journal article·2015-11

Vegetable oil-based polybenzoxazine derivatives coatings on Zn–Mg–Al alloy coated steel

Matei Raicopol, Brindusa Bălănucă, Kirill Sliozberg, Bert Schlüter, Sorina Alexandra Gârea, Nicoleta Chira, Wolfgang Schuhmann, Corina Andronescu

Corrosion Science· Volume 100
Publisher page

Abstract

Abstract Based on environmentally friendly (bio-based) precursor materials a new class of benzoxazine derivatives was synthesized using phenolated high oleic sunflower oil as phenol component and either aniline or 1,6-diaminohexane as amine components. Hydrophobic and dense poly(benzoxazine) coatings on Zn–Mg-Al alloy coated steel were obtained after spin-coating or air-brush type spray coating by crosslinking during a heat treatment step. The poly(benzoxazine)-coated ZM-steel samples showed an anodic shift of the open circuit potential as well as the break-through potential. Using an automatic scanning droplet cell the impact of the polymer film thickness on corrosion protection was evaluated.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Epoxy Resin Curing Processes · Injection Molding Process and Properties · Nanofabrication and Lithography Techniques

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References (24)

Show source-provided references
1. Polybenzoxazines - New high performance thermosetting resins: synthesis and properties10.1016/j.progpolymsci.2007.07.002 ↗
2. Physical and mechanical characterization of near-zero shrinkage polybenzoxazines10.1002/(SICI)1099-0488(19960430)34:6<1019::AID-POLB1>3.0.CO;2-T ↗
3. Corrosion resistance of novel silane-functional polybenzoxazine coating on steel10.1016/j.corsci.2013.01.023 ↗
4. Polybenzoxazine/SIO2 nanocomposite coatings for corrosion protection of mild steel10.1016/j.corsci.2013.11.042 ↗
5. Hydrophobic benzoxazine-cured epoxy coatings for corrosion protection10.1016/j.porgcoat.2013.03.013 ↗
6. Reaction mechanism and synergistic anticorrosion property of reactive blends of maleimide-containing benzoxazine and amine-capped aniline trimer10.1039/C4PY00274A ↗
7. Thermal curing study of bisphenol A benzoxazine for barrier coating applications on 1050 aluminium alloy10.1016/j.porgcoat.2014.11.004 ↗
8. A renewable approach to thermosetting resins10.1016/j.reactfunctpolym.2012.03.015 ↗
9. Plant oils: the perfect renewable resource for polymer science?!10.1016/j.eurpolymj.2010.11.020 ↗
10. Biological oils as precursors to novel polymeric materials10.7569/JRM.2013.634112 ↗
11. Thermally curable benzoxazine-modified vegetable oil as a coating material10.1007/s11998-013-9472-8 ↗
12. Preparation of oil-modified polycaprolactone and its further modification with benzoxazine for coating purposes10.1016/j.porgcoat.2012.08.022 ↗
13. Composite polymer-containing protective coatings on magnesium alloy MA810.1016/j.corsci.2014.03.035 ↗
14. A corrosion-protective coating based on a solution-processable polymer-grafted graphene oxide nanocomposite10.1016/j.corsci.2015.05.056 ↗
15. Conducting polymers for corrosion protection: A review10.1007/s11998-014-9586-7 ↗
16. Microstructural characterization and quantification of Zn–Al–Mg surface coatings10.1016/j.matchar.2010.06.008 ↗
17. Understanding corrosion via corrosion product characterization: II. Role of alloying elements in improving the corrosion resistance of Zn–Al–Mg coatings on steel10.1016/j.corsci.2011.03.016 ↗
18. Corrosion resistance of zinc-magnesium coated steel10.1016/j.corsci.2007.03.032 ↗
19. Phenolic materials via ring-opening polymerization: synthesis and characterization of bisphenol-A based benzoxazines and their polymers10.1002/pola.1994.080320614 ↗
20. Phenolated oleic acid based polybenzoxazine derivatives as corrosion protection layers10.1002/cplu.201500092 ↗
21. Phenolation of vegetable oils10.2298/JSC100820050I ↗
22. High-throughput characterization of Pt supported on this film oxide material libraries applied in the oxygen reduction reaction10.1021/ac102303u ↗
23. High-throughput screening of thin-film semiconductor material libraries I: system development and case study for Ti-W-O10.1002/cssc.201402917 ↗
24. Hybrid nanocomposites based on POSS and networks of methacrylated camelina oil and various PEG derivatives10.1002/ejlt.201300370 ↗