journal article·2010-04

Measurement of the critical aspect ratio and interfacial shear strength in MWNT/polymer composites

Renée K. Duncan, Xinyu G. Chen, J.B. Bult, L.C. Brinson, L.S. Schadler

Composites Science and Technology· Volume 70· Issue 4
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Abstract

Abstract This paper presents a bulk composite method for determining the critical aspect ratio and relative interfacial shear stress (ISS) for multiwalled carbon nanotube (MWNT)/polymer composites. Through a modified pullout test and fragmentation test, it was found that the critical aspect ratio was 300 and decreased by a factor of 3 due to surface modification, and that MWNTs at an angle of greater than 60° to the loading direction failed in bending instead of pulling out of the matrix. Finite element analysis was used to determine the critical bending shear strength and MWNT modulus. The obtained bending shear strength was used in a mechanics model developed to provide bounds for the ISS in the experimental composite system. The calculated ISS for as-received nanotube falls between 4.8 and 13.7 MPa, and for surface treated nanotube falls in the range of 11.1 and 38.3 MPa. These values are consistent with the ISS reported for carbon fiber/polymer composites and also show that the ISS almost triples due to chemical modification of the MWNT surface.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Fiber-reinforced polymer composites · Smart Materials for Construction

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References (34)

Show source-provided references
1. Fabrication and characterization of carbon nanotube/poly(vinyl alcohol) composites10.1002/(SICI)1521-4095(199908)11:11<937::AID-ADMA937>3.0.CO;2-9 ↗
2. Load transfer and deformation mechanisms in carbon nanotube–polystyrene composites10.1063/1.126500 ↗
3. Advanced shear-lag model applicable to discontinuous fiber composites10.1177/002199838101500107 ↗
4. Mechanical properties of thermoplastics strengthened by short discontinuous fibres10.1088/0022-3727/5/12/311 ↗
5. On the elastic properties of carbon nanotube-based composites: modelling and characterization10.1088/0022-3727/36/5/323 ↗
6. Carbon nanotube-reinforced composites as structural materials for microactuators in microelectromechanical systems10.1088/0957-4484/17/19/019 ↗
7. Rheological behaviour and mechanical characterization of injectable poly(propylene fumarate)/single-walled carbon nanotube composites for bone tissue engineering10.1088/0957-4484/16/7/030 ↗
8. Effects of nanotube waviness on the modulus of nanotube-reinforced polymers10.1063/1.1487900 ↗
9. Tensile properties of fibre-reinforced metals–Copper/tungsten and copper/molybdenum10.1016/0022-5096(65)90035-9 ↗
10. Gibson · 1994
11. Analysis of stress transfer from the matrix to the fiber through an imperfect interface: application to Raman data and the single-fiber fragmentation test
12. Bond strength measurement in composites – analysis of experimental techniques10.1016/0961-9526(92)90016-Y ↗
13. Micromechanics of single filament composites10.1016/0266-3538(91)90013-F ↗
14. A new method of evaluating the interfacial properties of composites by means of the gradual multi-fiber fragmentation test10.1016/S0266-3538(99)00141-4 ↗
15. Estimation of fibre and interfacial shear strength by using a single-fibre composite10.1016/0266-3538(95)00078-X ↗
16. Stiffness and strength of a polyamide thermoplastic reinforced with glass and carbon fibers10.1007/BF00647783 ↗
17. Mechanical and tribological properties of short discontinuous UHMWPE fiber reinforced UHMWPE10.1007/s002890050077 ↗
18. Stress-induced fragmentation of multiwall carbon nanotubes in a polymer matrix10.1063/1.120680 ↗
19. Fracture transitions at a carbon-nanotube/polymer interface10.1002/adma.200501033 ↗
20. Measurement of carbon nanotube–polymer interfacial strength10.1063/1.1579568 ↗
21. Large-scale synthesis of aligned carbon nanotubeslarge-scale synthesis of aligned carbon nanotubes10.1126/science.274.5293.1701 ↗
22. Passivation oxide controlled selective carbon nanotube growth on metal substrates10.1088/0957-4484/20/8/085302 ↗
23. Surface modification of multiwalled carbon nanotubes: toward the tailoring of the interface in polymer composites10.1021/cm020975d ↗
24. Chemical reactions occurring during the preparation of polycarbonate–epoxy blends10.1016/S0032-3861(96)01089-0 ↗
25. NMR and FT IR studies on transreactions and hydroxyl exchanges of bisphenol-A polycarbonate with an epoxy upon heating10.1016/S0032-3861(96)00751-3 ↗
26. Reinforcement mechanisms in MWCNT-filled polycarbonate10.1016/j.compscitech.2005.10.004 ↗
27. On the tensile strength distribution of multiwalled carbon nanotubes10.1063/1.2130713 ↗
28. Response to “comment on “on the tensile strength distribution of multiwalled carbon nanotubes” [Appl. Phys. Lett. 92, 206101 (2008)]”10.1063/1.2927305 ↗
29. Mechanical and morphological characterization of polymer–carbon nanocomposites from functionalized carbon nanotubes10.1016/j.carbon.2004.06.031 ↗
30. Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load10.1126/science.287.5453.637 ↗
31. Chen X, Brinson LC, in preparation.
32. A structural mechanics approach for the analysis of carbon nanotubes10.1016/S0020-7683(03)00056-8 ↗
33. The effective modulus of super carbon nanotubes predicted by molecular structure mechanics10.1088/0957-4484/19/22/225701 ↗
34. Gere · 1990