journal article·2016-11Open access

Grain orientation dependent Nb–Ti microalloying mediated surface segregation on ferritic stainless steel

Harri Ali-Löytty, Markku Hannula, Mari Honkanen, Kauko Östman, Kimmo Lahtonen, Mika Valden

Corrosion Science· Volume 112

Abstract

Abstract Surface segregation and oxide formation anisotropy on Ti–Nb stabilized ferritic stainless steel (EN 1.4521) were studied by XPS and Electron Backscatter Diffraction. Competitive surface segregation of Si, Nb and Ti was initiated at ∼550 °C, and segregation was favored to the open surface sites of 〈111〉 oriented grains. Furthermore, the surface segregation of Cr was strongly limited at the locations of stable Ti(CN)- and (NbTi)C-type precipitates. Consequently, the oxidation resistance of stainless steels can be enhanced cost-efficiently, without alloy additions, by optimizing the microstructure to facilitate the fast and uniform growth of protective oxide scale.
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Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · High-Temperature Coating Behaviors · Metal and Thin Film Mechanics

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