In situ construction of dual-noncovalent bonding to prepare enhanced carbon nanotubes/poly(methyl methacrylate) nanocomposites
Source abstract
Abstract
Abstract Interfacial interaction between carbon nanotubes (CNTs) and polymer matrix is crucial in preparing high-performance CNTs/polymer composites. In this work, dual-noncovalent bonding was constructed via in situ polymerization to improve the interfacial interaction between CNTs and polymer. Two functional monomers, 2-(methacryloyloxy) ethyltrimethyl ammonium chloride (MTC) and styrene (St), were utilized to copolymerize with methyl methacrylate (MMA) via in situ polymerization, meanwhile, carboxylic CNTs was adsorbed through electrostatic interaction and π-π interaction during the polymerization process. 1H NMR and GPC measurements verified that the successful synthesis of copolymer and its adsorption onto the surface of CNTs, while the enhanced interfacial interactions were confirmed by FTIR and Raman. Compared with neat PMMA, the thermal decomposition temperature and tensile strength of the composites were improved by 40 °C and 55.2%, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Nanotechnology research and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
Show source-provided references
1. The mechanical behavior of CNT reinforced nanocomposites assuming imperfect interfacial bonding between matrix and nanoparticles and percolation of interphase regions10.1016/j.compscitech.2017.03.012 ↗
2. Study of distinctions in the synergistic effects between carbon nanotubes and different metal oxide nanoparticles on enhancing thermal oxidative stability of silicone rubber10.1007/s10853-016-9990-8 ↗
3. Compositing polyetherimide with polyfluorene wrapped carbon nanotubes for enhanced interfacial interaction and conductivity10.1021/am4054805 ↗
4. Non-covalent functionalization of carbon nanotubes with polymers10.1039/C3RA44906H ↗
5. Catalytic action of graphene oxide towards the growth of carbon nanotubes10.1016/j.matlet.2016.05.022 ↗
6. Double percolation of multiwalled carbon nanotubes in polystyrene/polylactic acid blends10.1016/j.polymer.2016.06.058 ↗
7. Molecular dynamics simulation of carbon nanotube pull-out from polyethylene matrix10.1016/j.compscitech.2017.03.029 ↗
8. Noncovalent functionalization of multi-walled carbon nanotubes with pyrene-linked nylon66 for high performance nylon66/multi-walled carbon nanotube composites10.1016/j.carbon.2014.01.068 ↗
9. Lowly loaded carbon nanotubes induced high electrical conductivity and giant magnetoresistance in ethylene/1-octene copolymers10.1016/j.polymer.2016.09.056 ↗
10. Improving the filler dispersion and performance of silicone rubber/multi-walled carbon nanotube composites by noncovalent functionalization of polymethylphenylsiloxane10.1007/s10853-017-0984-y ↗
11. Design and fabrication of morphologically controlled carbon nanotube/polyamide-6-based composites as electrically insulating materials having enhanced thermal conductivity and elastic modulus10.1016/j.compscitech.2017.01.022 ↗
12. Polymer nanocomposites based on functionalized carbon nanotubes10.1016/j.progpolymsci.2010.03.002 ↗
13. Carbon nanotube-polymer composites: chemistry, processing, mechanical and electrical properties10.1016/j.progpolymsci.2009.09.003 ↗
14. Noncovalent compatibilization of polypropylene/MWCNT composites using an amino-pyridine grafted polypropylene matrix10.1002/pc.23475 ↗
15. In-situ polymerization and multifunctional properties of surface-modified multiwalled carbon nanotube-reinforced polyimide nanocomposites10.1177/0954008316657862 ↗
16. Recent advances in covalent functionalization of carbon nanomaterials with polymers: strategies and perspectives10.1002/pola.28426 ↗
17. Effects of covalent functionalization on the thermal transport in carbon nanotube/polymer composites: a multi-scale investigation10.1016/j.polymer.2014.11.062 ↗
18. Structural properties of the multiwall carbon nanotubes/poly(methyl methacrylate) nanocomposites: effect of the multiwall carbon nanotubes covalent functionalization10.1002/pc.23996 ↗
19. Role of interfacial interactions to control the extent of wrapping of polymer chains on multi-walled carbon nanotubes10.1039/C6RA06258J ↗
20. Dispersion of carbon nanotubes in water by self-assembled micelles of branched amphiphilic multifunctional copolymers with photosensitivity and electroactivity10.1039/C4TA02297A ↗
21. Rational design of multiamphiphilic polymer compatibilizers: versatile solubility and hybridization of noncovalently functionalized CNT nanocomposites10.1021/acsami.5b01849 ↗
22. Selective and reversible noncovalent functionalization of single-walled carbon nanotubes by a pH-responsive vinylogous tetrathiafulvalene-fluorene copolymer10.1021/ja409918n ↗
23. One-pot polymer conjugation on carbon nanotubes through simultaneous π–π stacking and the Biginelli reaction10.1016/j.polymer.2015.02.033 ↗
24. Wrapping carbon nanotubes with poly (sodium 4-styrenesulfonate) for enhanced adsorption of methylene blue and its mechanism10.1016/j.cej.2014.06.020 ↗
25. Carbon nanotube adsorptive materials derived from acid degradable poly(acetals)10.1021/ma500009s ↗
26. Interactions between polymers and carbon nanotubes: a molecular dynamics study10.1021/jp0442403 ↗
27. Carbon nanotube/epoxy resin composites using a block copolymer as a dispersing agent10.1002/pssa.200409065 ↗
28. Functionalization of carbon nanotubes for fabrication of CNT/epoxy nanocomposites
29. Evidences for π-interactions between pyridine modified copolymer and carbon nanotubes and its role as a compatibilizer in poly(methyl methacrylate) composites10.1016/j.compscitech.2013.02.012 ↗
30. Use of unmodified SiO2 as nanofiller to improve mechanical properties of polymer-based nanocomposites10.1016/j.compscitech.2013.09.018 ↗
31. Use of ionic monomers to prepare halloysite polymer nanocomposites with reinforced mechanical performance10.1016/j.clay.2017.03.003 ↗
32. Carbon nanotube-polyaniline composites10.1016/j.progpolymsci.2013.08.009 ↗
33. Design of superior conductive polymer composite with precisely controlling carbon nanotubes at the interface of a co-continuous polymer blend via a balance of π-π interactions and dipole-dipole interactions10.1016/j.carbon.2016.12.048 ↗
34. Modification of maleic anhydride-styrene copolymer with noradrenaline by chemical and enzymatic methods10.1002/app.34357 ↗
35. Structure and properties of buckypapers based on poly(methyl methacrylate-co-methacrylic acid)/polyamide 6,6 and carbon nanotube intercalated montmorillonite10.1177/0021998315586079 ↗
36. Bulk polymerized polystyrene in the presence of multiwalled carbon nanotubes10.1007/s00396-006-1599-z ↗
37. Incorporation of a new alkenyl-based nonionic surfmer into acrylic latexes10.1002/pola.20259 ↗
38. Preparation of copolymer particles by emulsion polymerization using a polymerizable amphiphilic macromonomer10.1016/j.colsurfa.2008.08.014 ↗
39. A comparative study on effect of aromatic polyimide chain conformation on reinforcement of carbon nanotube/polyimide nanocomposites10.1002/app.40479 ↗
40. Improving the filler dispersion of polychloroprene/carboxylated multi-walled carbon nanotubes composites by non-covalent functionalization of carboxylated ionic liquid10.1016/j.compscitech.2015.12.017 ↗
41. The synthesis of polyacrylonitrile/carbon nanotube microspheres by aqueous deposition polymerization under ultrasonication10.1016/j.carbon.2009.10.013 ↗
42. Preparation, characterization and properties of polycaprolactone diol-functionalized multi-walled carbon nanotube/thermoplastic polyurethane composite10.1016/j.compositesa.2014.10.028 ↗
43. Polyethylene multiwalled carbon nanotube composites10.1016/j.polymer.2005.06.094 ↗
44. Polybenzoxazine/single-walled carbon nanotube nanocomposites stabilized through noncovalent bonding interactions10.1016/j.polymer.2014.02.061 ↗
45. The effect of a doubly modified carbon nanotube derivative on the microstructure of epoxy resin10.1016/j.polymer.2013.12.012 ↗
46. Molecular dynamics simulations of orientation induced interfacial enhancement between single walled carbon nanotube and aromatic polymers chains10.1016/j.compositesa.2015.02.027 ↗
47. A noncovalent compatibilization approach to improve the filler dispersion and properties of polyethylene/graphene composites10.1021/am404979g ↗