journal article·2021-05

Effect of oxide layer and the duration of exposure on the liquid metal corrosion mechanism of RAFM steel in molten Pb-Li

P. Chakraborty, N. Naveen Kumar, N. Sai Krishna, N.K. Maheshwari, S. Bysakh, A. Bose, V. Kain, R. Tewari

Corrosion Science· Volume 183
Publisher page

Abstract

Abstract The long-term corrosion behavior of IN-RAFM steel in molten Pb-Li upto 10, 000 h of exposure was studied in a rotating disc corrosion test facility at 823 K. As-received IN-RAFMS material possessed an air-formed surface layer containing oxides of Fe, Ce and W. Precipitation of chromium carbides at the grain/lath boundaries of as-received IN-RAFMS led to grain boundary attack by liquid Pb-Li during the initial “Incubation Period” which depicted slow dissolution of surface oxides and lesser corrosion rate. Complete dissolution of oxide layer altered the corrosion mechanism from grain boundary attack to matrix dissolution thereby increasing the corrosion rate.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallurgical Processes and Thermodynamics · Fusion materials and technologies · Aluminum Alloy Microstructure Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Heavy liquid metal coolant - lead - bismuth and lead - technology10.1023/B:ATEN.0000047678.35315.b6 ↗
2. Lead - lithium eutectic material database for nuclear fusion technology10.1016/j.jnucmat.2008.02.016 ↗
3. Heavy liquid metal corrosion of structural materials in advanced nuclear systems10.1007/s11837-013-0663-7 ↗
4. ITER: the first experimental fusion reactor10.1016/0920-3796(94)00403-T ↗
5. Test blanket modules in ITER: an overview on proposed designs and required DEMO-relevant materials10.1016/j.jnucmat.2007.03.234 ↗
6. Overview of liquid metal TBM concepts and programs10.1016/j.fusengdes.2008.06.040 ↗
7. Overview of TBM R&D activities in India10.1016/j.fusengdes.2011.12.014 ↗
8. Fontana · 1986
9. Fundamentals of liquid metal corrosion10.5006/0010-9312-12.7.46 ↗
10. Liquid metal corrosion10.5006/0010-9312-9.3.78 ↗
11. Draley · 1970
12. Ferritic / martensitic steels: promises and problems
13. Ferritic/martensitic steels for advanced nuclear reactors10.1007/s12666-009-0011-3 ↗
14. On the potentiality of using ferritic/martensitic steels as structural materials for fusion reactors10.1088/0029-5515/44/1/006 ↗
15. Development and characterization of advanced 9Cr ferritic/martensitic steels for fission and fusion reactors10.1016/j.jnucmat.2010.09.022 ↗
16. Development of India-specific RAFM steel through optimization of tungsten and tantalum contents for better combination of impact, tensile, low cycle fatigue and creep properties10.1016/j.jnucmat.2013.03.073 ↗
17. Low-activation ferritic and martensitic steels for fusion application10.1016/S0022-3115(96)00327-3 ↗
18. Effect of thermal aging on microstructure and mechanical properties of china low-activation martensitic steel at 550 °C10.1016/j.net.2015.11.004 ↗
19. The development of EUROFER reduced activation steel10.1016/S0920-3796(03)00337-5 ↗
20. Recent progress of R&D activities on reduced activation ferritic/martensitic steels10.1016/j.jnucmat.2012.12.039 ↗
21. Corrosion behavior of EUROFER steel in flowing eutectic Pb–17Li alloy10.1016/j.jnucmat.2004.04.302 ↗
22. Corrosion analysis of CLAM steel in flowing liquid LiPb at 480°C10.1016/j.fusengdes.2010.06.021 ↗
23. Corrosion of ferritic-martensitic steels in the eutectic Pb-17Li10.1016/S0022-3115(00)00322-6 ↗
24. In-situ Raman and X-ray photoelectron spectroscopic studies on the pitting corrosion of modified 9Cr-1Mo steel in neutral chloride solution10.1016/j.apsusc.2017.09.179 ↗
25. Corrosion and mechanical properties of the martensitic steel X18CrMoVNb121 in flowing Pb-17Li10.1016/0920-3796(91)90016-J ↗
26. Compatibility of reduced activation ferritic martensitic steel JLF-1 with liquid metals Li and Pb–17Li10.1016/j.fusengdes.2011.12.013 ↗
27. Short-term corrosion behavior of Indian RAFM steel in liquid Pb-Li: Corrosion mechanism and effect of alloying elements10.1016/j.jnucmat.2019.04.018 ↗
28. Corrosion of Indian RAFMS in Pb-17Li in a rotating disc corrosion test facility at 773K10.1016/j.fusengdes.2015.05.053 ↗
29. Corrosion of an India produced RAFM steel in flowing lead-lithium eutectic10.1016/j.fusengdes.2017.08.010 ↗
30. MHD technology for the production of Pb-Li eutectic alloys
31. Results of corrosion test of EUROFER 97 in lead-lithium alloy
32. Compatibility behavior of EUROFER steel in flowing Pb–17Li10.1016/j.jnucmat.2008.12.271 ↗
33. Mass transfer of RAFM steel in Li by simple immersion, impeller induced flow and thermal convection10.1016/j.jnucmat.2011.01.096 ↗
34. Influence of tempering treatment on microstructure and pitting corrosion of 13 wt.% Cr martensitic stainless steel10.1016/j.corsci.2017.12.012 ↗
35. Krauss · 2007
36. Flow rate dependent corrosion behavior of Eurofer steel in Pb–15.7Li10.1016/j.jnucmat.2010.12.277 ↗
37. The effect of temperature and oxygen content on the flowing liquid metal corrosion of structural steels in the Pb–Bi eutectic10.1016/j.nucengdes.2006.02.003 ↗
38. The minerals, metals, and materials society
39. Corrosion behavior of IN-RAFM steel with stagnant lead-lithium at 550 °C up to 9000 h10.1016/j.fusengdes.2018.07.015 ↗
40. Investigation on models to predict the corrosion of steels in flowing liquid lead alloys10.1016/S0022-3115(01)00431-7 ↗
41. Effect of magnetic field on the corrosion behavior of Indian RAFMS in liquid Pb-Li10.1088/1741-4326/ab388c ↗
42. Investigation on models to predict the corrosion of steels in flowing liquid lead alloys10.1016/S0022-3115(01)00431-7 ↗
43. Correlation between the energy and structure of grain boundaries in b.c.c. metals. II. Symmetrical tilt boundaries10.1080/01418619008244790 ↗
44. Temperature dependence of austenite nucleation behavior from lath martensite10.2355/isijinternational.51.299 ↗
45. Compatibility of low activation ferritic steels with liquid lithium10.13182/FST07-A1555 ↗
46. Effect of chemical potential of carbon on phase transformation and corrosionof JLF-1 steel in a static lithium10.1016/j.jnucmat.2009.08.005 ↗
47. Liquid breeder materials10.1016/0022-3115(88)90239-5 ↗
48. Mechanical and corrosion behavior of EUROFER 97 steel exposed to Pb–17Li10.1016/S0022-3115(02)00990-X ↗