journal article·2021-07

An approach to improve the oxidation resistance of a Ni-28W-6Cr alloy by hindering the oxygen vacancy-mediated oxidation

Shulin Liu, Xiang-Xi Ye, Chen Ming, Shuai Yan, Li Jiang, Zhijun Li, Xingtai Zhou

Corrosion Science· Volume 187
Publisher page

Abstract

Abstract In this work, an approach to improve the oxidation resistance of a Ni-based alloy was proposed by doping a high valence metal element into the oxides. Oxidation kinetics of Ni-28W-6Cr alloys with 0−0.2 wt.% Zr at 850 °C show that Zr can significantly decrease the oxidation rate of the alloy and the thickness of the inner oxide. Zr charged +4 prefers to segregate in the inner NiWO4 by replacing Ni2+, which inhibits the formation of oxygen vacancies and reduces the oxygen diffusion pathways, improving the oxidation resistance of the alloy.
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Research context

OpenAlex topics: High-Temperature Coating Behaviors · Catalytic Processes in Materials Science · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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