journal article·2012-09

Nanoscale structure and local mechanical properties of fiber-reinforced composites containing MWCNT-grafted hybrid glass fibers

Charles D. Wood, Marc J. Palmeri, Karl W. Putz, Gregory Ho, Rick Barto, L. Catherine Brinson

Composites Science and Technology· Volume 72· Issue 14
Publisher page

Abstract

Abstract Carbon nanotubes (CNTs) were grown from the surface of glass fibers by chemical vapor deposition, and these hybrid fibers were individually dispersed in an epoxy matrix to investigate the local composite structure and properties near the fiber surface. High-resolution transmission electron microscopy revealed the influence of infiltration and curing of a liquid epoxy precursor on the morphology of the CNT “forest” region, or region of high CNT density near the fiber surface. Subsequent image analysis highlighted the importance of spatially dependent volume fractions of CNTs in the matrix as a function of distance from the fiber surface, and nanoindentation was used to probe local mechanical properties in the CNT forest region, showing strong correlations between local stiffness and volume fraction. This work represents the first in situ measurements of local mechanical properties of the nano-structured matrix region in hybrid fiber-reinforced composites, providing a means of quantifying the reinforcement provided by the grafted nanofillers.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Fiber-reinforced polymer composites · Mechanical Behavior of Composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Composite materials for aerospace applications10.1007/BF02749982 ↗
2. On short-beam shear tests for composite materials10.1007/BF02325100 ↗
3. Growth of carbon nanotubes on carbon fibre substrates to produce hybrid/phenolic composites with improved mechanical properties10.1016/j.compscitech.2008.02.020 ↗
4. Fabrication and multifunctional properties of a hybrid laminate with aligned carbon nanotubes grown In Situ10.1016/j.compscitech.2008.02.028 ↗
5. Mechanical properties of carbon nanofiber/fiber-reinforced hierarchical polymer composites manufactured with multiscale-reinforcement fabrics10.1016/j.carbon.2010.10.057 ↗
6. Multiscale carbon nanotube-carbon fiber reinforcement for advanced epoxy composites10.1021/la062743p ↗
7. Influence of nano-modification on the mechanical and electrical properties of conventional fibre-reinforced composites10.1016/j.compositesa.2005.02.007 ↗
8. Improvement in mechanical properties of carbon fabric-epoxy composite using carbon nanofibers10.1016/j.jmatprotec.2007.07.028 ↗
9. Fabrication and characterization of carbon/epoxy composites mixed with multi-walled carbon nanotubes10.1016/j.msea.2007.04.043 ↗
10. Mode I interlaminar fracture behavior and mechanical properties of CFRPs with nanoclay-filled epoxy matrix10.1016/j.compositesa.2006.03.001 ↗
11. Particle matrix interfacial bonding – effect on the fracture properties of rubber-modified epoxy polymers10.1021/ba-1993-0233.ch008 ↗
12. Deformation and fracture-behavior of a rubber-toughened epoxy. 1. Microstructure and fracture studies10.1016/0032-3861(83)90070-8 ↗
13. Reinforcement of carbon/epoxy composites with multi-wall carbon nanotubes and dispersion enhancing block copolymers10.1016/j.scriptamat.2007.11.011 ↗
14. Multi-scale reinforcement of CFRPs using carbon nanofibers10.1016/j.compscitech.2010.10.006 ↗
15. The toughness of epoxy polymers and fibre composites modified with rubber microparticles and silica nanoparticles10.1007/s10853-009-4064-9 ↗
16. The interlaminar toughness of carbon-fibre reinforced plastic composites using ‘hybrid-toughened’ matrices10.1007/s10853-006-0130-8 ↗
17. Fabrication and characterization of ultrahigh-volume- fraction aligned carbon nanotube–polymer composites10.1002/adma.200800295 ↗
18. Increasing the interfacial strength in carbon fiber/epoxy composites by controlling the orientation and length of carbon nanotubes grown on the fibers10.1016/j.carbon.2011.06.064 ↗
19. Synthesis and characterisation of carbon nanotubes grown on silica fibres by injection CVD10.1016/j.carbon.2009.09.029 ↗
20. Carbon microfibers sheathed with aligned carbon nanotubes: towards multidimensional, multicomponent, and multifunctional nanomaterials10.1002/smll.200600097 ↗
21. Size-selective growth of double-walled carbon nanotube forests from engineered iron catalysts10.1038/nnano.2006.95 ↗
22. Multifunctional composites using reinforced laminae with carbon-nanotube forests10.1038/nmat1650 ↗
23. Seah C-M, Chai S-P, Mohamed AR. Synthesis of aligned carbon nanotubes. Carbon 2011;49(14):4613–4635.10.1016/j.carbon.2011.06.090 ↗
24. Carbon fibers and composites with epoxy resins: topography, fractography and interphases10.1016/j.carbon.2003.12.085 ↗
25. Formation of a carbon fiber/polyhedral oligomeric silsesquioxane/carbon nanotube hybrid reinforcement and its effect on the interfacial properties of carbon fiber/epoxy composites10.1016/j.carbon.2011.02.026 ↗
26. Lv P, Feng Y-y, Zhang P, Chen H-m, Zhao N, Feng W. Increasing the interfacial strength in carbon fiber/epoxy composites by controlling the orientation and length of carbon nanotubes grown on the fibers. Carbon 2011;49(14):4665–4673.10.1016/j.carbon.2011.06.064 ↗
27. De Greef N, Gorbatikh L, Godara A, Mezzo L, Lomov SV, Verpoest I. The effect of carbon nanotubes on the damage development in carbon fiber/epoxy composites. Carbon 2011;49(14):4650–4664.10.1016/j.carbon.2011.06.047 ↗
28. Mechanical properties improvements in two-phase and three-phase composites using carbon nano-fiber dispersed resin10.1016/j.compositesa.2004.11.017 ↗
29. Multifunctional properties of high volume fraction aligned carbon nanotube polymer composites with controlled morphology10.1016/j.compscitech.2009.08.006 ↗
30. High-yield growth and morphology control of aligned carbon nanotubes on ceramic fibers for multifunctional enhancement of structural composites10.1016/j.carbon.2008.10.030 ↗
31. Reinforcement mechanisms in MWCNT-filled polycarbonate10.1016/j.compscitech.2005.10.004 ↗
32. The effect of inclusion waviness and waviness distribution on elastic properties of fiber-reinforced composites10.1016/j.compositesb.2010.09.004 ↗
33. Effects of nanotube waviness on the modulus of nanotube-reinforced polymers10.1063/1.1487900 ↗
34. Measurement of mechanical properties by ultra-low load indentation10.1016/S0921-5093(98)00724-2 ↗
35. Review of instrumented indentation10.6028/jres.108.024 ↗
36. Mechanical properties of multiwall carbon nanotubes/epoxy composites: influence of network morphology10.1016/j.carbon.2003.12.026 ↗
37. Mechanical and morphological characterization of polymer-carbon nanocomposites from functionalized carbon nanotubes10.1016/j.carbon.2004.06.031 ↗