Tribocorrosion and corrosion behavior of double borided layers formed on Ti-6Al-4V alloy: An approach for applications to bio-implants
Source abstract
Abstract
TiB 2 and TiB double layers were formed on surface of Ti-6Al-4V by a diffusional process at 850 ͦ C for 4–16 h. EIS and XPS analyses revealed that formation of a passive film on the coated samples in a PBS solution increased corrosion resistance of Ti-6Al-4V. Tribocorrosion rate of the borided samples decreased up to 40 times compared with Ti-6Al-4V under a reciprocating condition and normal loads of 0.5–15 N against an alumina ball. The presence of B 2O 3/H 3BO 3 tribofilm on the borided samples led to a lower coefficient of friction and a more stable fluctuation of OCP.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal and Thin Film Mechanics · Orthopaedic implants and arthroplasty · Advanced materials and composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (69)
Show source-provided references
1. Tribocorrosion of passive metals in the mixed lubrication regime: theoretical model and application to metal-on-metal artificial hip joints10.1016/j.wear.2014.12.003 ↗
2. Metallic implant biomaterials10.1016/j.mser.2014.10.001 ↗
3. Chemo-mechanical effects on the tribocorrosion behavior of titanium/ceramic dental implant pairs in artificial saliva10.1016/j.wear.2018.12.052 ↗
4. D. Landolt, S. Mischler, Tribocorrosion of passive metals and coatings, 2011. doi:10.1533/9780857093738.10.1533/9780857093738 ↗
5. S. Mischler, A.I. Muñoz, Wear of CoCrMo alloys used in metal-on-metal hip joints: a tribocorrosion appraisal, 2013. doi:10.1016/j.wear.2012.11.061.10.1016/j.wear.2012.11.061 ↗
6. Enhancement of wear and corrosion resistance of beta titanium alloy by laser gas alloying with nitrogen10.1016/j.apsusc.2016.01.091 ↗
7. Triboelectrochemical investigation of the friction and wear behaviour of TiN coatings in a neutral solution10.1016/S0301-679X(01)00052-4 ↗
8. Biotribological properties of Ti/TiB2 multilayers in simulated body solution10.1016/j.triboint.2015.02.004 ↗
9. Interplay between mechanical wear and electrochemical corrosion during tribocorrosion of oxygen diffusion layer on Ti–6Al–4V in PBS solution10.1016/j.apsusc.2020.146048 ↗
10. Microstructure and properties of laser-borided composite layers formed on commercially pure titanium10.1016/j.optlastec.2013.09.022 ↗
11. Electrochemical properties of commercially pure Ti with TiB/TiB 2 coatings in Hanks’ balanced salt solution10.1007/s11665-019-03930-6 ↗
12. Corrosion resistance of Ti-6Al-4V alloy with nitride coatings in Ringer’s solution10.1016/j.corsci.2012.10.005 ↗
13. Bio-corrosion behaviour of oxygen diffusion layer on Ti-6Al-4V during tribocorrosion10.1016/j.corsci.2017.08.031 ↗
14. Response of boride coating on the Ti-6Al-4V alloy to corrosion and fretting corrosion behavior in Ringer’s solution for bio-implant application10.1016/j.apsusc.2017.09.223 ↗
15. Effect of surface nanocrystallization on the corrosion behavior of Ti-6Al-4V titanium alloy10.1016/j.surfcoat.2013.02.052 ↗
16. Effect of surface nanostructuring on corrosion behavior of Ti–6Al–4V alloy10.1016/j.matchar.2016.09.031 ↗
17. Corrosion behavior of TiN and TiN/Ti composite films on Ti6Al4V alloy in Hank’s solution10.1007/s10800-008-9690-4 ↗
18. Enhancing biocompatibility and corrosion resistance of Ti-6Al-4V alloy by surface modification route10.1007/s11666-018-0746-7 ↗
19. Tribology of titanium boride-coated titanium balls against alumina ceramic: wear, friction, and micromechanisms10.1016/j.wear.2007.11.011 ↗
20. Anisotropic elastic and thermal properties of titanium borides by first-principles calculations10.1016/j.jallcom.2013.06.119 ↗
21. Fretting corrosion response of boride coated titanium in Ringer’s solution for bio-implant use: elucidation of degradation mechanism10.1016/j.triboint.2018.06.013 ↗
22. Plasma-assisted boriding of pure titanium and TiA16V410.1016/S0257-8972(01)01244-0 ↗
23. Fundamental properties and wear resistance of r.f.-sputtered TiB2 and Ti(B,N) coatings10.1016/0921-5093(91)90486-7 ↗
24. In vitro biocompatibility of titanium after plasma surface alloying with boron10.1016/j.msec.2016.08.006 ↗
25. Boriding titanium alloys at lower temperatures using electrochemical methods10.1016/j.tsf.2007.01.020 ↗
26. TiB whisker coating on titanium surfaces by solid-state diffusion: synthesis, microstructure, and mechanical properties10.1007/s11661-002-0336-6 ↗
27. Nature of growth of dual titanium boride layers with nanostructured titanium boride whiskers on the surface of titanium10.1016/j.scriptamat.2007.03.050 ↗
28. Characteristics, wear and corrosion properties of borided pure titanium by pack boriding near α → β phase transition temperature10.1016/j.ceramint.2020.03.197 ↗
29. Kinetics of growth of superhard boride layers during solid state diffusion of boron into titanium10.1016/j.ceramint.2012.05.077 ↗
30. Microstructure, growth kinetics and some mechanical properties of boride layers produced on pure titanium by molten-salt boriding10.1007/s11665-017-2884-3 ↗
31. Characteristics and growth kinetics of plasma paste borided Cp-Ti and Ti6Al4V alloy10.1016/j.surfcoat.2015.08.023 ↗
32. Surface treatments for boriding of Ti6Al4V alloy in view of applications as a biomaterial10.1016/j.triboint.2018.05.006 ↗
33. Accelerated kinetics of surface hardening by diffusion near phase transition temperature: mechanism of growth of boride layers on titanium10.1016/j.actamat.2011.03.046 ↗
34. Boriding behaviour of titanium alloys with different crystalline structures10.1080/02670844.2018.1552646 ↗
35. Low friction behaviour of boron carbide coatings (B4C) sliding against Ti–6Al–4V10.1016/j.surfcoat.2016.05.092 ↗
36. Evolution of microstructure and phases in in situ processed Ti-TiB composites containing high volume fractions of TiB whiskers10.1557/JMR.1999.0571 ↗
37. ASTM F2129–15, Testing, standard test method for conducting cyclic potentiodynamic polarization measurements to determine the corrosion susceptibility of, 2015. doi:〈10.1520/F2129–17.Copyright〉.
38. Surface evolution and growth kinetics of Ti6Al4V alloy in pack boriding10.1016/j.jallcom.2018.01.383 ↗
39. Electrochemical techniques in corrosion science and engineering
40. Triboelectrochemical techniques and interpretation methods in tribocorrosion: a comparative evaluation10.1016/j.triboint.2007.11.003 ↗
41. , In situ impedance spectroscopy study of the electrochemical corrosion of Ti and Ti-6Al-4V in simulated body fluid at 25 °C and 37 °C10.1016/j.corsci.2009.06.035 ↗
42. Study of the corrosion behavior of titanium and some of its alloys for biomedical and dental implant applications10.1016/S0022-0728(99)00260-0 ↗
43. Corrosion behavior of titanium boride composite coating fabricated on commercially pure titanium in Ringer’s solution for bioimplant applications10.1016/j.msec.2014.12.002 ↗
44. K.R. Trethewey, J. Chamberlain, Corrosion for students of science and engineering, 1988.
45. The role of an in-situ grown Zn-Al layered double hydroxide conversion coating in the protective properties of epoxy coating on galvanized steel10.1149/1945-7111/ac5d95 ↗
46. Corrosion characterization of titanium alloys by electrochemical techniques10.1016/j.electacta.2005.02.121 ↗
47. Tribocorrosion properties of different type titanium alloys in simulated body fluid10.1016/j.wear.2014.12.017 ↗
48. The effects of microstructures and repassivation kinetics on the tribocorrosion resistance of ferrite and ferrite-martensite stainless steels10.1016/j.wear.2018.10.023 ↗
49. Effects of bovine serum albumin on the corrosion behaviour of AISI 316L, Co-28Cr-6Mo, and Ti-6Al-4V alloys in phosphate buffered saline solutions10.1016/j.corsci.2011.06.009 ↗
50. H. Herrera Hernández, A.M. Ruiz Reynoso, J.C. Trinidad González, C.O. González Morán, J.G. Miranda Hernández, A. Mandujano Ruiz, J. Morales Hernández, R. Orozco Cruz, Electrochemical Impedance Spectroscopy (EIS): A Review Study of Basic Aspects of the Corrosion Mechanism Applied to Steels, 2020. doi:10.5772/intechopen.94470.10.5772/intechopen.94470 ↗
51. CPE analysis by local electrochemical impedance spectroscopy10.1016/j.electacta.2005.02.128 ↗
52. An electrochemical impedance spectroscopy and polarization study of the role of crystallographic orientation on electrochemical behavior of niobium10.1016/j.electacta.2013.12.085 ↗
53. Corrosion and tribocorrosion behavior of equiatomic refractory medium entropy TiZr(Hf, Ta, Nb) alloys in chloride solutions10.1016/j.corsci.2022.110166 ↗
54. Anomalous enhancement of corrosion resistance and antibacterial property of commercially pure Titanium (CP-Ti) with nanoscale rutile titania film10.1016/j.corsci.2020.108678 ↗
55. Formation of TiB2 coatings at room temperature by dynamic ion mixing10.1016/S0257-8972(95)02752-1 ↗
56. Surface modification of titanium with phosphonic acid to improve bone bonding: Characterization by XPS and ToF-SIMS10.1021/la010908i ↗
57. Chastain · 1992
58. Characteristics of passive films formed on As-Cast Ti–6Al-4V in Hank’s solution before and after transpassivation10.3389/fmats.2020.640081 ↗
59. Uhlig · 2008
60. XPS and EIS studies to account for the passive behavior of the alloy Ti-6Al-4V in Hank’s solution10.1007/s10008-019-04368-5 ↗
61. Characterization of surface film formed on titanium in electrolyte using XPS10.1016/0169-4332(92)90178-Z ↗
62. ARXPS and high energy XPS characterisation of titanium surfaces for medical implants10.1002/sia.2778 ↗
63. Difference in surface reactions between titanium and zirconium in Hanks’ solution to elucidate mechanism of calcium phosphate formation on titanium using XPS and cathodic polarization10.1016/j.msec.2009.01.016 ↗
64. XPS, AES and SEM analysis of recent dental implants10.1016/j.actbio.2009.01.049 ↗
65. In-vitro corrosion and wear of titanium alloys in the biological environment10.1016/0142-9612(96)00029-4 ↗
66. Tribocorrosion behaviour of Ti6Al4V under various normal loads in phosphate buffered saline solution10.1016/S1003-6326(20)65297-9 ↗
67. Local electrochemical studies and surface analysis on worn surfaces10.1149/1.2830954 ↗
68. Superhard NbB2-x thin films deposited by dc magnetron sputtering10.1016/j.surfcoat.2014.07.087 ↗
69. Bhushan · 2001