Preparation of acrylic anodic electrophoretic resin/clay nanocomposite films by water-based electrodeposition
Source abstract
Abstract
Abstract Polymer/clay nanocomposite films were prepared by electrodeposition from aqueous dispersions of acrylic anodic electrophoretic resin (AAER) and Na+-montmorillonite (MMT). The characterization results using XRD, SEM and TEM indicated well-dispersed MMT platelets in the composite films prepared. Mono-disperse-like hexagonal MMT platelets were observed when the MMT loading in the resin matrix was low. The ideal dispersity achieved was thought to be the result of aqueous compatibility between AAER molecules and MMT platelets and of the water-involved process as well. FTIR study proved the interaction between AAER and MMT and the intercalated or exfoliated morphology. Thermal stability, tensile modulus and strength, storage modulus and glass transition temperature of the polymer/clay nanocomposite films were effectively improved compared to those of the virgin AAER film.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Conducting polymers and applications · Electrophoretic Deposition in Materials Science · Polymer Nanocomposites and Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (32)
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1. 1990
2. 1984
3. A new method of STM tip fabrication for in-situ electrochemical studies10.1016/0304-3991(92)90308-7 ↗
4. A simple method for insulating carbon-fiber microelectrodes using anodic electrophoretic deposition of paint10.1021/ac960210n ↗
5. One-pot synthesis of nylon 6-clay hybrid10.1002/pola.1993.080310714 ↗
6. Clay-reinforced epoxy nanocomposites10.1021/cm00048a006 ↗
7. Polymer layered silicate nanocomposites10.1002/adma.19960080104 ↗
8. A commentary on “synthesis and electrorheological properties polyaniline–Na+-montmorillonite suspensions”10.1002/(SICI)1521-3927(19990801)20:8<450::AID-MARC450>3.0.CO;2-N ↗
9. Morphology, thermal and mechanical behavior of polyamide 6/layered-silicate nanocomposites10.1016/S0266-3538(02)00226-9 ↗
10. Preparation, structure, properties and thermal behavior of rigid-rod polyimide/montmorillonite nanocomposites10.1016/S0266-3538(01)00026-4 ↗
11. Polymer/layered silicate nanocomposites: a review from preparation to processing10.1016/j.progpolymsci.2003.08.002 ↗
12. Epoxy nanocomposites with highly exfoliated clay: mechanical properties and fracture mechanisms10.1021/ma048465n ↗
13. Multilayer composites from vapor-grown carbon nano-fibers10.1016/j.compscitech.2005.11.004 ↗
14. Poly(ε-caprolactone)-clay nanocomposites: structure and mechanical properties10.1021/ma052154a ↗
15. Electron beam synthesis and characterization of poly(vinyl alcohol)/montmorillonite nanocomposites10.1002/app.24370 ↗
16. Morphology and mechanical properties of clay/styrene–butadiene rubber nanocomposites10.1002/1097-4628(20001209)78:11<1873::AID-APP40>3.0.CO;2-8 ↗
17. Structure and properties of poly(vinyl alcohol)/Na+ montmorillonite Nanocomposites10.1021/cm000506g ↗
18. Influence of the layer charge and clay particle size on the interactions between the cationic dye methylene blue and clays in an aqueous suspension10.1006/jcis.2002.8654 ↗
19. Influence of dispersing agents and solution conditions on the solubility of crude kaolin10.1016/j.jcis.2003.09.015 ↗
20. Morphology characterization of PP/clay nanocomposites across the length scales of the structural architecture10.1002/mame.200600026 ↗
21. Stabilization of aqueous clay suspensions with AOT vesicular solution10.1016/0927-7757(95)03362-9 ↗
22. Olphen · 1963
23. Lattice model of polymer melt intercalation in organically-modified layered silicates10.1021/ma9514333 ↗
24. Surface chemical studies on the competitive adsorption of poly(acrylic acid) and poly(vinyl alcohol) onto alumina10.1006/jcis.1999.6289 ↗
25. Biopolymer–clay nanocomposites based on chitosan intercalated in montmorillonite10.1021/cm0343047 ↗
26. Hydrogen bonding and mechanical properties in segmented montmorillonite/polyurethane nanocomposites of different hard segment ratios10.1016/S0032-3861(00)00729-1 ↗
27. Physical, mechanical and conductivity properties of poly(3-hexythiophene)-montmorillonite clay nanocomposites produced by the solvent casting method10.1021/ma0490496 ↗
28. Development of EVOH-kaolinite nanocomposites10.1016/j.polymer.2004.05.018 ↗
29. Degradation of high barrier ethylene–vinyl alcohol copolymer under mild thermal-oxidative conditions studied by thermal analysis and infrared spectroscopy10.1002/pi.674 ↗
30. Nanostructured artificial nacre10.1038/nmat906 ↗
31. Multiscale micromechanical modeling of polymer/clay nanocomposites and the effective clay particle10.1016/j.polymer.2003.10.100 ↗
32. David · 2002