journal article·2023-08

Tetrafunctional vinyl polysilsesquioxane and its covalently cross-linked vinyl liquid silicone rubber for resistance to high temperature oxidation combustion and ablative behavior

Xutao Ma, Jun’an Zhang, Xiaoyan Ma, Zongwu Zhang, Shuai Shen, Jian Wang, Shumeng Wang, Peidong Xu, Shishan Yang, Le Wei

Corrosion Science· Volume 221
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Abstract

A novel lightweight tetrafunctional vinyl polysilsesquioxane (TV-DDSQ) was designed and synthesized as a crosslinking-modifier for vinyl liquid silicone rubber (SR) to form a denser cross-linked network structure and introduce a high-temperature resistant cage structure to obtained TV-DDSQ/SR resistance to high temperature oxidation combustion-ablation resistance composites (TV-DDSQ/SR). Compared to SR, 1 phr TV-DDSQ/SR exhibits good resistance to high temperature oxidation combustion (vertical combustion test to UL-94 V0) and excellent ablation properties (21.2 % reduction in linear ablation). The mechanism of ceramization transition of TV-DDSQ/SR under high temperature oxidation combustion and ablation resistance was investigated.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Silicone and Siloxane Chemistry · Flame retardant materials and properties · Energetic Materials and Combustion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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