journal article·2014-03

Effects of prior cathodic polarization on crystallographic pit initiation on aluminum

Lei Yao, Jianhua Liu, Songmei Li, Mei Yu

Corrosion Science· Volume 80
Publisher page

Abstract

Abstract The growth behavior of crystallographic pits on aluminum is examined during galvanostatic anodic etching with consideration of the effect of prior cathodic polarization. Pit density and size distribution are measured by using scanning electron microscope. The results show that prior cathodic polarization enhances pit nucleation greatly and the pit number density can be increased by 11 times with a cathodic current pulse of 100 mA cm −2 , 200 ms. Cathodic polarization leads to passivation of a substantial number of small pits, which alters the pit size distribution. The amount of cathodic charge is a main determinant of the effects.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Anodic Oxide Films and Nanostructures · Corrosion Behavior and Inhibition · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Direct nanoimprinting of Si single crystals using SiC molds for ordered anodic tunnel etching10.1002/adma.200401879 ↗
2. Self-organized growth of single crystals of nanopores10.1063/1.1537868 ↗
3. Inkjet printing for site-controlled tunnel pitting with high aspect ratio in Al10.1149/1.3294519 ↗
4. Fabrication of ordered trench structures with high aspect ratios by anisotropic anode etching of Al (100)10.1149/1.3388511 ↗
5. Metastable pitting behavior of aluminum single crystals10.1016/S0010-938X(00)00032-9 ↗
6. Formation of crystallographic etch pits during AC etching of aluminum10.1149/1.1596952 ↗
7. R.S. Alwitt, H. Uchi, Processing of Al foil for electrolytic capacitors, in: Proceedings of the 2nd International Symposium on Aluminium Surface Science and Technology (ASST 2000), UMIST, Manchester, England, 2000, pp. 213–220.
8. Electrochemical tunnel etching of aluminium10.1149/1.2115495 ↗
9. Tunnel morphology in anodic etching of aluminium10.1149/1.1837730 ↗
10. Growth of etch tunnels in aluminum at temperatures of 28–60°C10.1149/1.2404785 ↗
11. Tunnel morphology of aluminium foil etched by a two-step DC etching method10.1016/j.corsci.2008.08.031 ↗
12. Growth and passivation of aluminium etch tunnels10.1149/1.2096231 ↗
13. Local chemistry considerations in the tunnelling corrosion of aluminium10.1016/0010-938X(94)00163-Z ↗
14. A model for the 〈100〉 crystallographic tunnel etching of aluminium10.1007/BF01160833 ↗
15. Metal dissolution kinetics in aluminium etch tunnels10.1149/1.1394026 ↗
16. A mathematical model for the growth of aluminium etch tunnels10.1149/1.1369368 ↗
17. Kinetic model for aluminum dissolution in corrosion pits10.1149/1.1635386 ↗
18. Interfacial void model for corrosion pit initiation on aluminum10.1149/1.1715091 ↗
19. Electrochemical etching model in aluminium foil for capacitor10.1016/j.corsci.2008.02.017 ↗
20. Surface texture formed on AA2099 Al–Li–Cu alloy during alkaline etching10.1016/j.corsci.2012.09.032 ↗
21. Effect of hydration pretreatment on tunnel etching behaviour of aluminium foil10.1016/j.corsci.2013.01.027 ↗
22. Effect of pretreatment on electrochemical etching behaviour of Al foil in HCl–H2SO410.1016/S1003-6326(13)62564-9 ↗
23. Formation of uniform square-shaped tunnel pit by electrochemical etching with an opened polyimide layer on aluminium foil10.1002/sia.4961 ↗
24. Pit nucleation behavior of aluminium foil for electrolytic capacitors during early stage of DC etching10.1016/S0010-938X(99)00117-1 ↗
25. Pit growth behaviour of aluminium under galvanostatic control10.1016/j.corsci.2011.06.024 ↗
26. Crystallographic pit growth on aluminium (100)10.1149/1.1839471 ↗
27. Observations of the early stages of the pitting corrosion of aluminium10.1149/1.2085577 ↗
28. The effect of alternating voltage on aluminium electrodes in hydrochloric acid10.1016/S0010-938X(78)80092-4 ↗
29. Effect of sulfuric acid on pit propagation behaviour of aluminium under AC etch process10.1016/j.corsci.2009.06.021 ↗
30. Role of cathodic half-cycle on AC etch process of aluminium10.1016/j.corsci.2010.02.039 ↗
31. Effect of frequency and current density on AC etching of aluminium electrolytic capacitor foil10.1007/s10854-006-9058-7 ↗
32. The effect of prior cathodic polarization on the initiation of pitting on aluminium10.1149/1.2086293 ↗
33. Surface films produced by cathodic polarization of aluminium10.1149/1.2054716 ↗
34. Changes produced by cathodic polarization in the electrical conduction behavior of surface films on aluminium10.1149/1.2054667 ↗
35. Influence of the surface activation and local pitting susceptibility on the AC-electrograining of aluminium alloys10.1016/j.corsci.2010.11.020 ↗
36. Ultrasonic-assisted ac etching of aluminium foils for electrolytic capacitor electrodes with enhanced capacitance10.1016/j.matchemphys.2010.05.027 ↗
37. Effects of pretreatment on the aluminium etch pit formation10.1016/j.corsci.2009.02.028 ↗
38. Abnormal yields of hydrogen and the mechanism of its evolution during cathodic polarization of aluminium10.1016/0013-4686(90)87074-C ↗
39. Yield of hydrogen during cathodic polarisation of Al–Sn alloy10.1016/S0013-4686(03)00602-9 ↗
40. Cathodic breakdown of anodic oxide film on Al and Al–Sn alloys in NaCl solution10.1016/j.electacta.2005.03.041 ↗
41. Role of prior cathodic polarizaion in the pitting corrosion of pure aluminium in acidic chloride solution10.1016/S0921-5093(99)00638-3 ↗