journal article·2016-06

Graphene based nanocomposites for alloy (SnO2), and conversion (Fe3O4) type efficient anodes for Li-ion battery applications

Dattakumar Mhamane, Vanchiappan Aravindan, Divya Taneja, Anil Suryawanshi, Onkar Game, Madhavi Srinivasan, Satishchandra Ogale

Publisher page

Abstract

Abstract Two types of trigol reduced one pot synthesized graphene (TRG) based nanocomposites (SnO 2 -TRG, and Fe 3 O 4 -TRG) are examined as potential anodes for Lithium ion battery (LIB) applications. The two specific systems represent different electrode reaction mechanisms, namely alloying, and conversion respectively. The high resolution transmission electron microscopy (HR-TEM) analysis confirms the uniform distribution of SnO 2 (∼2 nm), and Fe 3 O 4 (∼8 nm) particulates on ultrathin TRG nanosheets and highlights the importance of surfactant free synthesis. The SnO 2 -TRG, and Fe 3 O 4 -TRG exhibited the maximum reversible capacity of ∼947, and ∼1024 mA h g −1 , respectively. The results show that such graphene based composite materials can be effectively used as prospective anodes for LIB applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Battery Materials · Graphene research and applications · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. The Li-ion rechargeable battery: a perspective10.1021/ja3091438 ↗
2. Electrospun nanofibers: a prospective electro-active material for constructing high performance Li-ion batteries10.1039/C4CC07824A ↗
3. LiMnPO4 - a next generation cathode material for lithium-ion batteries10.1039/c2ta01393b ↗
4. Electrical energy storage for transportation-approaching the limits of, and going beyond, lithium-ion batteries10.1039/c2ee21892e ↗
5. Advances in battery technology: rechargeable magnesium batteries and novel negative-electrode materials for lithium ion batteries10.1002/1439-7641(20020215)3:2<155::AID-CPHC155>3.0.CO;2-S ↗
6. Who will drive electric vehicles, olivine or spinel?10.1039/c0ee00559b ↗
7. Batteries for electric and hybrid-electric vehicles10.1146/annurev-chembioeng-073009-100942 ↗
8. Insertion-type electrodes for nonaqueous li-ion capacitors10.1021/cr5000915 ↗
9. The development of lithium ion secondary batteries10.1002/tcr.1024 ↗
10. Li-alloy based anode materials for Li secondary batteries10.1039/b919877f ↗
11. Metal oxides and oxysalts as anode materials for li ion batteries10.1021/cr3001884 ↗
12. Nanostructured carbon and carbon nanocomposites for electrochemical energy storage applications10.1002/cssc.200900182 ↗
13. Graphene-based nanomaterials for energy storage10.1039/C0EE00295J ↗
14. Lithiation of an iron oxide-based anode for stable, high-capacity lithium-ion batteries of porous carbon–Fe3O4/Li[Ni0.59Co0.16Mn0.25]O210.1002/ente.201402031 ↗
15. Carbon nanotube (CNT)-based composites as electrode material for rechargeable Li-ion batteries: a review10.1016/j.compscitech.2011.11.019 ↗
16. Large reversible li storage of graphene nanosheet families for use in rechargeable lithium ion batteries10.1021/nl800957b ↗
17. Electrospun carbon-tin oxide composite nanofibers for use as lithium ion battery anodes10.1021/am2004015 ↗
18. Seed-assisted synthesis of highly ordered TiO2@α-Fe2O3 core/shell arrays on carbon textiles for lithium-ion battery applications10.1039/c2ee03396h ↗
19. Insertion electrode materials for rechargeable lithium batteries10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z ↗
20. Review on recent progress of nanostructured anode materials for Li-ion batteries10.1016/j.jpowsour.2013.11.103 ↗
21. Graphene and graphene oxide: synthesis, properties, and applications10.1002/adma.201001068 ↗
22. Graphene/metal oxide composite electrode materials for energy storage10.1016/j.nanoen.2011.11.001 ↗
23. Chemical methods for the production of graphenes10.1038/nnano.2009.58 ↗
24. Synthesis of water soluble graphene10.1021/nl080604h ↗
25. Environmentally friendly approaches toward the mass production of processable graphene from graphite oxide10.1039/C0JM01717E ↗
26. Atomic layer deposited (ALD) SnO2 anodes with exceptional cycleability for Li-ion batteries10.1016/j.nanoen.2012.12.007 ↗
27. Does carbon coating really improves the electrochemical performance of electrospun SnO2 anodes?10.1016/j.electacta.2013.12.141 ↗
28. Mesoscopic magnetic iron oxide spheres for high performance Li-ion battery anode: a new pulsed laser induced reactive micro-bubble synthesis process10.1039/c3ta12790g ↗
29. Trigol based reduction of graphite oxide to graphene with enhanced charge storage activity10.1039/c2jm30582h ↗
30. Hierarchically nanoperforated graphene as a high performance electrode material for ultracapacitors10.1002/smll.201202670 ↗
31. Processable aqueous dispersions of graphene nanosheets10.1038/nnano.2007.451 ↗
32. Ternary self-assembly of ordered metal oxide−graphene nanocomposites for electrochemical energy storage10.1021/nn901819n ↗
33. Self-assembled TiO2–graphene hybrid nanostructures for enhanced Li-ion insertion10.1021/nn900150y ↗
34. Enhancing the catalytic activity of Pt nanoparticles using poly sodium styrene sulfonate stabilized graphene supports for methanol oxidation10.1039/c2ta00619g ↗
35. The direct growth of gold rods on graphene thin films10.1039/c002002h ↗
36. Self-assembly of cationic polyelectrolyte-functionalized graphene nanosheets and gold nanoparticles: a two-dimensional heterostructure for hydrogen peroxide sensing10.1021/la100575g ↗
37. Magnetic iron oxide nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations, and biological applications10.1021/cr068445e ↗
38. Non agglomerated, submicron α–Fe2O3 particles: preparation and application10.1557/JMR.2000.0322 ↗
39. Polyol-mediated preparation of nanoscale oxide particles10.1002/1521-3773(20010119)40:2<359::AID-ANIE359>3.0.CO;2-B ↗
40. Sub-micrometer CoAl2O4 pigment particles −synthesis and preparation of coatings10.1039/a910201i ↗
41. Tin-based amorphous oxide: a high-capacity lithium-ion-storage material10.1126/science.276.5317.1395 ↗
42. Electrochemical and in situ X-Ray diffraction studies of the reaction of lithium with tin oxide composites10.1149/1.1837740 ↗
43. Key factors controlling the reversibility of the reaction of lithium with SnO2 and Sn2BPO6 glass10.1149/1.1837941 ↗
44. Tin-based materials as negative electrodes for Li-ion batteries: combinatorial approaches and mechanical methods10.1002/er.1669 ↗
45. Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries10.1038/35035045 ↗
46. Iron-based cathodes/anodes for Li-ion and post Li-ion batteries
47. Non-aqueous energy storage devices using graphene nanosheets synthesized by green route10.1063/1.4802243 ↗