journal article·2023-09

Corrosion behavior of Cr-coated zirconium alloy cladding in LiOH/H3BO3-containing water at 360 ℃

Haibin Ma, Honglin Zhang, Lijuan Hu, Sigong Li, Jianan Zhang, Wenhuai Zhang, Rongrong Sun, Meiyi Yao, Jiaxiang Xue, Qisen Ren, Yehong Liao

Corrosion Science· Volume 222
Publisher page

Abstract

The corrosion behaviors of Cr-coated zirconium alloy (Zr-0.9 Nb) tube were investigated in 70 ppm Li and 3.5 ppm Li+ 1000 ppm B aqueous solutions at 360 °C/18.6 MPa by static autoclave tests, respectively. Results show that Cr coating improves the corrosion resistance of Zr-0.9 Nb under LiOH and Li+B conditions. The corrosion products of Cr coating were Cr 2O 3 and Cr(OH) 3, while the Cr 2O 3 was more easily transformed into Cr(OH) 3 under LiOH conditions. Some of the Cr(OH) 3 dissolved in the late stage of corrosion, resulting in the thinning of the oxide film.
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Research context

OpenAlex topics: Nuclear Materials and Properties · Fusion materials and technologies · Nuclear reactor physics and engineering

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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