Surface analysis by gas cluster ion beam XPS and ToF-SIMS tandem MS of 2-mercaptobenzoxazole corrosion inhibitor for brass
Source abstract
Abstract
Abstract This work presents the first study on 2-mercaprobenzoxazole (MBOH) as a corrosion inhibitor for brass in chloride solution. The corrosion inhibition effect was conclusively demonstrated. A detailed surface analysis using gas cluster ion beam (GCIB) and monoatomic Ar+ sputter beams in combination with X-ray photoelectron spectroscopy (XPS) measurements was performed. Furthermore, time-of-flight secondary ion mass spectrometry (ToF-SIMS) tandem MS (MS/MS) was used for large-area imaging, to proof the MBOH-specific peak, and to show the 3D distribution of MBOH, Cu, Zn, and Cl– species at the organics/brass interface by GCIB and C60+ sputtering in combination with ToF-SIMS analysis.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Ion-surface interactions and analysis · Semiconductor materials and devices · Analytical chemistry methods development
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (61)
Show source-provided references
1. Gas cluster ion beams for secondary ion mass spectrometry10.1146/annurev-anchem-061516-045249 ↗
2. Ionization probability in molecular secondary ion mass spectrometry: protonation efficiency of sputtered guanine molecules studied by laser postionization10.1021/acs.jpcc.7b01467 ↗
3. Determining the level and location of functional groups on few-layer graphene and their effect on the mechanical properties of nanocomposites10.1021/acsami.9b22144 ↗
4. Effect of sample preparation techniques upon single cell chemical imaging: a practical comparison between synchrotron radiation based X-ray fluorescence (SR-XRF) and Nanoscopic Secondary Ion Mass Spectrometry (nano-SIMS)10.1016/j.aca.2020.01.054 ↗
5. High-resolution secondary ion mass spectrometry analysis of cell membranes10.1021/acs.analchem.9b04492 ↗
6. Imaging mass spectrometry allows for neuroanatomic-specific detection of gangliosides in the healthy and diseased brain10.1039/C9AN02270H ↗
7. Imaging mass spectrometry to visualise increased acetylcholine in lungs of asthma model mice10.1007/s00216-020-02670-0 ↗
8. Lipid diversity in cells and tissue using imaging SIMS10.1146/annurev-anchem-091619-103512 ↗
9. MALDI imaging mass spectrometry and chemometric tools to discriminate highly similar colorectal cancer tissues10.1016/j.talanta.2019.120455 ↗
10. Mechanisms of lipid preservation in archaeological clay ceramics revealed by mass spectrometry imaging10.1073/pnas.1922445117 ↗
11. Metabolomics with 15N labeling for characterizing missing monoterpene indole alkaloids in plants10.1021/acs.analchem.9b03860 ↗
12. Multimodal, in situ imaging of ex vivo human skin reveals decrease of cholesterol sulfate in the neoepithelium during acute wound healing10.1021/acs.analchem.9b04542 ↗
13. Optimization of a MALDI-Imaging protocol for studying adipose tissue-associated disorders10.1016/j.talanta.2020.121184 ↗
14. Peroxidasin-mediated bromine enrichment of basement membranes10.1073/pnas.2007749117 ↗
15. Recent advances in the mass spectrometric analysis of glycosphingolipidome – a review10.1016/j.aca.2020.05.051 ↗
16. Surface chemistry study of Cu-Pb sulfide ore using ToF-SIMS and multivariate analysis10.1016/j.apsusc.2020.146270 ↗
17. ToF-SIMS and machine learning for single-pixel molecular discrimination of an acrylate polymer microarray10.1021/acs.analchem.0c00349 ↗
18. Unsupervised machine learning for exploratory data analysis in imaging mass spectrometry10.1002/mas.21602 ↗
19. 2-Mercaptobenzothiazole doped chitosan/11-alkanethiolate acid composite coating: dual function for copper protection10.1016/j.apsusc.2011.07.034 ↗
20. POSS-tetraaniline based giant molecule: synthesis, self-assembly, and active corrosion protection of epoxy-based organic coatings10.1016/j.corsci.2020.108555 ↗
21. A feasible method to improve the protection ability of metal by functionalized carbon dots as environment-friendly corrosion inhibitor10.1016/j.jclepro.2020.121682 ↗
22. Adsorption and corrosion inhibition behavior of polyethylene glycol on α-brass alloy in nitric acid solution10.1080/17518253.2018.1438525 ↗
23. Inhibition of brass (80/20) by 5-Mercaptopentyl-3-Amino-1,2,4-Triazole in neutral solutions10.3390/met7110488 ↗
24. Electrochemical and DFT studies of brass corrosion inhibition in 3% NaCl in the presence of environmentally friendly compounds10.1038/s41598-019-52635-2 ↗
25. Electrochemistry of corrosion mitigation of brasses by azoles in basic medium10.1007/s11696-018-00673-x ↗
26. Corrosion inhibition behaviour of sodium dodecyl benzene sulphonate for brass in an Al2O3 nanofluid and simulated cooling water10.1016/j.corsci.2018.12.006 ↗
27. Corrosion inhibition effect of sodium phytate on brass in NaOH media. Potential-resolved formation of soluble corrosion products10.1016/j.corsci.2013.04.031 ↗
28. Inhibitive properties of 2,5-bis(n-methylphenyl)-1,3,4-oxadiazole and biocide on corrosion, biocorrosion and scaling controls of brass in simulated cooling water10.1016/j.corsci.2013.11.067 ↗
29. Brass corrosion in tap water distribution systems inhibited by phosphate ions10.1016/j.corsci.2010.12.005 ↗
30. Etching and heating treatment combined approach for superhydrophobic surface on brass substrates and the consequent corrosion resistance10.1016/j.corsci.2015.10.013 ↗
31. Preparation of (3-mercaptopropyl)trimethoxylsilane film on brass and its corrosion resistance in natural seawater10.1016/j.porgcoat.2019.105392 ↗
32. EIS study on erosion–corrosion behavior of BA35 and BA22 brasses in drinking water at various impingement angles10.1016/j.colsurfa.2019.124151 ↗
33. Passivity breakdown and stress corrosion cracking of α-brass in sodium nitrate solutions10.1016/j.corsci.2010.09.025 ↗
34. Inhibitive effects and mechanism of phosphates on the stress corrosion cracking of brass in ammonia solutions10.1016/j.corsci.2012.04.011 ↗
35. Corrosion behaviour of heavily deformed pearlitic and brass-coated pearlitic steels in sodium chloride solutions10.1016/j.corsci.2014.06.002 ↗
36. The protective role of hydrozincite during initial corrosion of a Cu40Zn alloy in chloride-containing laboratory atmosphere10.1016/j.corsci.2015.10.027 ↗
37. Electrochemical, 3D topography, XPS, and ToF-SIMS analyses of 4-methyl-2-phenylimidazole as a corrosion inhibitor for brass10.1016/j.corsci.2020.108632 ↗
38. Massart · 1997
39. Raistrick · 2005
40. 2-mercaptobenzimidazole as a copper corrosion inhibitor: part I. Long-term immersion, 3D-Profilometry, and electrochemistry10.1016/j.corsci.2013.03.011 ↗
41. Orazem · 2008
42. An electrochemical, long-term immersion, and XPS study of 2-mercaptobenzothiazole as a copper corrosion inhibitor in chloride solution10.1016/j.corsci.2014.02.016 ↗
43. Application of multisine impedance spectroscopy, FE-AES and FE-SEM to study the early stages of copper corrosion10.1016/j.electacta.2008.01.052 ↗
44. Sastri · 2011
45. Vibrational spectroscopic (FT-IR, FT-Raman, 1H NMR and UV) investigations and computational study of 5-nitro-2-(4-nitrobenzyl) benzoxazole10.1016/j.saa.2012.09.032 ↗
46. Sulfonic derivatives of 2-Mercaptobenzoxazole and its conjugates with poly(maleic anhydride-alt-vinyl acetate) with potential pharmacological applications10.1080/00914037.2013.830254 ↗
47. Quantum mechanical and spectroscopic (FT-IR, FT-Raman, 1H NMR and UV) investigations of 5-nitro-2-phenylbenzoxazole10.1016/j.molstruc.2014.01.018 ↗
48. Effects of non-TR-able codiamines and rearrangement conditions on the chain packing and gas separation performance of thermally rearranged poly(benzoxazole-co-imide) membranes10.1016/j.memsci.2018.07.068 ↗
49. Tougaard · 1996 · 1415
50. Quantification of nano-structures by electron spectroscopy in surface analysis by auger and X-ray photoelectron spectroscopy
51. Characterization of 4-mercaptohydrocynnamic acid self-assembled film on Au(111) by means of X-ray photoelectron spectroscopy10.1016/S0368-2048(00)00315-7 ↗
52. X-ray photoelectron spectroscopy sulfur 2p study of organic thiol and disulfide binding interactions with gold surfaces10.1021/la960465w ↗
53. Self-assembly of π-Conjugated azomethine oligomers by sequential deposition of monomers from solution10.1021/la991686f ↗
54. Attachment of functionalized poly(ethylene glycol) films to gold surfaces10.1021/la990221m ↗
55. Photoelectron spectroscopy study of irradiation damage and metal-sulfur bonds of thiol on silver and copper surfaces10.1016/j.elspec.2004.10.001 ↗
56. Self-assembled organic thin films on electroplated copper for prevention of corrosion10.1116/1.1763901 ↗
57. Comparison of the structures and wetting properties of self-assembled monolayers of n-alkanethiols on the coinage metal surfaces, copper, silver, and gold10.1021/ja00019a011 ↗
58. Alkanethiol-oxidized copper interface: the critical influence of concentration10.1016/j.jcis.2008.06.038 ↗
59. Characterization of mercaptobenzimidazole adsorption on an Au(111) electrode, Iranian Journal of Science & Technology
60. 2-mercaptobenzimidazole as a copper corrosion inhibitor: part II. Surface analysis using X-ray photoelectron spectroscopy10.1016/j.corsci.2013.03.010 ↗
61. X-ray excited Auger Cu L3L4,5M4,5 spectra measured at low take-off angles as a fingerprint for a Cu‐organics connection10.1016/j.elspec.2017.10.005 ↗