Synthesis and characterization of polyaniline rubber composites
Source abstract
Abstract
Abstract Composite films of polyaniline and synthetic rubber ( cis -1,4-polyisoprene) were studied to understand the charge transport under pressure and temperature. Films of different compositions were prepared to measure current–voltage curves across the film thickness. The results reveal that these materials exhibit electrical conductivity as predicted by the classical theory of percolation. This has been discussed in the light of microscopic interaction between rubber and polyaniline aggregates. Pressure dependent electrical conductivity of these composites can be best explored to develop low cost pressure sensing materials.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Conducting polymers and applications · Advanced Sensor and Energy Harvesting Materials · Analytical Chemistry and Sensors
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (58)
Show source-provided references
1. Plastic electronics
2. Electrical conductivity in doped polyacetylene10.1103/PhysRevLett.39.1098 ↗
3. Plastic that conduct electricity10.1038/scientificamerican0288-106 ↗
4. Polyaniline: preparation of a conducting polymer10.1351/pac200274050857 ↗
5. Dimercaptan–polyaniline composite electrodes for lithium batteries with high energy density10.1038/373598a0 ↗
6. Rodriguez · 1997 · vol. 2
7. Comparison of different synthetic routes for sulphonation of polyaniline10.1016/0032-3861(92)90288-8 ↗
8. A switchable self-doped polyaniline: interconversion between self-doped and non-self-doped forms10.1021/ja038499v ↗
9. Synthesis of dendritic polyaniline nanofibers in a surfactant gel10.1021/ma035891k ↗
10. XPS study of self-doped conducting polyaniline and parent systems10.1021/ma00015a030 ↗
11. Synthesis of water-soluble self-acid-doped polyaniline10.1021/ja00096a078 ↗
12. Water-soluble self-doped conducting polyaniline copolymer10.1021/ma991626g ↗
13. The effects of composition and processing variables on the properties of thermoplastic polyaniline blends10.1023/A:1012480120667 ↗
14. Excluded-volume explanation of Archie’s law10.1103/PhysRevB.33.3618 ↗
15. Percolation thresholds in the three-dimensional sticks system10.1103/PhysRevLett.52.1465 ↗
16. Invariant properties of the percolation thresholds in the soft-core-hard-core transition10.1103/PhysRevA.35.5174 ↗
17. Conducting polyaniline nanoparticle blends with extremely low percolation thresholds10.1021/ma00115a029 ↗
18. Doping-dependent studies of the Anderson–Mott localization in polyaniline at the metal–insulator boundary
19. Dissipative structure formation in colloidal systems10.1002/adma.19930050418 ↗
20. Dispersion-induced insulator-to-metal transition in polyaniline10.1007/PL00013668 ↗
21. Polyaniline: a new concept in conducting polymers10.1016/0379-6779(87)90893-9 ↗
22. Synthesis of highly conducting polyaniline with photochromic azobenzene side groups10.1021/ma025584z ↗
23. A class of conducting polymers having nonconjugated backbones10.1021/ma00181a021 ↗
24. Electrical conduction in a nonconjugated polymer doped with SnCl4 and SbCl510.1002/polb.1994.090321216 ↗
25. Morphology and thermal properties of conductive polyaniline–polyamide composite films10.1002/polb.10316 ↗
26. Well-dispersed multi-walled carbon nanotube-polyaniline composite films10.1007/s10008-004-0589-7 ↗
27. Structural investigation of the effect of aging on conducting polyanilines10.1016/S0379-6779(98)00820-0 ↗
28. Thermal properties of polyaniline and poly (aniline-co-o-ethylaniline)10.1021/ma00123a019 ↗
29. Anhydrous halogen acid interaction with polyaniline membranes: A gas permeability study10.1021/jp953416l ↗
30. In situ electron spin resonance and cyclic voltammetric studies of polyaniline10.1016/0379-6779(89)90300-7 ↗
31. Thermal treatment and oxygen exposure dependence of the electronic structure of polyaniline: an X-ray photoelectron spectroscopy approach10.1016/0379-6779(91)91181-9 ↗
32. Thermal analysis of polyaniline Part I. Thermal degradation of HCl-doped emeraldine base10.1016/0379-6779(91)91770-B ↗
33. Thermal stabilities of polyanilines10.1016/0379-6779(91)91180-I ↗
34. 1987
35. Study of the thermomechanical and electrical properties of conducting composites containing natural rubber and carbon black10.1002/app.26689 ↗
36. Conductive composites of natural rubber and carbon black for pressure sensors10.1016/S0379-6779(02)00866-4 ↗
37. Stauffer · 1992
38. Tunneling and percolation in metal–insulator composite materials
39. Electrical permittivity and conductivity of carbon black-polyvinyl chloride composites10.1063/1.330027 ↗
40. Anisotropic percolation in carbon black–polyvinylchloride composites10.1016/0038-1098(83)90984-5 ↗
41. Reversible thermal fusing model of carbon black current- limiting thermistors10.1103/PhysRevB.62.9390 ↗
42. Controlling percolation in field-structured particle observations of giant thermoresistance, piezoresistance, and composites: chemiresistance10.1103/PhysRevB.67.094207 ↗
43. Systematic conductivity behavior in conducting polymers: effects of heterogeneous disorder10.1002/1521-4095(200107)13:12/13<927::AID-ADMA927>3.0.CO;2-B ↗
44. In-situ polymerized polyaniline films10.1016/S0379-6779(99)00105-8 ↗
45. Synthesis and physical properties of highly sulfonated polyaniline10.1021/ja952277i ↗
46. Transport and EPR studies of polyaniline: a quasi-one-dimensional conductor with three-dimensional ‘‘metallic’’ states10.1103/PhysRevB.45.4190 ↗
47. Three dimensionality of ‘‘metallic’’ states in conducting polymers: polyaniline10.1103/PhysRevLett.66.1745 ↗
48. Hopping in disordered conducting polymers10.1103/PhysRevB.50.5196 ↗
49. Scher · J Chem Phys · 1970 · 53 · 375910.1063/1.1674565 ↗
50. Percolation exponents and thresholds obtained from the nearly ideal continuum percolation system graphite-boron nitride10.1103/PhysRevB.56.1236 ↗
51. Measurement and interpretation of nonuniversal critical exponents in disordered conductor–insulator composites10.1103/PhysRevB.52.12477 ↗
52. Temperature and magnetic-field dependence of the resistivity of carbon–black polymer composites10.1103/PhysRevB.55.452 ↗
53. Conducting polymer composites of soluble polythiophenes in polystyrene10.1016/0379-6779(87)90573-X ↗
54. Synthesis of highly conducting polystyrene-polyacetylene copolymers10.1016/0032-3861(85)90164-8 ↗
55. Granular metal films10.1016/B978-0-12-002906-8.50007-X ↗
56. Scher and Zallen criterion: applicability to composite systems10.1103/PhysRevB.35.8749 ↗
57. Tunneling and nonuniversal conductivity in composite materials10.1103/PhysRevLett.59.1305 ↗
58. Percolation conductivity in W–Al2O3 granular metal films10.1103/PhysRevLett.35.247 ↗