Ultrarobust Thin‐Film Devices from Self‐Assembled Metal–Terpyridine Oligomers
Source abstract
Abstract
Ultrathin molecular layers of Fe(II) -terpyridine oligomers allow the fabrication of large-area crossbar junctions by conventional electrode vapor deposition. The junctions are electrically stable for over 2.5 years and operate over a wide range of temperatures (150-360 K) and voltages (±3 V) due to the high cohesive energy and packing density of the oligomer layer. Electrical measurements reveal ideal Richardson-Shottky emission in surprising agreement with electrochemical, optical, and photoemission data.
Source: europepmc · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Molecular Junctions and Nanostructures · Organic Electronics and Photovoltaics · Nanowire Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Sony Deutschland GmbH Materials Science Laboratory Hedelfinger Strasse 61 70327 Stuttgart Germany
Dipartimento di Chimica Università di Ferrara Via Borsari 46 44100 Ferrara Italy
Institute of Nanotechnology Karlsruhe Institute of Technology 76021 Karlsruhe Germany
Funding
Deutsche Forschungsgemeinschaft · Science and Technology of Nanosystems (STN) · EU FP7 Project MMM@HPC
References (50)
Show source-provided references
1. 10.1016/0009-2614(74)85031-110.1016/0009-2614(74)85031-1 ↗
2. 10.1002/1521-3773(20021202)41:23<4378::AID-ANIE4378>3.0.CO;2-A10.1002/1521-3773(20021202)41:23<4378::AID-ANIE4378>3.0.CO;2-A ↗
3. 10.1088/0953-8984/20/01/01300110.1088/0953-8984/20/01/013001 ↗
4. 10.1088/0957-4484/18/31/31520410.1088/0957-4484/18/31/315204 ↗
5. 10.1063/1.185474210.1063/1.1854742 ↗
6. 10.1038/nature0469910.1038/nature04699 ↗
7. 10.1021/ja994468h10.1021/ja994468h ↗
8. 10.1126/science.106435410.1126/science.1064354 ↗
9. 10.1103/PhysRevB.68.03541610.1103/PhysRevB.68.035416 ↗
10. 10.1063/1.165978510.1063/1.1659785 ↗
11. 10.1021/ja004055c10.1021/ja004055c ↗
12. 10.1038/nnano.2010.11910.1038/nnano.2010.119 ↗
13. 10.1002/anie.20070364210.1002/anie.200703642 ↗
14. 10.1039/b411490f10.1039/b411490f ↗
15. 10.1002/adfm.20029000910.1002/adfm.200290009 ↗
16. 10.1002/adma.20060019510.1002/adma.200600195 ↗
17. 10.1002/adma.20110455010.1002/adma.201104550 ↗
18. 10.1063/1.291787010.1063/1.2917870 ↗
19. 10.1088/0953-8984/20/37/37411710.1088/0953-8984/20/37/374117 ↗
20. 10.1002/adma.20110125110.1002/adma.201101251 ↗
21. 10.1038/nmat233210.1038/nmat2332 ↗
22. 10.1002/adma.20130484810.1002/adma.201304848 ↗
23. 10.1002/cphc.20060057310.1002/cphc.200600573 ↗
24. 10.1016/j.ccr.2012.08.02510.1016/j.ccr.2012.08.025 ↗
25. 10.1021/nn300126m10.1021/nn300126m ↗
26. 10.1021/nn502794z10.1021/nn502794z ↗
27. 10.1007/BF0134319610.1007/BF01343196 ↗
28. 10.1021/jp048904k10.1021/jp048904k ↗
29. 10.1021/ja039015y10.1021/ja039015y ↗
30. 10.1021/ja072990v10.1021/ja072990v ↗
31. 10.1126/science.115653810.1126/science.1156538 ↗
32. 10.1021/ja910547c10.1021/ja910547c ↗
33. Lampert M. A. · 1970
34. Richardson O. W. · 1965 · 1928
35. Weißmantel C. · 1981
36. 10.1063/1.158835810.1063/1.1588358 ↗
37. 10.1103/PhysRevB.60.879110.1103/PhysRevB.60.8791 ↗
38. 10.1063/1.12019510.1063/1.120195 ↗
39. 10.1016/S0009-2614(98)01277-910.1016/S0009-2614(98)01277-9 ↗
40. Sze S. M. · 2012
41. 10.1063/1.149588010.1063/1.1495880 ↗
42. 10.1071/CH985020710.1071/CH9850207 ↗
43. 10.1007/978-3-662-06945-510.1007/978-3-662-06945-5 ↗
44. 10.1002/adfm.20050036410.1002/adfm.200500364 ↗
45. 10.1002/adma.20080289310.1002/adma.200802893 ↗
46. 10.1103/PhysRevB.54.R1432110.1103/PhysRevB.54.R14321 ↗
47. 10.1021/jp03466510.1021/jp034665 ↗
48. 10.1063/1.220826710.1063/1.2208267 ↗
49. 10.1021/ct500418f10.1021/ct500418f ↗
50. 10.1103/PhysRevB.91.15520310.1103/PhysRevB.91.155203 ↗