journal article·2013-10

Novel silicon-modified phenolic novolacs and their biofiber-reinforced composites: Preparation, characterization and performance

Cheng Li, Hong Fan, De-Yi Wang, Jijiang Hu, Jintao Wan, Bogeng Li

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Abstract

Abstract 4,4′-(1,3-Dipropyl-tetramethyldisiloxane)bis-2-methoxyphenol (SIE), a novel silicone-contained biphenol type monomer, is synthesized from eugenol and 1,1,3,3-tetramethyldisiloxane, and used to modify phenolic novolac through copolymerization with phenol and formaldehyde to yield SIE-modified resins (SPNs). Then, the SPNs are used as resin matrix, while surface-treated chopped sisal fiber is used as the reinforced filler to produce the novel phenolic molding composites. Eugenol and sisal are biobased renewable materials. Due to modification of SIE, the ultimate composites expressed excellent electrical resistance, low water absorption and high thermal stability compared to the normal composites. Our work provides a facile and effective way to prepare the silicone modified, biofiber-reinforced phenolic composites with improved water resistance and electric property.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Thermal and Kinetic Analysis · Epoxy Resin Curing Processes · Polymer Nanocomposites and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Pilato · 2010
2. Thermoset phenolic matrices reinforced with unmodified and surface-grafted furfuryl alcohol sugar cane bagasse and curaua fibers: properties of fibers and composites10.1021/bm058006+ ↗
3. Biobased composites from glyoxal-phenolic resins and sisal fibers10.1016/j.biortech.2009.10.005 ↗
4. Chlorine dioxide treatment of sisal fibre: surface lignin and its influences on fibre surface characteristics and interfacial behaviour of sisal fibre/phenolic resin composites10.15376/biores.5.4.2431-2446 ↗
5. Influence of interfacial adhesion on the mechanical properties and fracture behaviour of short sisal fibre reinforced polymer composites10.1016/S0014-3057(96)00051-1 ↗
6. Renewable resources as reinforcement of polymeric matrices: composites based on phenolic thermosets and chemically modified sisal fibers10.1002/mabi.200700083 ↗
7. Unmodified and modified surface sisal fibers as reinforcement of phenolic and lignophenolic matrices composites: thermal analyses of fibers and composites10.1002/mame.200500334 ↗
8. Thermoset matrix reinforced with sisal fibers: effect of the cure cycle on the properties of the biobased composite10.1016/j.polymertesting.2009.07.001 ↗
9. Electrical properties of short sisal fiber reinforced polyester composites fabricated by resin transfer molding10.1016/j.compositesa.2011.11.018 ↗
10. Application of glass-nonmetals of waste printed circuit boards to produce phenolic moulding compound10.1016/j.jhazmat.2007.09.029 ↗
11. Cardanol–formaldehyde thermoset composites reinforced with buriti fibers: preparation and characterization10.1016/j.compositesa.2010.04.010 ↗
12. Design and evaluation of bio-based composites for printed circuit board application10.1016/j.compositesa.2012.11.014 ↗
13. Differential scanning calorimetry of epoxy resins10.1016/0032-3861(68)90024-4 ↗
14. The application of differential scanning calorimetry (DSC) to the study of epoxy resin curing reactions10.1007/3-540-15546-5_5 ↗
15. Modeling of curing reaction kinetics in liquid-crystalline epoxy resins10.1021/ie9606810 ↗
16. Kinetic studies of the polymerization of an epoxy resin modified with rhodamine B10.1016/j.tca.2009.03.015 ↗
17. Effect of molecular weight and molecular weight distribution on cure reaction of novolac with hexamethylenetetramine and properties of related composites10.1016/j.tca.2011.11.032 ↗
18. Nonisothermal curing behaviors of novolac-type phenolic resins of varied ortho to para ratios10.1080/03602559.2011.553864 ↗
19. Nonisothermal curing of a solid resole phenolic resin10.1002/app.33775 ↗
20. ICTAC kinetics committee recommendations for performing kinetic computations on thermal analysis data10.1016/j.tca.2011.03.034 ↗
21. Isoconversional kinetic analysis of thermally stimulated processes in polymers10.1002/marc.200600404 ↗
22. Curing kinetics of a furan resin and its nanocomposites10.1016/j.tca.2011.01.022 ↗
23. Isoconversional method to explore the mechanism and kinetics of multi-step epoxy cures10.1002/(SICI)1521-3927(19990701)20:7<387::AID-MARC387>3.0.CO;2-S ↗
24. Kinetic analysis of isothermal cures performed below the limiting glass transition temperature10.1002/(SICI)1521-3927(20000201)21:2<85::AID-MARC85>3.0.CO;2-G ↗
25. Model-free and model-fitting approaches to kinetic analysis of isothermal and nonisothermal data10.1016/S0040-6031(99)00253-1 ↗
26. Is the friedman method applicable to transformations with temperature dependent reaction heat?10.1002/macp.200700100 ↗
27. Modification of the integral isoconversional method to account for variation in the activation energy10.1002/1096-987X(20010130)22:2<178::AID-JCC5>3.0.CO;2-# ↗
28. The study of hydrogen bonding and miscibility in poly(vinylpyridines) with phenolic resin10.1016/S0032-3861(02)00214-8 ↗
29. Solid state NMR studies of hydrogen bonding network formation of novolac type phenolic resin and poly(ethylene oxide) blend10.1016/S0032-3861(99)00098-1 ↗
30. Phase behavior and hydrogen bonding in ternary polymer blends of phenolic resin/poly(ethylene oxide)/poly(ε-caprolactone)10.1021/ma011255f ↗
31. Miscibility and hydrogen bonding in blends of poly(vinyl acetate) with phenolic resin10.1016/S0032-3861(02)00007-1 ↗
32. Hydrogen bonding in the novolac type phenolic resin blended with phenoxy resin10.1016/S0032-3861(97)00067-0 ↗