Time-concentration superpositioning principle accounting for the size effects of reinforcement and dissipation of polymer nanocomposites
Source abstract
Abstract
Abstract Understanding the linear rheology of polymer nanocomposites has great importance in designing and processing of soft materials. Herein linear rheological responses of silica/poly(2-vinylpyridine) and carbon black/polystyrene nanocomposites in wide ranges of filler volume fraction and polymer molecular weight are shown to be generalized and captured in a simple, unique time-concentration superpositioning principle, providing a potentially universal mean for rationalizing the apparent liquid-to-solid transition and an important guidance for understanding the role of dynamics of the non-Newtonian dispersing medium.
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Research context
OpenAlex topics: Material Dynamics and Properties · Polymer Nanocomposites and Properties · Rheology and Fluid Dynamics Studies
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References (100+)
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