journal article·2024-05

Thermal cycling behavior of Yb3+-Ce4+ co-doped La2Zr2O7-based TBCs: Experimental and theoretical research

Pengsen Zhao, Haizhong Zheng, Guifa Li, Yongxiang Geng, Yixin Xiao, Hongbo Guo, Gang Wang, Shixian Zhao, Ping Peng

Corrosion Science· Volume 231
Publisher page

Abstract

The thermal cycling behavior of Yb 3+-Ce 4+-La 2Zr 2O 7 /YSZ (LYZCO/YSZ) TBCs was systematically investigated via experiment and first-principles calculation. Results suggest that ceramic grain boundary cracking is the root cause of LYZCO/YSZ TBCs thermal cycle failure. Compared to La 2Zr 2O 7 /YSZ TBCs, LYZCO/YSZ TBCs own an outstanding thermal cycle life at 1100 ℃, which is attributed to LYZCO`s higher TEC (10.431×10 −6 /K, 1100 ℃) and lower thermal conductivity (1.299 W/(m·K), 1100 ℃). Furthermore, Griffith`s separation work of the LYZCO/YSZ interface is merely −0.576 J/m 2, implying that the LYZCO/YSZ TBCs are particularly prone to cracking at this interface. Weakly bonded La-O is the first site at this interface cracking.
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Research context

OpenAlex topics: Nuclear materials and radiation effects · Nuclear Materials and Properties · Advanced ceramic materials synthesis

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