Corrosion and tribocorrosion mitigation of perhydropolysilazane-derived coatings on low carbon steel
Source abstract
Abstract
Abstract Perhydropolysilazane (PHPS) is a polymer with [–SiH2–NH–]n repeating units. By pyrolysis with PHPS as a precursor, highly adhesive and protective silicon oxynitride (SiON)-based coatings were synthesized. The formation of Si O Si bonds increased with pyrolysis temperature. Both the hardness and Young’s modulus of the PHPS-derived coatings were enhanced at higher pyrolysis temperatures. The PHPS-derived coatings significantly enhanced the corrosion resistance of low carbon steel in a 0.6 M NaCl aqueous solution, especially for the coatings with the formation of extensive Si-O-Si bonds. The PHPS-derived coating at the pyrolysis temperature of 600 °C exhibited the best resistance to corrosion and tribocorrosion.
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Research context
OpenAlex topics: Metal and Thin Film Mechanics · Diamond and Carbon-based Materials Research · Advanced ceramic materials synthesis
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