journal article·2020-07

Long-term oxidation resistance and deterioration mechanism of magnetron sputtered Cr-Al-Si-N coatings on zirconium alloys in 1200 °C steam atmosphere

Han Zhu, Haiyong Liu, Jingyuan Zhou, Yue Dong, Peng Li, Leilei Chen, Jun Yi, Qing Huang, Feng Huang, Fangfang Ge

Corrosion Science· Volume 171
Publisher page

Abstract

Abstract Oxidation behavior of magnetron sputtered Cr-Al-Si-N coatings on zirconium-alloy coupons was studied in 1200 °C steam up to 8 h, revealing the microstructural evolution and the oxidation resistance by electron microscopy. A ∼310 μm thick Zr-O layer formed on the uncoated coupon after the 6 h oxidation, whereas the coated coupon retained almost unoxidized, due to a homogenous and stable bilayer scale of Cr2O3/α-Al2O3 on the surface. It was assumed that the column-free structure and isotropic nanostructure of coatings could favor a timely and in situ formation of the bilayer scale, followed by long-term maintenance of its integrity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nuclear Materials and Properties · Fusion materials and technologies · High-Temperature Coating Behaviors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (40)

Show source-provided references
1. Protective coatings on zirconium-based alloys as accident-tolerant fuel (ATF) cladding10.1515/corrrev-2017-0010 ↗
2. Application of coating technology on Zirconium-based alloy to decrease high-temperature oxidation
3. Early studies on Cr-Coated Zircaloy-4 as enhanced accident tolerant nuclear fuel claddings for light water reactors10.1016/j.jnucmat.2019.02.018 ↗
4. Accident tolerant fuel cladding development: Promise, status, and challenges10.1016/j.jnucmat.2017.12.043 ↗
5. Predicting oxide stability in high-temperature water vapor10.1007/s11837-006-0063-3 ↗
6. Alloy design strategies for promoting protective oxide scale formation10.1007/s11837-000-0109-x ↗
7. Microstructure, corrosion resistance and oxidation behavior of Cr-coatings on Zircaloy-4 prepared by vacuum arc plasma deposition10.1016/j.corsci.2019.06.029 ↗
8. Adhesion property and high-temperature oxidation behavior of Cr-coated Zircaloy-4 cladding tube prepared by 3D laser coating10.1016/j.jnucmat.2015.06.030 ↗
9. Development of Cr cold spray-coated fuel cladding with enhanced accident tolerance
10. High-temperature oxidation of thick Cr coating prepared by arc deposition for accident tolerant fuel claddings10.1016/j.jnucmat.2019.01.039 ↗
11. High-temperature oxidation resistance of chrominum-based coatings deposited by DLI-MOCVD for enhanced protection of the inner surface of long tubes10.1016/j.surfcoat.2018.05.088 ↗
12. On-going studies at CEA on chromium coated zirconium based nuclear fuel claddings for enhanced accident tolerant LWRs fuel
13. Response of Cr and Cr-Al coatings on Zircaloy-2 to high temperature steam10.1016/j.jnucmat.2017.10.021 ↗
14. Vacuum-arc chromium-based coatings for protection of zirconium alloys from the high-temperature oxidation in air10.1016/j.jnucmat.2015.06.016 ↗
15. High temperature steam-oxidation behavior of arc ion plated Cr coatings for accident tolerant fuel claddings10.1016/j.surfcoat.2015.09.022 ↗
16. Behavior of an improved Zr fuel cladding with oxidation resistant coating under loss-of-coolant accident conditions10.1016/j.jnucmat.2016.10.021 ↗
17. Development of cold spray chromium coatings for improved accident tolerant zirconium-alloy cladding10.1016/j.jnucmat.2019.03.039 ↗
18. An interesting oxidation phenomenon of Cr coatings on Zry-4 substrates in high temperature steam environment10.1016/j.corsci.2019.05.017 ↗
19. Behavior of plasma sprayed Cr coatings and FeCrAl coatings on Zr fuel cladding under loss-of-coolant accident conditions10.1016/j.surfcoat.2018.03.016 ↗
20. Microstructural eff ;ects on the high-temperature steam oxidation resistance of magnetron sputtered Cr-Al-Si-N quaternary coatings on zirconium coupons10.1016/j.surfcoat.2019.06.013 ↗
21. Improved oxidation resistance of zirconium at high-temperature steam by magnetron sputtered Cr-Al-Si ternary coatings10.1016/j.surfcoat.2018.04.029 ↗
22. Birks · 2006
23. Effect of Cr/Al atomic ratio on the oxidation resistance in 1200 °C steam for the CrAlSiN coatings deposited on Zr alloy substrate10.1007/s11837-019-03839-4 ↗
24. Investigations of aluminum-doped self-healing zircaloy surfaces in context of accident-tolerant fuel cladding research10.1007/s11665-016-2094-4 ↗
25. Oxidation of multicomponent two-phase alloys10.1007/BF01046728 ↗
26. Neumann · 2009
27. Oxidation behavior of CrNx and (Cr,Al)Nx hard coatings10.1002/maco.19900411222 ↗
28. Oxidation of Ni-Cr-Al alloys between 1000 °C and 1200 °C10.1149/1.2407837 ↗
29. Gupta · 1988
30. Hard nanocomposite coatings: Thermal stability, oxidation resistance and toughness10.1016/j.surfcoat.2012.05.073 ↗
31. Oxidation resistance of nanocomposite CrAlSiN under long-time heat treatment10.1016/j.surfcoat.2011.06.009 ↗
32. Isothermal oxidation of β-NiAl alloys and sputtered coating at 1000 °C in air10.4028/www.scientific.net/MSF.369-372.361 ↗
33. Influence of columnar microstructure of a sputtered NiAl coating on its oxidation behavior at 1000 °C10.1016/S0966-9795(02)00020-1 ↗
34. The effect of an oxide dispersion on the critical Al content in Fe-Al alloys10.1023/A:1018862404800 ↗
35. Chromium diffusion in Ni-20 Wt Pct Cr-3 Vol Pct Y2O3 and Co-21 Wt Pct Cr-3 Vol Pct Y2O310.1007/BF02661341 ↗
36. Oxidation behavior of Si-doped nanocomposite CrAlSiN coatings10.1016/j.surfcoat.2010.08.156 ↗
37. Factors aff ;ecting isothermal oxidation of pure chromium in air10.1016/j.corsci.2017.11.006 ↗
38. The effect of volatilization on the oxidation kinetics of Cr and Fe-Cr alloys10.1149/1.2424115 ↗
39. Conditions for the initiation of oxide-scale cracking and spallation10.1016/0010-938X(84)90051-9 ↗
40. The influence of alloying elements on the development and maintenance of protective scales10.1007/BF01046725 ↗