journal article·2014-05

Sustainable waterborne polyurethane ionomer reinforced poly(vinyl alcohol) composite films

Chang-Lian Xu, Jian-Bing Zeng, Yu-Zhong Wang

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Abstract

Abstract Poly(vinyl alcohol) (PVA) was successfully reinforced by castor oil based waterborne polyurethane ionomer (PUI) synthesized from castor oil, dimethylolpropionic acid, 4,4′-methylenediphenyl diisocyanate, and triethylamine. The average diameter of PUI determined by dynamic light scattering and transmission electron microscope was around 45 nm. The size of dispersed PUI in PVA/PUI composite was in the ranges of 1.2–3.7 μm with varying PUI content from 1 wt.% to 7 wt.%. The storage modulus of PVA/PUI composite films determined by dynamic mechanical analysis was much higher than that of neat PVA film and increased first and then decreased with the content of PUI. PVA/PUI with 3 wt.% PUI showed the highest storage modulus. The reinforcement effect was also demonstrated by tensile test from the enhancement in Young’s modulus and tensile strength. The UV/vis spectra analysis suggested that the transparency of PVA was seldom influenced by incorporation of PUI.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Polymer composites and self-healing · Polymer Nanocomposites and Properties · Dielectric materials and actuators

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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