journal article·2021-09

The addition of graphene nanoplatelets into epoxy/polycaprolactone composites for autonomous self-healing activation by Joule's heating effect

Xoan F. Sánchez-Romate, Alejandro Sans, Alberto Jiménez-Suárez, Silvia G. Prolongo

Publisher page

Abstract

Abstract Graphene nanoplatelet (GNP) doped epoxy/polycaprolactone (PCL) blends have been proposed in the present work. It has been observed that the addition of GNPs induces an enhancement on the electrical conductivity with a prevalent exponential behavior due to the hopping conduction. In this regard, the presence of small insulating domains of PCL leads to an increase of the electrical conductivity due to the reduction of agglomerates. Furthermore, the addition of GNPs allows the thermal heating by Joule's Effect, leading to an autonomous self-healing due to the melting of the PCL. In this context, several samples where subjected to Joule's activated healing, leading to healing efficiencies from 40 to 70% under the presence of an artificial crack. Therefore, the proposed novel materials open a way for autonomous self-healable systems.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Conducting polymers and applications · Advanced Sensor and Energy Harvesting Materials · Polymer composites and self-healing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Thermal and electrical properties of the epoxy nanocomposites reinforced with purified carbon nanotubes10.1016/j.matlet.2019.03.037 ↗
2. Highly thermally conductive dielectric nanocomposites with synergistic alignments of graphene and boron nitride nanosheets10.1002/adfm.201910826 ↗
3. Thermal properties enhancement of epoxy resins by incorporating polybenzimidazole nanofibers filled with graphene and carbon nanotubes as reinforcing material10.1016/j.polymertesting.2019.106317 ↗
4. Formation of percolating networks in multi-wall carbon-nanotube–epoxy composites10.1016/j.compscitech.2004.01.025 ↗
5. Polymer nanocomposites: insights on rheology, percolation and molecular mobility10.1016/j.polymer.2018.07.079 ↗
6. Structured reduced graphene oxide/polymer composites for ultra‐efficient electromagnetic interference shielding10.1002/adfm.201403809 ↗
7. Application of hybrid fillers for improving the through-plane heat transport in graphite nanoplatelet-based thermal interface layers10.1038/srep13108 ↗
8. Strong linear-piezoresistive-response of carbon nanostructures reinforced hyperelastic polymer nanocomposites10.1016/j.compositesa.2018.07.021 ↗
9. Piezoresistive thermoplastic polyurethane nanocomposites with carbon nanostructures10.1016/j.carbon.2018.06.037 ↗
10. Scalable and multifunctional carbon nanotube-based textile as distributed sensors for flow and cure monitoring10.1016/j.carbon.2020.02.079 ↗
11. Anti-icing and de-icing coatings based Joule's heating of graphene nanoplatelets10.1016/j.compscitech.2018.05.031 ↗
12. Printable self-heating coatings based on the use of carbon nanoreinforcements10.1002/pc.25367 ↗
13. Wireless monitoring of small strains in intelligent robots via a Joule heating effect in stretchable graphene–polymer nanocomposites10.1002/adfm.201910809 ↗
14. Novel timed and self-resistive heating shape memory polymer hybrid for large area and energy efficient application10.1016/j.carbon.2018.07.018 ↗
15. Interlaminar toughening of resin transfer molded laminates by electrospun polycaprolactone structures: effect of the interleave morphology10.1016/j.compscitech.2016.09.024 ↗
16. Epoxy toughening via formation of polyisoprene nanophases with amphiphilic diblock copolymer10.1016/j.eurpolymj.2017.11.032 ↗
17. Self-healing properties of epoxy resins with poly (ε-caprolactone) healing agent10.1007/s00289-016-1642-2 ↗
18. Self-healing epoxy coatings with enhanced properties and facile processability10.1016/j.polymer.2018.06.017 ↗
19. Self-healable graphene polymer composites10.1039/c0jm00307g ↗
20. Three-dimensional graphene structure for healable flexible electronics based on diels–alder chemistry10.1021/acsami.7b19649 ↗
21. Graphene based self-healing materials10.1016/j.carbon.2019.02.011 ↗
22. Multichannel and repeatable self‐healing of mechanical enhanced graphene‐thermoplastic polyurethane composites10.1002/adma.201204768 ↗
23. Highly multifunctional GNP/epoxy nanocomposites: from strain-sensing to Joule heating applications10.3390/nano10122431 ↗
24. Mechanical and strain sensing properties of carbon nanotube reinforced epoxy/poly (caprolactone) blends10.1016/j.polymer.2020.122236 ↗
25. Current-voltage characteristics of the composites based on epoxy resin and carbon nanotubes10.1155/2015/405345 ↗
26. Charge carrier transport and low electrical percolation threshold in multiwalled carbon nanotube polymer nanocomposites10.1016/j.carbon.2014.04.031 ↗
27. 3D nanocomposites of covalently interconnected multiwalled carbon nanotubes with SiC with enhanced thermal and electrical properties10.1002/adfm.201501696 ↗
28. Correlations between percolation threshold, dispersion state, and aspect ratio of carbon nanotubes10.1002/adfm.200700065 ↗
29. Observation of percolation‐like scaling–far from the percolation threshold–in high volume fraction, high conductivity polymer‐nanotube composite films10.1002/adma.200602912 ↗
30. Stretchable nanoparticle conductors with self-organized conductive pathways10.1038/nature12401 ↗
31. Effect of defects on thermal conductivity of graphene/epoxy nanocomposites10.1016/j.carbon.2017.12.110 ↗
32. Theory of thermal conductivity of graphene-polymer nanocomposites with interfacial Kapitza resistance and graphene-graphene contact resistance10.1016/j.carbon.2018.05.033 ↗
33. Stress controllability in thermal and electrical conductivity of 3D elastic graphene‐crosslinked carbon nanotube sponge/polyimide nanocomposite10.1002/adfm.201901383 ↗
34. Rudnik · 2013 · 217
35. The effects of temperature and alignment state of nanofillers on the thermal conductivity of both metal and nonmetal based graphene nanocomposites10.1016/j.actamat.2019.12.032 ↗