journal article·2020-05

Homogeneously dispersed urchin-structured Fe3O4 with graphitic carbon spines inside poly(vinylidene fluoride) for efficient thermal conduction

Chunyu Du, Min Cao, Mei Li, Hong Guo, Rukang Liu, Baoan Li

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Abstract

Abstract Noteworthy improvements of functional composite materials that combine excellent thermal conductivity and superior mechanical strength have induced the rapid development of thermal management technology. However, the frustrating dispersion of fillers leads to phonon scattering, thereby hindering the thermal conduction in the polymer matrix. This study reports an urchin-structured filler that is obtained via hydrothermal synthesis and subsequent graphitic carbon coating and its application in thermally conductive composites. The obtained composites exhibit high thermal conductivity at low filler loadings (2.306 W/m·K, 5 wt%) and excellent stability of the thermal conductivity with the change of the operating temperature. The high thermal conductivity is attributed to the improved dispersibility of the urchin-structured filler according to Agari's model. This work paves a new way for the synthesis of reinforced fillers in thermally conductive composites.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Thermal properties of materials · Tribology and Wear Analysis · Carbon Nanotubes in Composites

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References (45)

Show source-provided references
1. Thermal conductivity of polymer-based composites: fundamentals and applications10.1016/j.progpolymsci.2016.03.001 ↗
2. Review of thermal conductivity in composites: mechanisms, parameters and theory10.1016/j.progpolymsci.2016.05.001 ↗
3. Recent advances in research on carbon nanotube-polymer composites10.1002/adma.200901545 ↗
4. Thermal conductivity of carbon nanotubes and their polymer nanocomposites: a review10.1016/j.progpolymsci.2010.11.004 ↗
5. A review on thermally conductive polymeric composites: classification, measurement, model and equations, mechanism and fabrication methods10.1007/s42114-018-0031-8 ↗
6. Synergetic effects of graphene platelets and carbon nanotubes on the mechanical and thermal properties of epoxy composites10.1016/j.carbon.2010.10.014 ↗
7. Preparation and characterization of thermal conductive composite membranes of aligned esterified carbon nanotubes/poly(vinylidene fluoride)10.1080/03602559.2014.935403 ↗
8. Paving thermally conductive highway by 3D interconnected framework of carbon nanotube and graphene oxide in poly(vinylidene fluoride)10.1016/j.compositesa.2018.09.024 ↗
9. Largely enhanced thermal conductivity of poly(vinylidene fluoride)/carbon nanotube composites achieved by adding graphene oxide10.1016/j.carbon.2015.04.040 ↗
10. Enhanced thermal and mechanical properties of polyvinlydene fluoride composites with magnetic oriented carbon nanotube10.1016/j.carbon.2017.10.027 ↗
11. Preparation of polyvinylidene fluoride/expanded graphite composites with enhanced thermal conductivity via ball milling treatment10.1039/C6RA09521F ↗
12. Thermal conductivity of graphene/poly(vinylidene fluoride) nanocomposite membrane10.1016/j.matdes.2016.11.010 ↗
13. Mussel-Inspired and magnetic Co-functionalization of hexagonal boron nitride in polyvinylidene fluoride composites towards enhanced thermal and mechanical performance for heat exchanger10.1021/acsami.8b14154 ↗
14. Hybrid network structure and thermal conductive properties in poly(vinylidene fluoride) composites based on carbon nanotubes and graphene nanoplatelets10.1016/j.compositesa.2016.08.029 ↗
15. Largely enhanced thermal conductivity and high dielectric constant of poly(vinylidene fluoride)/boron nitride composites achieved by adding a few carbon nanotubes10.1021/acs.jpcc.5b12651 ↗
16. Improved thermal conductivity and flame retardancy in polystyrene/poly(vinylidene fluoride) blends by controlling selective localization and surface modification of SiC nanoparticles10.1021/am401703m ↗
17. Thermal conductivity of PVDF/PANI-nanofiber composite membrane aligned in an electric field10.1016/j.cjche.2017.12.015 ↗
18. Dielectric properties and thermal conductivity of PVDF reinforced with three types of Zn particles10.1016/j.compositesa.2015.09.004 ↗
19. Thermal conductivity and dielectric properties of Al/PVDF composites10.1016/j.compositesa.2011.11.024 ↗
20. Anisotropic thermal conductive properties of hot-pressed polystyrene/graphene composites in the through-plane and in-plane directions10.1016/j.compscitech.2015.01.015 ↗
21. Synergistic effect of BN and graphene nanosheets in 3D framework on the enhancement of thermal conductive properties of polymeric composites10.1016/j.compscitech.2016.09.013 ↗
22. Highly anisotropic graphene/boron nitride hybrid aerogels with long-range ordered architecture and moderate density for highly thermally conductive composites10.1016/j.carbon.2017.10.011 ↗
23. Highly thermal conductive composites with polyamide-6 covalently-grafted graphene by an in situ polymerization and thermal reduction process10.1016/j.carbon.2013.09.041 ↗
24. Highly thermally conductive flame-retardant epoxy nanocomposites with reduced ignitability and excellent electrical conductivities10.1016/j.compscitech.2016.12.015 ↗
25. Synergetic enhancement of thermal conductivity by constructing hybrid conductive network in the segregated polymer composites10.1016/j.compscitech.2018.03.016 ↗
26. Effect of dispersion of MWCNTs on the static and dynamic mechanical behavior of epoxy matrix nanocomposites10.1007/s10853-011-5804-1 ↗
27. Polyhedral oligomeric silsesquioxane functionalized carbon nanotubes for high thermal conductive poly(vinylidene fluoride) composite membrane10.1016/j.matdes.2018.06.052 ↗
28. Bioinspired modification of h-BN for high thermal conductive composite films with aligned structure10.1021/am507416y ↗
29. Functionalized hexagonal boron nitride nanomaterials: emerging properties and applications10.1039/C5CS00869G ↗
30. Functionalized carbon nanotubes with phosphorus- and nitrogen-containing agents: effective reinforcer for thermal, mechanical, and flame-retardant properties of polystyrene nanocomposites10.1021/acsami.6b06864 ↗
31. Surface silverized meta-aramid fibers prepared by bio-inspired poly(dopamine) functionalization10.1021/am302956h ↗
32. Self-healing, recoverable epoxy elastomers and their composites with desirable thermal conductivities by incorporating BN fillers via in-situ polymerization10.1016/j.compscitech.2018.05.038 ↗
33. Fabrication, proposed model and simulation predictions on thermally conductive hybrid cyanate ester composites with boron nitride fillers10.1016/j.compositesa.2018.02.006 ↗
34. Functionalized glass fibers cloth/spherical BN fillers/epoxy laminated composites with excellent thermal conductivities and electrical insulation properties10.1016/j.coco.2019.08.007 ↗
35. Highly conductive NiCo2S4 urchin-like nanostructures for high-rate pseudocapacitors10.1039/c3nr02958a ↗
36. Synthesis of urchin-like Co3O4 hierarchical micro/nanostructures and their photocatalytic activity10.1016/j.apsusc.2011.02.066 ↗
37. Template-free formation of uniform urchin-like α-FeOOH hollow spheres with superior capability for water treatment10.1002/adma.201104599 ↗
38. Carbon encapsulation of elemental nanoparticles by spark discharge10.1007/s10853-018-2647-z ↗
39. Graphitic encapsulation of MgO and Fe3C nanoparticles in the reaction of iron pentacarbonyl with magnesium10.1016/j.matchar.2013.04.014 ↗
40. Achieving electrical insulation, high thermal conductivity and high fracture toughness in polyamide 6/carbon nanofiber composites through the interfacial welding effect of elastomer10.1016/j.compositesa.2019.105671 ↗
41. Improved wave-transparent performances and enhanced mechanical properties for fluoride-containing PBO precursor modified cyanate ester resins and their PBO fibers/cyanate ester composites10.1016/j.compositesb.2019.107466 ↗
42. Significant improvement of thermal conductivities for BNNS/PVA composite films via electrospinning followed by hot-pressing technology10.1016/j.compositesb.2019.107070 ↗
43. Obviously improved electromagnetic interference shielding performances for epoxy composites via constructing honeycomb structural reduced graphene oxide10.1016/j.compscitech.2019.107698 ↗
44. Thermal conductivity of a polyethylene filled with disoriented short-cut carbon fibers10.1002/app.1991.070430612 ↗
45. Thermal conductivities of composites in several types of dispersion systems10.1002/app.1991.070420621 ↗