journal article·2016-04Open access

Thermosetting hierarchical composites with high carbon nanotube loadings: En route to high performance

Tomi M. Herceg, M. Shukur Zainol Abidin, Emile S. Greenhalgh, Milo S.P. Shaffer, Alexander Bismarck

Abstract

A wet powder impregnation route to manufacture carbon fibre reinforced thermoplastic composites was adapted to accommodate thermosetting matrices reinforced with high fractions (20 wt%/13.6 vol%) of multiwalled carbon nanotubes (CNTs). The produced carbon fibre prepregs were consolidated into laminates with fibre volume fractions of 50-58% and up to 6.1 vol% CNTs. Microscopic imaging confirmed successful consolidation at intermediate CNT loadings, but some voidage at the highest CNT loading due to the highly viscoelastic uncured matrix. Nonetheless, through-thickness electrical conductivity and Mode I interlaminar fracture toughness were enhanced by as much as 152% and 24% to unprecedented values of σ = 53 S m -1 and G IC = 840 J m -2, respectively. Fractographic characterisation indicated that crack deflection was the mechanism responsible for the improved fracture toughness. The material properties were shown to be strongly dependent on the microstructure of the matrix.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Smart Materials for Construction · Fiber-reinforced polymer composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (54)

Show source-provided references
1. Grant · 2001
2. Thermoplastic toughening of epoxy resins: a critical review10.1002/(SICI)1099-1581(199801)9:1<3::AID-PAT727>3.0.CO;2-I ↗
3. Review of z-pinned composite laminates10.1016/j.compositesa.2007.08.016 ↗
4. The potential of knitting for engineering composites – a review10.1016/S1359-835X(99)00067-6 ↗
5. The role of reinforcement architecture on impact damage mechanisms and post-impact compression behaviour10.1007/BF00353091 ↗
6. The assessment of novel materials and processes for the impact tolerant design of stiffened composite aerospace structures10.1016/S1359-835X(02)00188-4 ↗
7. An investigation of Mode I and Mode II fracture toughness enhancement using aligned carbon nanotubes forests at the crack interface10.1016/j.compstruct.2013.05.051 ↗
8. Analysis of interlaminar fracture toughness and damage mechanisms in composite laminates reinforced with sprayed multi-walled carbon nanotubes10.1016/j.matdes.2013.07.081 ↗
9. Evaluation of toughening concepts at structural features in CFRP – Part 1: stiffener pull-off10.1016/j.compositesa.2005.11.009 ↗
10. Carbon nanotube-based multifunctional polymer nanocomposites10.1080/15583724.2012.703747 ↗
11. A review and analysis of electrical percolation in carbon nanotube polymer composites10.1016/j.compscitech.2008.06.018 ↗
12. Thermal conductivity of carbon nanotubes and their polymer nanocomposites: a review10.1016/j.progpolymsci.2010.11.004 ↗
13. Carbon nanotube-based hierarchical composites: a review10.1039/c000041h ↗
14. Interfacial improvement of carbon fiber/epoxy composites using a simple process for depositing commercially functionalized carbon nanotubes on the fibers10.1016/j.carbon.2012.09.011 ↗
15. Mechanical characterization and impact damage assessment of a woven carbon fiber reinforced carbon nanotube-epoxy composite10.1016/j.compscitech.2012.12.005 ↗
16. Effect of the carbon nanotube functionalization on flexural properties of multiscale carbon fiber/epoxy composites manufactured by VARIM10.1016/j.compositesb.2012.09.063 ↗
17. Development of carbon nanofibre incorporated three phase carbon/epoxy composites with enhanced mechanical, electrical and thermal properties10.1016/j.compositesa.2010.12.018 ↗
18. Influence of carbon nanotube reinforcement on the processing and the mechanical behaviour of carbon fiber/epoxy composites10.1016/j.carbon.2009.06.039 ↗
19. Mechanical properties improvements in two-phase and three-phase composites using carbon nano-fiber dispersed resin10.1016/j.compositesa.2004.11.017 ↗
20. Multiscale carbon nanotube-carbon fiber reinforcement for advanced epoxy composites10.1021/la062743p ↗
21. Fracture toughness improvement of CFRP laminates by dispersion of cup-stacked carbon nanotubes10.1016/j.compscitech.2008.12.017 ↗
22. Fabrication and multifunctional properties of a hybrid laminate with aligned carbon nanotubes grown in situ10.1016/j.compscitech.2008.02.028 ↗
23. Joining prepreg composite interfaces with aligned carbon nanotubes10.1016/j.compositesa.2008.03.011 ↗
24. Multi-scale interlaminar fracture mechanisms in woven composite laminates reinforced with aligned carbon nanotubes10.1016/j.compscitech.2014.06.003 ↗
25. Mixed-mode fracture in an interleaved carbon-fibre epoxy composite10.1016/0266-3538(95)00062-3 ↗
26. Mechanical properties of CFRP laminates manufactured from unidirectional prepregs using CSCNT-dispersed epoxy10.1016/j.compositesa.2007.07.002 ↗
27. Multi-scale reinforcement of CFRPs using carbon nanofibers10.1016/j.compscitech.2010.10.006 ↗
28. Dispersion and packing of carbon nanotubes10.1016/S0008-6223(98)00130-4 ↗
29. Optical microstructure and viscosity enhancement for an epoxy resin matrix containing multiwall carbon nanotubes10.1122/1.2221699 ↗
30. Influence of nano-modification on the mechanical and electrical properties of conventional fibre-reinforced composites10.1016/j.compositesa.2005.02.007 ↗
31. Experimental investigation of dispersion during flow of multi-walled carbon nanotube/polymer suspension in fibrous porous media10.1016/j.carbon.2004.01.067 ↗
32. Manufacturing carbon nanofibers toughened polyester/glass fiber composites using vacuum assisted resin transfer molding for enhancing the mode-I delamination resistance10.1016/j.compositesa.2005.09.010 ↗
33. Basalt fiber-epoxy laminates with functionalized multi-walled carbon nanotubes10.1016/j.compositesa.2009.04.027 ↗
34. Matrix cracking behaviors in carbon fiber/epoxy laminates filled with cup-stacked carbon nanotubes (CSCNTs)10.1016/j.compositesa.2006.07.005 ↗
35. A review of strategies for improving the degradation properties of laminated continuous-fiber/epoxy composites with carbon-based nanoreinforcements10.1016/j.carbon.2012.01.059 ↗
36. A new material captures the market
37. Wet impregnation as route to unidirectional carbon fibre reinforced thermoplastic composites manufacturing10.1179/174328911X12988622801098 ↗
38. Thermosetting nanocomposites with high CNT loadings processed by a scalable powder based method10.1016/j.compscitech.2016.01.017 ↗
39. Diao · 2015
40. Electromagnetic interference shielding using continuous carbon-fiber carbon-matrix and polymer-matrix composites10.1016/S1359-8368(98)00065-1 ↗
41. Electrical conductivity improvement of aeronautical carbon fiber reinforced polyepoxy composites by insertion of carbon nanotubes10.1016/j.jnoncrysol.2012.05.038 ↗
42. Electrical anisotropy in multiscale nanotube/fiber hybrid composites10.1063/1.3202788 ↗
43. Self-sensing attained in carbon-fiber-polymer-matrix structural composites by using the interlaminar interface as a sensor10.1088/0964-1726/13/3/017 ↗
44. Increasing the through-thickness thermal conductivity of carbon fiber polymer-matrix composite by curing pressure increase and filler incorporation10.1016/j.compscitech.2011.09.011 ↗
45. Multifunctional composites using reinforced laminae with carbon-nanotube forests10.1038/nmat1650 ↗
46. Electrical and thermal property enhancement of fiber-reinforced polymer laminate composites through controlled implementation of multi-walled carbon nanotubes10.1016/j.compscitech.2012.09.006 ↗
47. Mechanical properties of carbon nanofiber/fiber-reinforced hierarchical polymer composites manufactured with multiscale-reinforcement fabrics10.1016/j.carbon.2010.10.057 ↗
48. The influence of porosity on the interlaminar shear strength of carbon/epoxy and carbon/bismaleimide fabric laminates10.1016/S0266-3538(01)00157-9 ↗
49. Hodgkinson · 2000
50. 2014
51. A micromechanical model for kink-band formation: Part II-analytical modelling10.1016/j.compscitech.2009.02.003 ↗
52. Greenhalgh · 2009
53. The toughness of epoxy polymers and fibre composites modified with rubber microparticles and silica nanoparticles10.1007/s10853-009-4064-9 ↗
54. Intermittent bonding for high toughness – high-strength composites10.1007/BF01163077 ↗