journal article·2013-08

Self-stratifying and orientation of exfoliated few-layer graphene nanoplatelets in epoxy composites

S.G. Prolongo, R. Moriche, M. Sánchez, A. Ureña

Publisher page

Abstract

Abstract A deep morphological study was carried out in graphene/epoxy composites reinforced with two types of nanoparticles: chemically exfoliated graphene and non-treated graphene nanoplatelets. Different morphological features, such as exfoliation, distribution, dispersion and orientation were analyzed. Composites with exfoliated graphene nanoparticles presented stratification, where few-layer graphene particles occupy top positions while thicker nanoplatelets fell down at the bottom. In order to solve this heterogeneity, a rotating mould was designed. Rotating the reinforced probes during curing treatment, up gelation, the stratification of graphene nanoplatelets could be avoided. It was also corroborated that the graphene/epoxy composites show preferential orientation, where most of graphene particles lies parallel to the sample surface, leading anisotropy in materials. This effect was specially marked in composites with thicker graphene nanoplatelets reinforcement regard to those with exfoliated nanosheets.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Graphene research and applications · Carbon Nanotubes in Composites · Fiber-reinforced polymer composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (22)

Show source-provided references
1. Recent advances in graphene based polymer composites10.1016/j.progpolymsci.2010.07.005 ↗
2. Graphene/polymer nanocomposites10.1021/ma100572e ↗
3. Trends and frontiers in graphene-based polymer nanocomposites10.1002/j.1941-9635.2011.tb00669.x ↗
4. Measurement of the elastic properties and intrinsic strength of nanolayer graphene10.1126/science.1157996 ↗
5. Superior thermal conductivity of single-layer graphene10.1021/nl0731872 ↗
6. Effective elastic mechanical properties of single layer graphene sheets10.1088/0957-4484/20/6/065709 ↗
7. Graphene-based polymer nanocomposites10.1016/j.polymer.2010.11.042 ↗
8. Exfoliation and dispersion of graphene in ethanol-water mixtures
9. Chemical and thermal reduction of graphene oxide and its electrically conductive polylactic acid nanocomposites10.1016/j.compscitech.2012.05.018 ↗
10. Electronic transport properties of individual chemically reduced graphene oxide sheets10.1021/nl072090c ↗
11. Solvothermal-assisted exfoliation process to produce graphene with high yield and high quality10.1007/s12274-009-9074-z ↗
12. Processable aqueous dispersions of graphene nanosheets10.1038/nnano.2007.451 ↗
13. Synthesis of high-performance graphene nanosheets by thermal reduction of graphene oxide10.1016/j.materresbull.2011.06.036 ↗
14. Few-layer graphene under high pressure: Raman and X-ray diffraction studies10.1016/j.ssc.2012.10.002 ↗
15. Epoxy/graphene platelets nanocomposites with two levels of interface strength10.1016/j.polymer.2011.02.003 ↗
16. Processing of expanded graphite reinforced polymer nanocomposites10.1016/j.compscitech.2005.10.014 ↗
17. A facile approach to chemically modified graphene and its polymer nanocomposites10.1002/adfm.201103041 ↗
18. Self-orientation of graphite-nanoplates induces anisotropy of nanoplates-epoxy composites10.1016/j.ceramint.2011.04.057 ↗
19. Processing-property relationship of polycarbonate/graphene composites10.1016/j.polymer.2009.05.038 ↗
20. Thermal expansion in single-walled carbon nanotubes and graphene: nonequilibrium greeńs function approach10.1103/PhysRevB.80.113405 ↗
21. Thermal stability and dynamic mechanical behavior of exfoliated graphite nanoplatelets-LLDPE nanocomposites10.1002/pc.20781 ↗
22. Effect of functionalized graphene on the physical properties of linear low density polyethylene nanocomposites10.1016/j.polymertesting.2011.09.007 ↗