journal article·2018-01

Coupling of electrochemical, electrogravimetric and surface analysis techniques to study dithiocarbamate/bronze interactions in chloride media

W. Qafsaoui, A. Et Taouil, M.W. Kendig, H. Cachet, S. Joiret, H. Perrot, H. Takenouti

Corrosion Science· Volume 130
Publisher page

Abstract

Abstract Interaction between ammonium pyrrolidinedithiocarbamate (PDTC) and bronze in 30 g L−1 NaCl was investigated at several concentrations between 0.1 and 10 mM by means of various electrochemical and spectroscopic techniques. Electrochemical measurements revealed a fast adsorption process of PDTC on Cu and Pb and the formation of a thick insulating and protective film with a high surface coverage. At high concentrations, PDTC prevents oxides formation. Surface analyses confirm PDTC adsorption on bronze mainly via interaction between sulphur atoms and Cu sites to form CuI-PDTC complex.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Electrodeposition and Electroless Coatings · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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