Carbon depositions within the oxide scale and its effect on the oxidation behavior of low alloy steel in low (0.1 MPa), sub-(5 MPa) and supercritical (10 MPa) CO2 at 550°C
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Abstract
Abstract The oxidation behavior of CrMoV steel in 0.1, 5, and 10 MPa CO2 was studied at 550 °C for 500 h. Reaction rates decreased from 0.1–5 MPa, and breakaway occurred sooner with increasing pressure. Amorphous carbon was identified within the inner layer in all CO2 pressure values, while graphite was mainly detected under 5 and 10 MPa. Carbon deposition may link to the formation of Fe- and (Fe, Ni)-rich M3C carbides at the oxide/steel interface, which catalyzed the Boudouard reaction. A high external CO2 pressure and the oxidation of Cr-rich carbides within the steel may favor carbon depositions.
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Research context
OpenAlex topics: High-Temperature Coating Behaviors · Diamond and Carbon-based Materials Research · Advanced materials and composites
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References (100+)
Show source-provided references
1. A review of thermodynamic cycles and working fluids for the conversion of low-grade heat10.1016/j.rser.2010.07.006 ↗
2. The supercritical carbon dioxide power cycle: comparison to other advanced power cycles10.13182/NT06-A3734 ↗
3. Supercritical CO2 Brayton cycles for solar-thermal energy10.1016/j.apenergy.2013.06.020 ↗
4. Brun · 2017
5. Effect of CO2 gas pressure on composition, growth rate, and structure of duplex oxide formed on 9Cr steel at 550 °C10.1016/j.corsci.2019.108252 ↗
6. Corrosion behaviors of four stainless steels with similar chromium content in supercritical carbon dioxide environment at 650 °C10.1016/j.corsci.2019.04.043 ↗
7. Corrosion and carburization behavior of heat-resistant steels in a high-temperature supercritical carbon dioxide environment10.1007/s11085-019-09917-x ↗
8. Corrosion and carburization behavior of chromia-forming heat resistant alloys in a high-temperature supercritical-carbon dioxide environment10.1016/j.corsci.2015.07.007 ↗
9. Effect of pressure on the corrosion and carburization behavior of chromia-forming heat-resistant alloys in high-temperature carbon dioxide environments10.1016/j.corsci.2016.06.004 ↗
10. Oxidation behavior and lifetime prediction of three commercial alloys used in power plants at 550 °C in CO2 environment10.1007/s42243-019-00232-y ↗
11. Corrosion of austenitic and ferritic-martensitic steels exposed to supercritical carbon dioxide10.1016/j.corsci.2011.06.002 ↗
12. Coordination of pre-oxidation time and temperature for a better corrosion resistance to CO2 at 550 °C10.1007/s11085-019-09901-5 ↗
13. Pre-oxidation effect on oxidation behavior of F91 in Carbon Dioxide at 550 °C10.1007/s11085-018-9850-9 ↗
14. Effect of surface finish on high-temperature oxidation of steels in CO2, supercritical CO2, and air10.1007/s11085-019-09938-6 ↗
15. Draycott · 1962 · 1
16. 4.14 - materials performance in CO2 and supercritical CO2
17. Wright · 2013
18. Ferrite morphologies and carbide precipitation in a Cr-Mo-V creep-resisting steel10.1179/030634576790431976 ↗
19. Microstructure and mechanical properties of CrMoV steel after long-term service10.1515/amm-2016-0014 ↗
20. Precipitation of carbides in Cr – Mo – V cast steel after service and regenerative heat treatment
21. Carbide transformation behaviors of a Cr–Mo–V secondary hardening steel during over-ageing10.1088/2053-1591/ab7c86 ↗
22. Relationship between microstructure and mechanical properties of a 5% Cr tempered martensitic tool steel10.1016/j.msea.2004.02.073 ↗
23. Carbide transformations in Cr-Mo steels during long-term ageing and operation
24. Carbide reactions and phase equilibria in low alloy Cr–Mo–V steels tempered at 773–993 K. Part I: experimental measurements10.1016/S1359-6454(97)00238-3 ↗
25. Evolution behavior of carbides in 2.25Cr-1Mo-0.25V steel10.2320/matertrans.M2009172 ↗
26. Precipitation of multiple carbides in martensitic CrMoV steels - experimental analysis and exploration of alloying strategy through thermodynamic calculations10.1016/j.mtla.2020.100630 ↗
27. Effect of tempering on development of carbide particles in 2.7Cr-0.6Mo-0.3V steel10.1007/BF01165937 ↗
28. Microstructure and mechanical properties of Cr-Mo steels for nuclear industry applications
29. Effect of alloy composition and exposure conditions on the selective oxidation behavior of ferritic Fe–Cr and Fe–Cr–X alloys10.1007/s11085-010-9215-5 ↗
30. High temperature oxidation of Cr–Mo–V tool steel in carbon dioxide10.1007/s10973-013-2947-0 ↗
31. High-temperature oxidation of commercial alloys in supercritical CO2 and related power cycle environments10.1007/s11837-018-2952-7 ↗
32. The growth and structure of oxide films formed on Fe in O2 and CO2 at 550°C10.1007/BF00612135 ↗
33. Corrosion of 9Cr steel in CO2 at intermediate temperature I: mechanism of void-induced duplex oxide formation10.1007/s11085-011-9271-5 ↗
34. Kinetics of duplex oxide growth on 9Cr steels exposed in CO2: application of dimensional metrology10.1007/s11085-017-9766-9 ↗
35. Chapter 9 corrosion by carbon10.1016/S1875-9491(08)00009-4 ↗
36. Oxidation of mild and low-alloy steels in CO2 based atmospheres10.1016/S0010-938X(68)80103-9 ↗
37. A model for mild steel oxidation in CO210.1007/BF00610578 ↗
38. Chapter 7 alloy oxidation III: multiphase scales10.1016/S1875-9491(08)00007-0 ↗
39. The role of metal vacancies during high-temperature oxidation of alloys10.1038/s41529-018-0046-1 ↗
40. Transport processes during the growth of oxide films at elevated temperature10.1103/RevModPhys.57.437 ↗
41. Enhanced oxidation of the 9%Cr steel P91 in water vapour containing environments10.1016/j.corsci.2006.02.002 ↗
42. Scale growth on steels at 1200°C: rationale of rate and morphology10.1179/msc.1984.18.3.127 ↗
43. Oxidation of Fe-C alloys at 700°C10.1007/BF00603670 ↗
44. The observation of stress effects during the high temperature oxidation of iron10.1007/BF00540812 ↗
45. The oxidation of iron-carbon alloys at 500°C10.1149/1.2411889 ↗
46. Oxidation of rimming steels in carbon dioxide atmospheres*10.1179/000705969798325479 ↗
47. The influence of metal lattice vacancies on the oxidation of high temperature materials10.1016/0010-938X(77)90004-X ↗
48. Scale stresses during protective and breakaway corrosion of iron and rimming steel in CO210.1007/BF00610579 ↗
49. The mechanisms of breakaway oxidation of three mild steels in high-pressure CO2 at 500°C10.1007/BF00613232 ↗
50. The application of thermodynamics to the oxidation behavior of mild steels in carbon dioxide-based atmospheres10.1007/BF00603748 ↗
51. Influence of CO2 purity on the oxidation of a 12Cr ferritic – martensitic steel at 550°C and importance of the initial stage10.3184/096034012X13323581167078 ↗
52. Sridharan · 2013
53. Effect of pressure and impurities on oxidation in supercritical CO210.1002/maco.201810652 ↗
54. Corrosion of austenitic alloys in high temperature supercritical carbon dioxide10.1016/j.corsci.2012.03.029 ↗
55. Corrosion behavior of FBR structural materials in high temperature supercritical carbon dioxide10.1299/jpes.4.252 ↗
56. Corrosion behavior of different metallic materials in supercritical carbon dioxide at 550°C and 250 bars10.5006/1.3628683 ↗
57. Kubaschewski · 1993
58. Young · 2016
59. High-temperature oxidation behavior of CrMoV, F91 and Mar-M247 superalloys exposed to laboratory air at 550 °C10.1007/s11085-018-9839-4 ↗
60. Infrared- and raman-active phonons of magnetite, maghemite, and hematite: a computer simulation and spectroscopic study10.1021/jp048748h ↗
61. Composition, structure and properties of the oxide films formed on the stainless steel 316L in a primary type PWR environment10.1016/S0010-938X(97)00158-3 ↗
62. A Raman study of the systems Fe3−xCrxO4 and Fe2−xCrxO310.1016/0022-4596(89)90245-4 ↗
63. First- and second-order Raman scattering from finite-size crystals of graphite10.1103/PhysRevB.20.392 ↗
64. Raman spectroscopy of thin corrosion films on Iron at 100 to 150 C in air10.5006/1.3583054 ↗
65. Laser Raman spectroscopy: a technique for rapid characterisation of oxide scale layers10.1179/mst.1998.14.5.373 ↗
66. Influence of water vapor on oxide scale morphology of Incoloy800HT at 850°C10.4028/www.scientific.net/AMM.875.36 ↗
67. In-situ Raman spectroscopy combined with X-Ray photoelectron spectroscopy and nuclear microanalysis for studies of anodic corrosion film formation on Fe-Cr single crystals10.1149/1.2095605 ↗
68. Raman Spectrum of graphite10.1063/1.1674108 ↗
69. Temperature-dependent light-scattering studies of the Verwey transition and electronic disorder in magnetite10.1103/PhysRevB.9.5236 ↗
70. New lines in the Raman spectra of carbons and graphite10.1111/j.1151-2916.1978.tb09219.x ↗
71. Effect of cyclic reaction on corrosion behavior of chromium-containing alloys in CO2 gas at 650 °C10.1007/s11085-019-09950-w ↗
72. Investigation of metal-dusting mechanism in Fe-Base alloys using raman spectroscopy, X-Ray diffraction, and Electron microscopy10.1023/A:1016068625429 ↗
73. Lattice dynamics and vibrational spectra of Lithium manganese oxides: a computer simulation and spectroscopic study10.1021/jp984398l ↗
74. The characterization by Raman spectroscopy of oxide scales formed on a 20Cr□25Ni□Nb stabilized stainless steel10.1016/0010-938X(86)90021-1 ↗
75. Infrared and Raman studies of the Verwey transition in magnetite10.1103/PhysRevB.62.7939 ↗
76. The transformation of lepidocrocite during heating: a magnetic and spectroscopic study10.1346/CCMN.1994.0420405 ↗
77. A study of breakaway oxidation of 9Cr–1Mo steel in a Hot CO2 atmosphere using Raman spectroscopy10.1080/09603409.2017.1389424 ↗
78. Effects of hydrogen peroxide on corrosion of stainless steel, (V) characterization of oxide film with multilateral surface analyses10.1080/18811248.2006.9711173 ↗
79. Transient oxidation in Fe-Cr-Ni alloys: a Raman-scattering study10.1007/BF01048636 ↗
80. Raman Spectra of possible corrosion products of Iron10.1366/000370278774330739 ↗
81. Structure of rust on weathering steel in rural and industrial environments10.5006/1.3294356 ↗
82. Thermo-Calc & DICTRA, computational tools for materials science10.1016/S0364-5916(02)00037-8 ↗
83. Caburisation of heat-resistant steels10.1002/(SICI)1521-4176(199804)49:4<231::AID-MACO231>3.0.CO;2-T ↗
84. The C-Fe (carbon-iron) system10.1007/BF02665767 ↗
85. Point defect model for the corrosion of steels in supercritical water: part I, film growth kinetics10.1016/j.corsci.2019.108280 ↗
86. Predictions and analyses on the growth behavior of oxide scales formed on ferritic–martensitic in supercritical water10.1007/s11085-019-09912-2 ↗
87. Anomalous temperature dependence of oxidation kinetics during steam oxidation of ferritic steels in the temperature range 550–650 °C10.1016/j.corsci.2004.01.010 ↗
88. The oxidation behaviour of the 9 % Cr steel P92in CO2- and H2O-rich gases relevant to oxyfuel environments10.3139/146.110271 ↗
89. Dispersion of complex carbides at the oxidation front during the oxidation of 9Cr-1Mo steel10.1016/j.corsci.2019.108389 ↗
90. High temperature oxidation of low alloy steels10.1007/BF00660927 ↗
91. The oxidation of FeNi alloys10.1016/S0010-938X(69)80100-9 ↗
92. BIRKS · 2006
93. Comparative study on high temperature oxidation of T92 steel in dry and wet oxyfuel environments10.1007/s11085-015-9565-0 ↗
94. Impact of oxyfuel atmospheres H2O/CO2/O2 and H2O/CO2 on the oxidation of ferritic–martensitic and austenitic steels10.1016/j.corsci.2011.03.015 ↗
95. Equilibria in the Systems Fe2C—Fe—CH4—H2 and Fe3C—Fe—CH4—H2110.1021/ja01165a108 ↗
96. Thermodynamics of Cr2O3, FeCr2O4, ZnCr2O4, and CoCr2O410.1016/j.jct.2007.03.001 ↗
97. Modelling carburisation in 9Cr-1Mo ferritic steel tube substrates in experimental CO2 atmospheres10.1016/j.corsci.2019.108248 ↗
98. Oxidation of Fe-C alloys at 500°C10.1007/BF00609975 ↗
99. High-temperature oxidation of transition metal, carbide-dispersed iron-base alloys10.1007/BF00657060 ↗
100. Corrosion of iron-, nickel-, and cobalt-base alloys in atmospheres containing carbon and oxygen10.1007/BF00738385 ↗