journal article·2017-03

Reversible plasticity shape memory effect in epoxy/CNT nanocomposites - A theoretical study

R. Abishera, R. Velmurugan, K.V. Nagendra Gopal

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Abstract

Abstract A theoretical investigation on the reversible plasticity shape memory (RPSM) properties of Multi-Walled Carbon Nanotubes (MWCNT) reinforced epoxy nanocomposites is presented. A typical RPSM cycle involves loading and stress relaxation below the glass transition temperature and unconstrained strain recovery above glass transition temperature. This paper attempts to study the underlying mechanisms by employing a thermo-visco-elastic model incorporating structural and stress relaxation mechanisms. The effective properties of the nanocomposites were determined from basic micro-mechanics models and standard thermo-mechanical experiments. The variations in model parameters between neat and filled epoxy were studied and the influence of MWCNT on the material behavior are discussed. The simulations agreed quite well with the experimental results for both neat and filled epoxy. The model was further able to capture the thermo-mechanical behavior under different programming conditions like strain rate, strain level and relaxation time.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Polymer composites and self-healing · Shape Memory Alloy Transformations · Carbon Nanotubes in Composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (46)

Show source-provided references
2. Recent advances in polymer shape memory10.1016/j.polymer.2011.08.003 ↗
3. Reversible plasticity shape memory polymers: key factors and applications10.1002/polb.23916 ↗
4. Shape memory polymer based self-healing syntactic foam: 3-d confined thermomechanical characterization10.1016/j.compscitech.2010.04.026 ↗
5. Effect of strain hardening of shape memory polymer fibers on healing efficiency of thermosetting polymer composites10.1016/j.polymer.2012.12.046 ↗
6. Modeling shape-memory behavior of polymers10.1080/15583724.2012.751922 ↗
7. Thermomechanics of shape memory polymers: uniaxial experiments and constitutive modeling10.1016/j.ijplas.2005.03.004 ↗
8. A constitutive theory for shape memory polymers. Part I: large deformations10.1016/j.jmps.2007.12.005 ↗
9. Finite deformation thermo-mechanical behavior of thermally induced shape memory polymers10.1016/j.jmps.2007.12.002 ↗
10. A thermodynamically-consistent 3d constitutive model for shape memory polymers10.1016/j.ijplas.2012.01.007 ↗
11. Constitutive modeling of shape memory polymer based self-healing syntactic foam10.1016/j.ijsolstr.2010.01.015 ↗
12. Thermomechanical behavior of thermoset shape memory polymer programmed by cold-compression: testing and constitutive modeling10.1016/j.jmps.2011.03.001 ↗
13. A thermoviscoelastic model for amorphous shape memory polymers: incorporating structural and stress relaxation10.1016/j.jmps.2008.04.007 ↗
14. Thermomechanical constitutive model of shape memory polymer10.1016/S0167-6636(01)00075-8 ↗
15. Modeling of shape memory induction and recovery in heat-shrinkable polymers10.1002/mats.200400108 ↗
16. Finite strain 3d thermoviscoelastic constitutive model for shape memory polymers10.1002/pen.20497 ↗
17. Thermally actuated shape-memory polymers: experiments, theory, and numerical simulations10.1016/j.jmps.2010.04.004 ↗
18. Koo · 2006
19. Nanocomposites in context10.1016/j.compscitech.2004.11.003 ↗
20. Advances in the science and technology of carbon nanotubes and their composites: a review10.1016/S0266-3538(01)00094-X ↗
21. Influence of carbon nanotubes and polypyrrole on the thermal, mechanical and electroactive shape-memory properties of polyurethane nanocomposites10.1016/j.compscitech.2006.10.013 ↗
22. Improved recovery stress in multi-walled-carbon-nanotubes reinforced polyurethane10.1016/j.matdes.2014.10.062 ↗
23. An assessment of the science and technology of carbon nanotube-based fibers and composites10.1016/j.compscitech.2009.10.004 ↗
24. Facile tailoring of thermal transition temperatures of epoxy shape memory polymers10.1016/j.polymer.2009.02.035 ↗
25. Reversible plasticity shape memory effect in carbon nanotubes reinforced epoxy nanocomposites10.1016/j.compscitech.2016.10.030 ↗
26. On the large deformation behaviour of reinforced rubber at different temperatures10.1016/S0022-5096(97)00028-8 ↗
27. A theory of amorphous solids undergoing large deformations, with application to polymeric glasses10.1016/S0020-7683(02)00651-0 ↗
28. Relation between inelastic deformability and thermal expansion of glass in its annealing range10.1111/j.1151-2916.1946.tb11592.x ↗
29. Use of the adam-gibbs equation in the analysis of structural relaxation10.1111/j.1151-2916.1984.tb19643.x ↗
30. Adam-gibbs formulation of enthalpy relaxation near the glass transition10.6028/jres.102.015 ↗
31. On the temperature dependence of cooperative relaxation properties in glass-forming liquids10.1063/1.1696442 ↗
32. A three-dimensional constitutive model for the large stretch behavior of rubber elastic materials10.1016/0022-5096(93)90013-6 ↗
33. Variational and projection methods for the volume constraint in finite deformation elasto-plasticity10.1016/0045-7825(85)90033-7 ↗
34. On the kinematics of finite strain plasticity10.1016/0022-5096(89)90033-1 ↗
35. On the elastic properties of carbon nanotube-based composites: modelling and characterization10.1088/0022-3727/36/5/323 ↗
36. Halpin · 1969
37. Fiber waviness in nanotube-reinforced polymer composites: modulus predictions using effective nanotube properties10.1016/S0266-3538(03)00069-1 ↗
38. Mechanical behavior of phenolic-based composites reinforced with multi-walled carbon nanotubes10.1016/j.carbon.2005.07.005 ↗
39. A hybrid method for computing the effective properties of composites containing arbitrarily shaped inclusions10.1016/j.compstruc.2014.12.010 ↗
40. Influence of fiber waviness on the effective properties of discontinuous fiber reinforced composites10.1016/j.commatsci.2014.05.004 ↗
41. Improved mechanical properties of carbon nanotube/polymer composites through the use of carboxyl-epoxide functional group linkages10.1016/j.polymer.2010.08.063 ↗
42. Mechanical properties of multi-walled carbon nanotube/epoxy composites10.1016/j.matdes.2010.04.018 ↗
43. Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load10.1126/science.287.5453.637 ↗
44. Quantitative analysis of errors in tmdsc in the glass transition region10.1016/S0040-6031(99)00482-7 ↗
45. Viscoelastic properties and determination of free volume fraction of multi-walled carbon nanotube/epoxy composite using dynamic mechanical thermal analysis10.1016/j.matdes.2011.11.038 ↗
46. Modeling and validation of the large deformation inelastic response of amorphous polymers over a wide range of temperatures and strain rates10.1016/j.ijsolstr.2007.05.018 ↗