Diverse oxidation behaviors of metal carbide solutions in high-temperature water vapor
Source abstract
Abstract
Abstract Carbide solid solutions show diverse oxidation behaviors at 1000–1400 °C in water vapor. (Ti,Nb,Ta,Hf,Zr)C and (Ti,Nb,Ta,Hf)C exhibit parabolic or near-parabolic oxidation kinetics, while the oxidations of (Ti,Nb,Ta) and (Ti,Nb)C are mainly controlled by linear oxidation kinetics. The oxidation kinetics of (Ti,Nb,Ta,Hf,Zr)C shows a tendency of transition from parabolic to linear oxidation rate law with increasing temperature. On the contrary, a tendency of transition from linear to parabolic rate law with increasing temperature was observed in (Ti,Nb)C, which exhibits the highest oxidation resistance at investigated temperatures. The presence of dense Nb-doped TiO2 oxidation layer is responsible for the high oxidation resistance.
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Research context
OpenAlex topics: Advanced materials and composites · MXene and MAX Phase Materials · Metal and Thin Film Mechanics
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References (46)
Show source-provided references
1. Ultra-high temperature ceramics: materials for extreme environments10.1016/j.scriptamat.2016.10.018 ↗
2. Densification and mechanical properties of TiC by SPS-effects of holding time, sintering temperature and pressure condition10.1016/j.jeurceramsoc.2012.04.017 ↗
3. Radiation effects in carbides: TiC and ZrC versus SiC10.1016/j.nimb.2013.11.046 ↗
4. Properties of zirconium carbide for nuclear fuel applications10.1016/j.jnucmat.2013.05.037 ↗
5. A comparative study of low energy radiation responses of SiC, TiC and ZrC10.1016/j.actamat.2016.03.011 ↗
6. Corrosion kinetics and mechanisms of ZrC1−x ceramics in high temperature water vapor10.1039/C8RA02386G ↗
7. Zirconium carbide oxidation: kinetics and oxygen diffusion through the intermediate layer10.1111/jace.15479 ↗
8. Oxidation of HIPed TiC ceramics in dry O2, wet O2, and H2O atmospheres10.1111/j.1551-2916.2005.00876.x ↗
9. The oxidation of TiC in dry oxygen, wet oxygen, and water vapor10.1023/B:JMSC.0000011514.46932.e2 ↗
10. Oxidation of hafnium carbide and titanium carbide single crystals with the formation of carbon at high temperatures and low oxygen pressures10.1111/j.1151-2916.2000.tb01265.x ↗
11. Comparison of the oxidation behaviour of two dense hot isostatically pressed tantalum carbide (TaC and Ta2C) materials10.1016/S0955-2219(96)00235-X ↗
12. Oxidation kinetics of zirconium carbide at relatively low temperatures10.1111/j.1151-2916.1990.tb06678.x ↗
13. Ultra-high temperature steam corrosion of complex silicates for nuclear applications: a computational study10.1016/j.jnucmat.2013.09.021 ↗
14. High temperature oxidation of fuel cladding candidate materials in steam–hydrogen environments10.1016/j.jnucmat.2013.05.047 ↗
15. Understanding the oxidation behavior of Ta–Hf–C ternary ceramics at high temperature10.1016/j.corsci.2019.108348 ↗
16. Oxidation of spark plasma sintered ZrC-Mo and ZrC-TiC composites10.1016/j.ijrmhm.2017.03.019 ↗
17. Oxidation resistance of tantalum carbide-hafnium carbide solid solutions under the extreme conditions of a plasma jet10.1016/j.ceramint.2017.07.227 ↗
18. High-entropy ceramics10.1038/s41578-019-0170-8 ↗
19. Review of high entropy ceramics: design, synthesis, structure and properties10.1039/C9TA05698J ↗
20. Phase stability and mechanical properties of novel high entropy transition metal carbides10.1016/j.actamat.2018.12.054 ↗
21. Strength of single-phase high-entropy carbide ceramics up to 2300°C10.1111/jace.17443 ↗
22. Strength enhancement and slip behaviour of high-entropy carbide grains during micro-compression10.1038/s41598-019-46614-w ↗
23. Microstructure and mechanical properties of (TiZrNbTaMo)C high-entropy ceramic10.1016/j.jmst.2019.07.056 ↗
24. Microstructures and mechanical properties of high-entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C ceramics with the addition of SiC secondary phase10.1016/j.jeurceramsoc.2019.12.056 ↗
25. Small scale fracture and strength of high-entropy carbide grains during microcantilever bending experiments10.1016/j.jeurceramsoc.2020.04.023 ↗
26. High-temperature oxidation behavior of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics in air10.1111/jace.16725 ↗
27. Oxidation behaviors of (Hf0.25Zr0.25Ta0.25Nb0.25)C and (Hf0.25Zr0.25Ta0.25Nb0.25)C-SiC at 1300–1500 °C10.1016/j.jmst.2020.05.037 ↗
28. Oxidation behavior of (Hf0.2Ta0.2Zr0.2Ti0.2Nb0.2)C-xSiC ceramics at high temperature10.1016/j.ceramint.2020.01.137 ↗
29. The role of multi-elements and interlayer on the oxidation behaviour of (Hf-Ta-Zr-Nb)C high entropy ceramics10.1016/j.corsci.2020.109019 ↗
30. Oxidation resistance of (Hf-Ta-Zr-Nb)C high entropy carbide powders compared with the component monocarbides and binary carbide powders10.1016/j.scriptamat.2020.10.038 ↗
31. Oxidation behavior of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics at 1073–1473 K in air10.1016/j.corsci.2019.04.001 ↗
32. Oxidation behaviours of high-entropy transition metal carbides in 1200 °C water vapor10.1016/j.jallcom.2019.152523 ↗
33. Oxidation behavior of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics at 1073–1473 K in air10.1016/j.corsci.2019.04.001 ↗
34. Oxidation behavior of high-entropy carbide (Hf0.2Ta0.2Zr0.2Ti0.2Nb0.2)C at 1400–1600 °C10.1016/j.ceramint.2020.12.201 ↗
35. Part I: Theoretical predictions of preferential oxidation in refractory high entropy materials10.1016/j.actamat.2020.07.003 ↗
36. Part II: Experimental verification of computationally predicted preferential oxidation in refractory high entropy ultra-high temperature ceramics10.1016/j.actamat.2020.07.004 ↗
37. Compositional effect on mechanical properties of transition-metal carbide solid solutions10.1016/j.ceramint.2021.02.264 ↗
38. Effect of La2O3 addition on long-term oxidation kinetics of ZrB2–SiC and HfB2–SiC ultra-high temperature ceramics10.1016/j.jeurceramsoc.2014.06.004 ↗
39. Oxidation resistance and strength retention of ZrB2–SiC ceramics10.1016/j.jeurceramsoc.2010.01.028 ↗
40. Study of the TiC1−x - TiO2 reactive interface10.1016/j.actamat.2017.12.055 ↗
41. Nb-doped rutile TiO2: a potential anode material for Na-ion battery10.1021/am508670z ↗
42. Insights into the structural and chemical modifications of Nb additive on TiO2 nanoparticles10.1021/cm0351238 ↗
43. Lattice distortion in high-entropy carbide ceramics from first-principles calculations10.1111/jace.17600 ↗
44. (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high‐entropy ceramics with low thermal conductivity10.1111/jace.15779 ↗
45. Investigation on the effect of Nb doping on the oxidation mechanism of Ti3SiC210.1016/j.corsci.2018.05.028 ↗
46. Microstructure and mechanical strength of Ti3AlC2 joints bonded using oxides as interlayer10.1016/j.ceramint.2019.05.282 ↗