Oxidation behavior of Ti–Cu binary metallic glass
Source abstract
Abstract
Abstract The oxidation behavior of Ti 50 Cu 50 metallic glass has been investigated. When the oxide is in amorphous state blow the glass transition temperature, the diffusion rate of Ti ion from the matrix controls the growth rate of the oxide layer. With the increase of thickness, the amorphous oxide is crystallized into TiO 2 , which grows in inward direction by diffusion of oxygen ion through the oxide layer. Above the crystallization temperature, fast diffusion of Ti and oxygen ions through columnar grain boundary of TiO 2 results in the formation of Ti 3 Cu 3 O underneath the oxide layer and TiO 2 on the surface.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metallic Glasses and Amorphous Alloys · Electromagnetic wave absorption materials · Glass properties and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (59)
Show source-provided references
1. Bulk metallic glass nanowire architecture for electrochemical applications10.1021/nn200033c ↗
2. Capillary flow of amorphous metal for high performance electrode10.1038/srep02185 ↗
3. Oxidation induced amorphous stabilization of the subsurface region in Zr-Cu metallic glass10.1063/1.4862025 ↗
4. Corrosion behaviors of coatings fabricated using bulk metallic glass powders with the composition of Fe68.5C7.1Si3.3B5.5P8.7Cr2.3Mo2.5Al2.010.1007/s12540-012-4006-y ↗
5. Effect of electrolyte pH on the electrochemical behavior of Fe-based bulk metallic glass10.1007/s12540-012-5007-6 ↗
6. Thermal and mechanical properties of Cu60-xZr25Ti15Nix bulk metallic glasses with x=0 1, 3, 5, 7, 9 and 11at.%10.1007/s12540-013-1024-3 ↗
7. Assessment of surface-local strains from remnant microindents on a Zr-based metallic glass10.1007/s12540-014-3006-5 ↗
8. Design of cost-effective Fe-based amorphous coating alloys having high amorphous forming ability by thermodynamic calculation10.1007/s12540-014-4001-6 ↗
9. Corrosion behavior in a 3.5wt% NaCl solution of amorphous coatings prepared through plasma-spray and cold-spray coating processes10.1007/s12540-014-6008-4 ↗
10. The oxidation behavior of a Ti50Cu28Ni15Sn7 bulk metallic glass at 400–500°C10.1016/j.jallcom.2010.04.128 ↗
11. The oxidation behavior of an Fe61B15Zr8Mo7Co5Y2Cr2 bulk metallic glass at 500–700°C10.1016/j.intermet.2008.08.013 ↗
12. Air oxidation of a Zr58Cu22Al12Fe8 bulk metallic glass at 350–550°C10.1016/j.jallcom.2008.10.133 ↗
13. Replacement of oxide glass with metallic glass for Ag screen printing metallization on Si emitter10.1063/1.3596469 ↗
14. Large-area and uniform amorphous metallic nanowire arrays prepared by die nanoimprinting10.1016/j.jallcom.2014.03.176 ↗
15. Enhancement of oxidation resistance of the supercooled liquid in Cu–Zr-based metallic glass by forming an amorphous oxide layer with high thermal stability10.1016/j.corsci.2012.09.018 ↗
16. Thermal and mechanical properties of Ti–Ni–Cu–Sn amorphous alloys with a wide supercooled liquid region before crystallization10.2320/matertrans1989.39.1001 ↗
17. Ductile titanium-based glassy alloy ingots10.1063/1.1872214 ↗
18. Oxidation of Cu60Zr30Ti10 metallic glasses10.1016/j.msea.2006.02.291 ↗
19. Crystallization kinetic of Cux Ti100-x (x=43, 50 and 53) glasses10.1016/S0921-4526(00)00761-4 ↗
20. Enthalpies of formation of Ti–Cu intermetallic and amorphous phases10.1016/S0925-8388(96)02590-X ↗
21. Enhancement of electrical conductivity of thick silver electrode using a tailored amorphous alloy10.1063/1.4747216 ↗
22. Replacement of oxide glass with metallic glass for Ag screen printing metallization on Si emitter10.1063/1.3596469 ↗
23. Effect of Ni on glass-forming ability of Cu–Ti-based amorphous alloys10.1016/S1003-6326(06)60106-4 ↗
24. High-temperature oxidation of Cu–Ti-based rapidly solidified alloys
25. Morphology of oxide scales formed on titanium10.1007/BF00659464 ↗
26. Oxidation of titanium in the temperature range 800–1200°C10.1016/0022-5088(61)90001-7 ↗
27. Grain boundary diffusion and oxidation processes10.1016/S0167-2738(98)00242-2 ↗
28. The oxidation of titanium in oxygen at high temperatures10.1016/0001-6160(60)90170-X ↗
29. Birks · 2006
30. Oxidation behavior of equiatomic TiNi alloy in high temperature air environment10.1016/0921-5093(96)10409-3 ↗
31. Temperature effects in the early stages of titanium oxidation10.1016/0169-4332(95)00334-7 ↗
32. Investigation on the oxidation mechanism of titanium10.3891/acta.chem.scand.12-0239 ↗
33. Oxidation of titanium, zirconium and hafnium10.1149/1.2427248 ↗
34. High-temperature oxidation of titanium10.1016/0022-5088(67)90017-3 ↗
35. Chemical reactions at surface: titanium oxidation10.1016/S0257-8972(99)00420-X ↗
36. Isothermal oxidation mechanism of Nb–Ti–V–Al–Zr alloy at 700–1200°C: diffusion and interface reaction10.1016/j.corsci.2015.04.002 ↗
37. Atomic-scale modeling of the dynamics of titanium oxidation10.1021/jp309305n ↗
38. Concentration of electrons at grain boundaries in TiO2 (rutile): impact on charge transport and reactivity10.1016/j.cattod.2013.11.039 ↗
39. Diffusion along grain boundaries and dislocations in oxides, alkali halides and carbides10.1016/0167-2738(84)90160-7 ↗
40. The lateral growth strain accompanying the formation of a thermally grown oxide10.1016/S1359-6454(02)00532-3 ↗
41. An investigation on oxidation wear mechanism of Ti–46Al–7Nb–0.7Cr–0.1Si–0.2Ni intermetallic-based alloys10.1016/j.corsci.2009.09.015 ↗
42. Effect of thermal stability of the amorphous substrate on the amorphous oxide growth on Zr–Al–(Cu,Ni) metallic glass surfaces10.1016/j.corsci.2013.04.009 ↗
43. Elliott · 1990
44. The thermodynamic stability of amorphous oxide overgrowths on metals10.1016/j.actamat.2007.10.023 ↗
45. Xia · 2011
46. Formation of amorphous oxide in Al82Ni13Zr5 and Al88Ni7Ca5 alloys10.1016/j.corsci.2014.07.035 ↗
47. Thermodynamic evaluation of reaction products and layering in brazed alumina joints10.1557/JMR.1994.2244 ↗
48. Oxidation resistance of the supercooled liquid in Cu50Zr50 and Cu46Zr46Al8 metallic glasses10.1557/jmr.2012.23 ↗
49. Oxidation of Zr-based metallic glasses and nanocrystalline alloys10.1016/j.msea.2006.02.316 ↗
50. Air oxidation of a Zr55Cu50 Al10Ni5 bulk metallic glass at its super cooled liquid state10.1016/j.corsci.2014.02.007 ↗
51. Self limiting oxidation of copper10.1063/1.122608 ↗
52. The homogeneous nucleation mechanism of Cu2O on Cu(001)10.1016/S1359-6462(98)00026-8 ↗
53. Oxygen surface diffusion in three-dimensional Cu2O growth on Cu(001) thin films10.1063/1.119220 ↗
54. The oxidation behavior of Cu–Zr–Ti-base bulk metallic glasses in air at 350–500°C10.1007/s11085-007-9049-y ↗
55. The glass transition as a free volume related kinetic phenomenon10.1016/0956-7151(90)90142-4 ↗
56. Calculated solubilities of oxygen in liquid and solid silicon10.1149/1.2109053 ↗
57. Oxidation induced phase instability of Cu54Zr22Ti18Ni6 bulk metallic glass10.1016/j.msea.2006.03.136 ↗
58. High temperature oxidation behavior of Ti–Ni–Hf shape memory alloy10.1016/j.tca.2014.02.016 ↗
59. Role of kirkendall effect in diffusion processes in solids10.1016/S1003-6326(14)63021-1 ↗