journal article·2013-03

Fiber association and network formation in PLA/lignocellulosic fiber composites

G. Faludi, J. Hári, K. Renner, J. Móczó, B. Pukánszky

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Abstract

Abstract PLA composites were prepared in an internal mixer with a lignocellulosic fiber having relatively large aspect ratio. Fiber content changed between 0 and 60 vol.% and the homogenized material was compression molded to 1 mm thick plates. The composites showed anomalous behavior above certain fiber content. Their modulus and especially their strength decreased drastically and modeling also proved the loss of reinforcement at large fiber contents. Micromechanical testing showed that the mechanism of deformation and failure changes at a critical fiber content. Microscopic analysis indicated the formation of a network purely from geometrical reasons. The inherent strength of the network is very small because of the weak forces acting among the fibers. This weak inherent strength makes the structure of the composites very sensitive to processing conditions, and decreases strength, reproducibility as well as reliability.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: biodegradable polymer synthesis and properties · Natural Fiber Reinforced Composites · Polymer Foaming and Composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (52)

Show source-provided references
1. Poly(lactic acid): plasticization and properties of biodegradable multiphase systems10.1016/S0032-3861(01)00086-6 ↗
2. Tributyl citrate oligomers as plasticizers for poly (lactic acid): thermo-mechanical film properties and aging10.1016/j.polymer.2003.09.055 ↗
3. Plasticization of poly(L-lactide) with poly(propylene glycol)10.1021/bm060089m ↗
4. Thermo-mechanical characterization of plasticized PLA: Is the miscibility the only significant factor?10.1016/j.polymer.2006.04.013 ↗
5. Plasticization of poly(lactide) with blends of tributyl citrate and low molecular weight poly(D, L-lactide)-b-poly(ethylene glycol) copolymers10.1016/j.eurpolymj.2009.07.006 ↗
6. Synthesis of poly(lactic acid-b-p-dioxanone) block copolymers from ring opening polymerization of p-dioxanone by poly(L-lactic acid) macroinitiators10.1007/s00289-008-0939-1 ↗
7. Thermo mechanical properties of stereoblock poly(lactic acid)s with different PLLA/PDLA block compositions10.1016/j.polymer.2008.04.014 ↗
8. Synthesis and characterization of TPO-PLA copolymer and its behavior as compatibilizer for PLA/TPO blends10.1016/j.polymer.2008.06.054 ↗
9. Surface characterization of poly(L-lactic acid)-methoxy poly(ethylene glycol) diblock copolymers by static and dynamic contact angle measurements, FTIR, and ATR-FTIR10.1021/la701966d ↗
10. Effects of synthesis conditions on chemical structures and physical properties of copolyesters from lactic acid, ethylene glycol and dimethyl terephthalate10.3144/expresspolymlett.2009.56 ↗
11. Synthesis and characterizations of degradable aliphatic-aromatic copolyesters from lactic acid, dimethyl terephthalate and diol: effects of diol type and monomer feed ratio10.3144/expresspolymlett.2010.52 ↗
12. New development on plasticized poly(lactide): chemical grafting of citrate on PLA by reactive extrusion10.1016/j.eurpolymj.2011.12.001 ↗
13. Melt rheology of polylactide/poly(butylene adipate-co-terephthalate) blends10.1016/j.carbpol.2008.01.017 ↗
14. Poly(D, L-lactide)/poly(methyl methacrylate) interpenetrating polymer networks: synthesis, characterization, and use as precursors to porous polymeric materials10.1016/j.polymer.2007.09.044 ↗
15. Mechanical properties of biodegradable composites from poly lactic acid (PLA) and microcrystalline cellulose (MCC)10.1002/app.21779 ↗
16. Biodegradation of poly(lactic acid)/starch/coir biocomposites under controlled composting conditions10.1016/j.polymdegradstab.2007.10.011 ↗
17. Compostability and biodegradation study of PLA-wheat straw and PLA-soy straw based green composites in simulated composting bioreactor10.1016/j.biortech.2010.06.053 ↗
18. Rothon · 2003
19. Twin-screw extrusion compounding of mineral filled thermoplastics – dispersive mixing effects
20. Aggregation of particulate fillers: factors, determination, properties10.1002/masy.200390071 ↗
21. Agglomeration
22. Powder compaction and interface shear: adhesion of solids
23. Forces between particles in continuous and discrete liquid media
24. Surface energy determinations of wood: comparison of methods and wood species10.1021/la001080n ↗
25. Investigation on the surface properties of chemically modified natural fibers using inverse gas chromatography10.1016/j.carbpol.2011.11.001 ↗
26. ‘Green’ composites from soy based plastic and pineapple leaf fiber: fabrication and properties evaluation10.1016/j.polymer.2005.01.027 ↗
27. Injection molded biocomposites from soy protein based bioplastic and short industrial hemp fiber10.1007/s10924-005-4762-6 ↗
28. Effect of fiber surface-treatments on the properties of laminated biocomposites from poly(lactic acid) (PLA) and kenaf fibers10.1016/j.compscitech.2007.06.022 ↗
29. Mechanical-properties of surface-modified cellulose fiber thermoplastic composites10.1021/bk-1992-0476.ch006 ↗
30. Reinforcing high-density polyethylene with cellulosic fibers. 1. The effect of additives on fiber dispersion and mechanical-properties10.1002/pen.760311811 ↗
31. Effect of various surface modifications of wood flour on the properties of PP/wood composites10.1016/j.compositesa.2009.10.008 ↗
32. Dora G., Faludi G., Imre B., Renner K., Móczó J., Pukánszky B.: PLA/Lignocelulosic Fiber Composites: Interfacial Adhesion and Failure Mechanism. Compos Part A: Appl Sci Manuf; 2012 (Submitted).10.1002/app.39902 ↗
33. Impact and tensile properties of PLA/Cordenka and PLA/flax composites10.1016/j.compscitech.2008.01.004 ↗
34. Biodegradable composites based on – polylactide and jute fibres10.1016/S0266-3538(03)00100-3 ↗
35. Wood–fiber-reinforced poly(lactic acid) composites: Evaluation of the physicomechanical and morphological properties10.1002/app.24829 ↗
36. “Green” composites from recycled cellulose and poly(lactic acid): Physico-mechanical and morphological properties evaluation10.1007/s10853-005-1998-4 ↗
37. Natural fibres as reinforcement in polylactic acid (PLA) composites10.1016/S0266-3538(03)00103-9 ↗
38. Mechanical properties of PLA composites with man-made cellulose and abaca fibres10.1016/j.compositesa.2009.01.002 ↗
39. Effect of matrix-particle interfacial adhesion on the mechanical properties of poly(lactic acid)/wood-flour micro-composites10.1007/s10924-009-0124-0 ↗
40. Extrusion of five biopolymers reinforced with increasing wood flour concentration on a production machine, injection moulding and mechanical performance10.1016/j.compositesa.2009.05.023 ↗
41. The effect of crystallization of PLA on the thermal and mechanical properties of microfibrillated cellulose-reinforced PLA composites10.1016/j.compscitech.2009.02.022 ↗
42. Biocomposite from polylactic acid and lignocellulosic fibers: structure-property correlations10.1016/j.carbpol.2012.11.006 ↗
43. Influence of interface interaction on the ultimate tensile properties of polymer composites10.1016/0010-4361(90)90240-W ↗
44. Aggregation of CaCO3 particles in PP composites: effect of surface coating10.1016/j.compscitech.2006.07.010 ↗
45. Formation and Detection of clay network structure in poly(propylene)/layered silicate nanocomposites10.1002/marc.200500687 ↗
46. Study on rheological behavior of polypropylene/clay nanocomposites10.1002/app.12643 ↗
47. Dispersed structure change of smectic clay/poly(methyl methacrylate) nanocomposites by copolymerization with polar comonomers10.1016/S0032-3861(00)00419-5 ↗
48. Nanocomposites based on layered silicate and miscible PVDF/PMMA blends: melt preparation, nanophase morphology and rheological behaviour10.1016/j.polymer.2003.10.053 ↗
49. A house of cards structure in polypropylene/clay nanocomposites under elongational flow10.1021/nl0100163 ↗
50. Network formation in polymer nanocomposites under shear10.1039/c0sm00990c ↗
51. Rheology, compounding and processing of filled thermoplastics
52. The thermal and electrical conductivity of two-phase systems10.1021/i160049a004 ↗