journal article·2006-12

Thermal desorption of fullerene C60 from polymer matrices

Aleksei O. Pozdnyakov

Composites Science and Technology· Volume 66· Issue 16
Publisher page

Abstract

Abstract The data on thermally stimulated desorption (TSD) study of fullerene C60 molecules from different polymer matrices are compared in view of the temperature positions and relative intensities of resolved thermal desorption stages. An increase of the low temperature C60 desorption stages is observed for polydimethylsiloxane (PDMS) and polystyrene (PS) contrary to polyimide (PI). This is in agreement with the difference in glass transition temperatures (Tg) of these polymers. The TSD data allow us to conclude that above Tg of the polymer the solubility of fullerene C60 in PDMS and PS is up to the order of magnitude higher compared with C60 solubility in low molecular weight solvents.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fullerene Chemistry and Applications · Carbon Nanotubes in Composites · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Phase structure and adhesion in polymer blends: a criterion for rubber toughening10.1016/0032-3861(85)90015-1 ↗
2. Polymer based nanocomposites: effect of filler–filler and filler–matrix interactions10.1002/1527-2648(200108)3:8<571::AID-ADEM571>3.0.CO;2-M ↗
3. Adhesion of nanoparticles within spray-dried agglomerates10.1088/0022-3727/25/1A/002 ↗
4. Rheology of nanocomposites based on layered silicates and polyamide-1210.1007/s003960000294 ↗
5. Toughening of polymers by self-assembling molecules10.1002/1521-4095(20021104)14:21<1540::AID-ADMA1540>3.0.CO;2-T ↗
6. 1986 · vol. 1
7. 1994
8. 1991
9. Solubility of C60 in a variety of solvents10.1021/j100115a049 ↗
10. Relation between the solubility and the effective solute–solute interaction for C60 solutions and lysozyme solutions: a comparison using the sticky hard-sphere potential10.1016/S0022-0248(97)00416-8 ↗
11. Colloidal dispersions of fullerene in water: some properties and C60 regularities of coagulation by electrolytes10.1039/a705494g ↗
12. Comparative analysis of two aqueous-colloidal solutions of C60 fullerene with help of FTIR refectance and UV–Vis spectroscopy10.1016/S0009-2614(02)01305-2 ↗
13. Enthalpy of solution of fullerene[60] in some aromatic solvents10.1016/j.molliq.2004.07.003 ↗
14. 1989
15. Thermal desorption states of C60 in polymer matrices10.1134/1.2142900 ↗
16. Fullerene C60 diffusion in thin layers of amorphous polymers: polystyrene and poly(α-methylstyrene)10.1134/1.1813726 ↗
17. Thermal stability of the films of PS chemically bound to C60: thickness effect in submicron range
18. Effect of the film thickness on the thermal stability of submicron polymer layers containing fullerene C6010.1134/1.1467271 ↗
19. Thermally stimulated desorption of C60 and C70 fullerenes from rigid-chain polyimide films10.1134/1.1778466 ↗
20. Sliding wear of polyimide-C60 coatings10.1016/S0043-1648(03)00139-X ↗
21. Pozdnyakov AO, Friedrich K, Kudryavtsev VV. Gleitverschleiss polymerer verbundwerkstoffe zwischen raumtemperatur und 4,2 K, BAM-sonderheft 3-2001, 2001. p. 35–8.
22. Polymer Encyclopedia, Sovetskaya Enciklopedia: Moscow: v. 3, 1977. p. 492.
23. Pozdnyakov AO, Krumova M, Cagiao ME, Funari SS, Kudryavtsev VV, Friedrich K, et al. Influence of fullerene upon imidization of polyamic acid: temperature dependence as revealed by SAXS and WAXS, Hazylab Annual report, Gehrke R, Krell U, Schneider JR, editors. 2001. Available from: http://www-hasylab.desy.de/science/annual_reports/2001_report/part1/contrib/48/5074.pdf.
24. Growth and photoluminescence spectra of C60 single crystals10.1016/S0022-2313(97)00224-X ↗
25. Optical limiting in organic polyimide systems doped with fullerenes and dyes10.1117/12.386380 ↗
26. New polymers containing diquinolyl units in the backbone and their complexes with Cu(I): synthesis and photophysical properties
27. Diffusion controlled thermal desorption of gas from solid body
28. Viscosity, plasticity, and diffusion as examples of absolute reaction rates10.1063/1.1749836 ↗
29. Kinetic theory of liquids
30. Transport and equilibrium phenomena in gas-elastomer systems. I. Kinetic phenomena10.1002/pol.1948.120030410 ↗
31. Theory of Do for atomic diffusion in metals10.1063/1.1699967 ↗
32. Relation between prefactor and activation energy for the diffusion of atoms and small molecules in polymers10.1016/1359-6462(96)00011-5 ↗