal and repair: regeneration, healing, and fibrosis
42. Physicochemical characterization of photoelectrodes of Ti/TiO2 prepared by thermal oxidation of titanium10.1016/S0921-5107(97)00043-3 ↗
43. Corrosion and electrochemical impedance properties of Ti alloys as orthopaedic trauma implant materials10.20964/2017.10.05 ↗
44. EIS study of Ti and its alloys in biological media10.1016/S0022-0728(02)00814-8 ↗
45. Degradation characteristics of hydroxyapatite coatings on orthopaedic TiAlV in simulated physiological media investigated by electrochemical impedance spectroscopy10.1016/S0142-9612(03)00362-4 ↗
46. Corrosion characterization of titanium alloys by electrochemical techniques10.1016/j.electacta.2005.02.121 ↗
47. Chapter 5 - Electrochemistry
48. Tribological and electrochemical performance of PVD TiN coatings on the femoral head of Ti-6Al-4V artificial hip joints10.1016/S0257-8972(02)00630-8 ↗
49. A study of the corrosion properties of TiN coated and nitrided Ti-6Al-4V10.1016/0010-938X(95)00065-R ↗
50. Impedance study on the corrosion of PVD and CVD titanium nitride coatings10.4028/www.scientific.net/MSF.44-45.29 ↗
51. Electrochemical impedance spestroscopy of complex titanium nitride coating with thin oxide surface film deposited on pure titanium
52. F. Cai, X. Huang, Q. Yang, Electrochemical behaviours of titanium nitride (TiN) and chromium nitride (CrN) based PVD coating systems (Paper No: GT2013–94024, V05 AT21A002; 8 pages). In: Proceedings of ASME Turbo Expo 2013 Vol 5A GT2013, June 3–7, 2013, San Antonio, Texas, USA, The American Society of Mechanical Engineers.; ASME International Gas Turbine Institute. 〈https://doi.org/10.1115/GT2013–94024〉.10.1115/GT2013-94024 ↗
53. Laser-sustained plasma (LSP) nitriding of titanium: a review10.3390/coatings9050283 ↗
54. Titanium nitride films for micro-supercapacitors: effect of surface chemistry and film morphology on the capacitance10.1016/j.jpowsour.2015.09.012 ↗
55. Effect of oxidative surface treatments on charge storage at titanium nitride surfaces for supercapacitor applications10.1039/C6TA08308K ↗
56. An overview on the development of electrochemical capacitors and batteries – Part I
57. Corrosion mechanism in PVD deposited nano-scale titanium nitride thin film with intercalated titanium for protecting the surface of silicon10.1016/j.electacta.2018.01.042 ↗
58. A review of the corrosion of laser nitrided Ti‐6Al‐4V10.1108/00035591111130523 ↗
59. Effect of laser gas nitriding on the microstructure and corrosion properties of Ti–6Al–4V alloy10.2355/isijinternational.47.709 ↗