journal article·2019-09

Bio-inspired incorporation of functionalized graphene oxide into carbon nanotube fibers for their efficient mechanical reinforcement

Young-Jin Kim, Junbeom Park, Cheol-Min Yang, Hyeon Su Jeong, Seung Min Kim, Sang Woo Han, Beomjoo Yang, Young-Kwan Kim

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Abstract

Abstract An efficient strategy for the enhancement of mechanical properties of carbon nanotube (CNT) fibers is developed using functionalized graphene oxide with a quaternary ammonium (QA) group (QA-FGO). QA-FGO is designed to induce the π-cation interaction, one of the strongest interactions in living systems, with CNT fibers. Based on the strategy, the tensile strength (58 MPa), specific strength (0.49 N/tex), modulus (2.5 GPa) and toughness (1.1 MJ/m3) of CNT fibers are enhanced to 409 MPa, 0.65 N/tex, 13.4 GPa, and 10.1 MJ/m3, respectively. The reinforcement mechanism is systematically demonstrated with experimental and theoretical approaches.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Graphene research and applications · Carbon Nanotubes in Composites · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Electronic, thermal and mechanical properties of carbon nanotubes10.1098/rsta.2004.1430 ↗
2. Carbon nanotube-based neat fibers10.1016/S1748-0132(08)70062-8 ↗
3. High-performance carbon nanotube fiber10.1126/science.1147635 ↗
4. Influence of carbon nanotube characteristics on macroscopic fiber properties10.1021/acsami.7b10968 ↗
5. Multifunctional carbon nanotube yarns by downsizing an ancient technology10.1126/science.1104276 ↗
6. Enhancement of the mechanical properties of directly spun CNT fibers by chemical treatment10.1021/nn202685x ↗
7. Liquid infiltration into carbon nanotube fibers: effect on structure and electrical properties10.1021/nn401337m ↗
8. Hierarchical structure of carbon nanotube fibers, and the change of structure during densification by wet stretching10.1016/j.carbon.2018.04.071 ↗
9. Effect of polymer infiltration on structure and properties of carbon nanotube yarns10.1016/j.carbon.2015.02.065 ↗
10. High-strength carbon nanotube/carbon composite fibers via chemical vapor infiltration10.1039/C6NR06479E ↗
11. Post-treatments for multifunctional property enhancement of carbon nanotube fibers from the floating catalyst method10.1021/acsami.5b09912 ↗
12. High-strength carbon nanotube fibre-like ribbon with high ductility and high electrical conductivity10.1038/ncomms4848 ↗
13. Multifunctionalization of carbon nanotube fibers with the aid of graphene wrapping10.1039/c2jm32978f ↗
14. Improvements in the mechanical properties of carbon nanotube fibers through graphene oxide interlocking10.1016/j.carbon.2015.11.008 ↗
15. Positive synergistic effect of graphene oxide/carbon nanotube hybrid coating on glass fiber/epoxy interfacial normal bond strength10.1016/j.compscitech.2017.06.024 ↗
16. Tailoring anisotropic thermal properties of reduced graphene oxide/multi-walled carbon nanotube hybrid composite films10.1016/j.compscitech.2017.07.015 ↗
17. Mimicking mussel adhesion to improve interfacial properties in composites10.1016/j.compscitech.2008.02.036 ↗
18. Cation–π interaction in DOPA-deficient mussel adhesive protein mfp-110.1039/C4TB01646G ↗
19. Salt triggers the simple coacervation of an underwater adhesive when cations meet aromatic π electrons in seawater10.1021/acsnano.7b01370 ↗
20. The structural influence of graphene oxide on its fragmentation during laser desorption/ionization mass spectrometry for efficient small molecule analysis10.1002/chem.201404067 ↗
21. Covalent functionalization based heteroatom doped graphene nanosheet as a metal-free electrocatalyst for oxygen reduction reaction10.1039/c3nr03581f ↗
22. From molecules to solids with the DMol 3 approach10.1063/1.1316015 ↗
23. Fluorine atoms interaction with the nanoporous materials: experiment and DFT simulation10.1140/epjd/e2017-70619-7 ↗
24. A combined molecular dynamics/micromechanics/finite element approach for multiscale constitutive modeling of nanocomposites with interface effects10.1063/1.4819383 ↗
25. Adhesion enhancement and damage protection for carbon fiber-reinforced polymer (CFRP) composites via silica particle coating10.1016/j.compositesa.2018.02.042 ↗
26. Strain rate and adhesive energy dependent viscoplastic damage modeling for nanoparticulate composites: molecular dynamics and micromechanical simulations10.1063/1.4868034 ↗
27. Signal‐induced release of guests from a photolatent metal–phenolic supramolecular cage and its hybrid assemblies10.1002/anie.201701152 ↗
28. COMPASS II: extended coverage for polymer and drug-like molecule databases10.1007/s00894-016-2909-0 ↗
29. Multiscale prediction of thermal conductivity for nanocomposites containing crumpled carbon nanofillers with interfacial characteristics10.1016/j.compscitech.2017.12.011 ↗
30. Simultaneous reduction and functionalization of graphene oxide by polyallylamine for nanocomposite formation10.5714/CL.2012.13.1.029 ↗
31. Highly dispersed palladium nanoparticles on poly(N1,N3-dimethylbenzimidazolium)iodide-functionalized multiwalled carbon nanotubes for ethanol oxidation in alkaline solution10.1039/C6RA19256D ↗
32. Facile supramolecular processing of carbon nanotubes and polymers for electromechanical sensors10.1002/anie.201708111 ↗
33. Effect of chemisorption on the interfacial bonding characteristics of graphene− polymer composites10.1021/jp100110n ↗
34. Characterizing thermal and mechanical properties of graphene/epoxy nanocomposites10.1016/j.compositesb.2013.09.007 ↗