journal article·2017-04

Network structure and mechanical properties of polydimethylsiloxane filled with nanodiamond – Effect of degree of silanization of nanodiamond

Faezeh Hajiali, Akbar Shojaei

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Abstract

Abstract Reinforcement of polydimethylsiloxane (PDMS) was investigated using untreated nanodiamond (uND) and silane functionalized ND (sND) at various degrees of silanization. Scanning electron microscopy revealed an improved dispersion of ND in PDMS by silanization. The incorporation of uND and sNDs enhanced tensile strength up to 45% and 70%, respectively; however, greater improvement was observed for sNDs at very low concentrations, e.g. 0.2 wt%. The much improvement in crosslinking density, analyzed by Flory-Rehner model and Mooney-Rivlin plot, and interfacial interaction, characterized by Kraus and Cunneen-Russell plots, was also observed for sNDs. Interestingly, it was found that the extent of improvement in all the properties was closely related to the degree of silanization of sND. Dynamic mechanical properties of PDMS/ND composites were also investigated and discussed accordingly.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Diamond and Carbon-based Materials Research · Tribology and Wear Analysis · Force Microscopy Techniques and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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