journal article·2015-12

Styrene-free unsaturated polyesters for hemp fibre composites

Wendi Liu, Tianshun Xie, Renhui Qiu

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Abstract

Abstract N-vinyl-2-pyrrolidone (NVP) and tri(ethylene glycol) divinyl ether (TDE) are utilized as reactive diluents to replace carcinogenic styrene (St) during the formulation of unsaturated polyester (UPE) resins. The processability and thermomechanical properties of the UPE resin-containing hemp fibre composites are evaluated. Both NVP-UPE and TDE-UPE resins exhibit better miscibility than the St-UPE resin. Rheological and curing measurements reveal that the St-free resins have much lower viscosity and curing temperatures than the St-UPE resin, indicating their superior processability. Furthermore, hemp fibre composites with NVP-UPE resin show comparable mechanical properties to the St-UPE composites. Composites of TDE-UPE have comparable tensile and impact strengths to the St-UPE composites. However, the flexural strength and modulus, storage modulus, and glass transition temperature of TDE-UPE composites are all lower than those of the St-UPE composites.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Natural Fiber Reinforced Composites · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Unsaturated polyester resins: chemistry and technology10.1007/b136243 ↗
2. U. S. Department of Health and Human Services, Public Health Services, National Toxicology Program 12th Report on Carcinogens 2011.
3. Effect of low-profile additives on thermo-mechanical properties of glass fiber-reinforced unsaturated polyester composites10.1177/0731684411412643 ↗
4. Studies on poly (styrene-co-butyl acrylate) latex-reinforced polyester nonwoven fabric thermoplastic composites10.1177/0731684405049881 ↗
5. Effect of reactive diluents on properties of unsaturated polyester/montmorillonite nanocomposites10.1002/app.13657 ↗
6. Fatty acid-based comonomers as styrene replacements in soybean and castor oil-based thermosetting polymers10.1002/app.32810 ↗
7. Fatty acid-based monomers as styrene replacements for liquid molding resins10.1016/j.polymer.2004.08.056 ↗
8. The use of acrylated fatty acid methyl esters as styrene replacements in triglyceride-based thermosetting polymers10.1002/pen.21486 ↗
9. Biobased vinyl levulinate as styrene replacement for unsaturated polyester resins10.1002/pola.27397 ↗
10. Synthesis and characterization of a novel bio-based reactive diluent as a styrene replacement10.1166/jbmb.2012.1193 ↗
11. Vanillin-based resin for use in composite applications10.1039/c2gc35672d ↗
12. Lignin esters for use in unsaturated thermosets: lignin modification and solubility modeling10.1021/bm0500345 ↗
13. Lignin model compounds as bio-based reactive diluents for liquid molding resins10.1002/cssc.201100687 ↗
14. Effect of water absorption on the mechanical properties of hemp fibre reinforced unsaturated polyester composites10.1016/j.compscitech.2006.06.019 ↗
15. Environmental effects on the mechanical behaviour of pultruded jute/glass fibre-reinforced polyester hybrid composites10.1016/j.compscitech.2014.01.017 ↗
16. Enhanced mechanical properties and water resistance of bamboo fiber-unsaturated polyester composites coupled by isocyanatoethyl methacrylate10.1007/s00226-014-0668-6 ↗
17. Study of water behaviour of chemically treated flax fibres-based composites: a way to approach the hydric interface10.1016/j.compscitech.2011.02.004 ↗
18. Mechanical properties of natural fibre reinforced polyester composites: jowar, sisal and bamboo10.1016/j.matdes.2011.03.015 ↗
19. N-methylol acrylamide grafting bamboo fibers and their composites10.1016/j.compscitech.2015.06.005 ↗
20. Improvement of interfacial adhesion in natural plant fiber-reinforced unsaturated polyester composites: a critical review10.7569/RAA.2015.097301 ↗
21. Fumaric acid monoethyl ester-functionalized poly (D, L-lactide)/N-vinyl-2-pyrrolidone resins for the preparation of tissue engineering scaffolds by stereolithography10.1021/bm801001r ↗
22. Synthesis and characterization of UV-curable vinyl ether functionalized urethane oligomers10.1016/S0300-9440(03)00148-6 ↗
23. Reactivity ratios of N-vinylpyrrolidone-acrylic acid copolymer
24. Van Krevelen · 2009
25. Isosorbide as the structural component of bio-based unsaturated polyesters for use as thermosetting resins10.1016/j.carbpol.2013.04.036 ↗
26. Odian · 2004
27. Brandrup · 1999
28. Rheology of chemically modified triglycerides10.1002/app.20846 ↗
29. Curing behavior of an unsaturated polyester system analyzed by Avrami equation10.1016/S0040-6031(98)00506-1 ↗
30. DSC and TSDC study of unsaturated polyester resin. Influence of the promoter content10.1023/A:1010172408643 ↗
31. Relative reactivities in vinyl copolymerization10.1002/pol.1947.120020112 ↗
32. Thermal properties and hydrogen bonding in polymer blend of polybenzoxazine/poly (N-vinyl-2-pyrrolidone)10.1016/S0032-3861(02)00928-X ↗
33. Use of tung oil as a reactive toughening agent in dicyclopentadiene-terminated unsaturated polyester resins10.1016/j.indcrop.2013.05.023 ↗
34. Polarity parameters and dynamic mechanical behaviour of chemically modified banana fiber reinforced polyester composites10.1016/S0266-3538(03)00092-7 ↗