journal article·2022-09

Long-term and cyclic ablation behavior of La2O3 modified Cf/ZrB2-SiC composites at 2500 ℃

Bo-Wen Chen, De-Wei Ni, Jun Lu, Fei-Yan Cai, Xue-Gang Zou, Chun-Jing Liao, Hong-Da Wang, Shao-Ming Dong

Corrosion Science· Volume 206
Publisher page

Abstract

In this work, long-term and cyclic ablation behavior of the La 2O 3 modified C f/ZrB 2 -SiC composites were studied by air plasma torch at 2500 ℃. It is indicated that a micron-sized ZrO 2-La 2O 3-SiO 2 liquid phase layer forms on the ablation surface at 2500 ℃, which reduces the evaporation of SiO 2 and decreases the mass recession rates of the composites. However, the ZrO 2-La 2O 3-SiO 2 liquid phase layer exhibits poor structure stability. In addition, the La 2O 3 weakens the pinning effect of bulk ZrO 2 . Consequently, the oxide layer with low viscosity tends to sputter out due to the mechanical scouring by plasma flame. Therefore, the linear recession rates of the composites are increased during cyclic ablation with the increase of the La 2O 3 content.
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · Advanced materials and composites · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Micro/nano multiscale reinforcing strategies toward extreme high-temperature applications: take carbon/carbon composites and their coatings as the examples10.1016/j.jmst.2021.03.076 ↗
2. Properties of large scale ultra-high temperature ceramic matrix composites made by filament winding and spark plasma sintering10.1016/j.compositesb.2021.108839 ↗
3. Ablation-resistant carbide Zr0.8Ti0.2C0.74B0.26 for oxidizing environments up to 3000 °C10.1038/ncomms15836 ↗
4. Chemical reactions and thermal stress induced microstructure evolution in 2D-Cf/ZrB2-SiC composites10.1016/j.jmst.2020.12.054 ↗
5. Fabrication and properties of Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C-SiC high-entropy ceramic matrix composites via precursor infiltration and pyrolysis10.1016/j.jeurceramsoc.2021.05.026 ↗
6. Fabrication and microstructure evolution of Csf/ZrB2-SiC composites via direct ink writing and reactive melt infiltration10.1007/s40145-021-0512-z ↗
7. Selection, processing, properties and applications of ultra-high temperature ceramic matrix composites, UHTCMCs–a review
8. Advanced structural ceramics in aerospace propulsion10.1038/nmat4687 ↗
9. L. Zoli, D. Sciti, A. Vinci, P. Galizia, F. Monteverde, S. Failla, L. Silvestroni, Ultra-High Temperature Ceramic Matrix Composites, Faenza, Italy, 2021.10.1016/B978-0-12-818542-1.00023-0 ↗
10. Advances in ultra-high temperature ceramics, composites, and coatings10.1007/s40145-021-0550-6 ↗
11. K.M. Sayler, Defense Primer: Emerging Technologies, Congressional Research Service, 2021.
12. K.M. Sayler, Hypersonic Weapons: Background and Issues for Congress, Congressional Research Service, 2019.
13. Difference evaluation on ablation behaviors of ZrC-based and ZrB2-based UHTCs coatings10.1016/j.corsci.2020.109181 ↗
14. Influence of pressure on the oxidation resistance of carbon fiber reinforced ZrB2/SiC composites at 2000 and 2200 °C10.1016/j.corsci.2021.109377 ↗
15. ZrB2/HfB2-SiC ceramics modified by refractory carbides: an overview10.1134/S0036023619140079 ↗
16. HfB2-SiC-MoSi2 oxidation resistance coating fabricated through in-situ synthesis for SiC coated C/C composites10.1016/j.jallcom.2017.06.008 ↗
17. Surface modification and ablation behaviors of nitrogen-doped C/C-ZrC-SiC composites via hot isostatic pressing10.1016/j.corsci.2021.109844 ↗
18. Ablation and heat insulation performances of nose-shaped ZrC-C composites with gradient pore structure10.1016/j.compositesb.2021.109040 ↗
19. Stable Zirconium Carbide Fibers Fabricated by Centrifugal Spinning Technique10.15541/jim20200031 ↗
20. Ablation behavior of HfC coating with different thickness for carbon/carbon composites at ultra-high temperature10.1016/j.jeurceramsoc.2020.10.055 ↗
21. Ablation behavior of a novel HfC-SiC gradient coating fabricated by a facile one-step chemical vapor co-deposition10.1016/j.jeurceramsoc.2018.05.034 ↗
22. Fabrication and properties of Cf/Ta4HfC5-SiC composite via precursor infiltration and pyrolysis10.1111/jace.18007 ↗
23. Mechanical behaviour of carbon fibre reinforced TaC/SiC and ZrC/SiC composites up to 2100°C10.1016/j.jeurceramsoc.2018.11.017 ↗
24. Ablation behavior and mechanisms of 3D Cf/ZrB2-SiC composite applied in long-term temperature up to 2400 °C10.1016/j.corsci.2021.109706 ↗
25. Thermodynamic assessment of the ZrO2-LaO1.5 system10.1016/0955-2219(95)00040-2 ↗
26. Silicates of the rare earth elements
27. Long-term ablation behavior and mechanisms of 2D-Cf/ZrB2-SiC composites at temperatures up to 2400 ℃10.1016/j.corsci.2020.108967 ↗
28. Multi-cycle and long-term ablation behavior of Cf/ZrB2-SiC composites at 2500 ℃10.1016/j.corsci.2021.109385 ↗
29. Microstructure and ablation properties of La2O3 modified C/C-SiC composites prepared via precursor infiltration pyrolysis10.1016/j.jeurceramsoc.2018.11.041 ↗
30. The effect of YB4 addition in ZrB2-SiC composites on the mechanical properties and oxidation performance tested up to 2000 °C10.1016/j.jeurceramsoc.2020.03.060 ↗
31. Deposition of SiC/La2Zr2O7 multi-component coating on C/SiC substrate by combining sol-gel process and slurry10.1016/j.surfcoat.2016.05.079 ↗
32. Properties of selected zirconia containing silicate glasses
33. Carbon Carbon composites10.1146/annurev.ms.24.080194.000315 ↗
34. Viscosity and surface tension measurements of RE2O3-MgO-SiO2 (RE=Y, Gd, Nd and La) melts10.2355/isijinternational.46.388 ↗
35. Effect of La2O3 on the viscosity and structure of CaO-SiO2(-Al2O3)-La2O3 melts10.1016/j.matchemphys.2021.124526 ↗