Improving thermal, electrical and mechanical properties of fluoroelastomer/amino-functionalized multi-walled carbon nanotube composites by constructing dual crosslinking networks
Source abstract
Abstract
Abstract Carboxylic functionalized multi-walled carbon nanotubes (MWCNTs-COOH) were modified by using ethylenediamine (EDA) to prepare amino-functionalized multi-walled carbon nanotubes (MWCNTs-A). MWCNTs-A were characterized by Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). Fluoroelastomer (FKM) was reinforced by incorporation of MWCNTs-COOH and MWCNTs-A, respectively. The thermal, electrical and mechanical properties of the FKM/MWCNT composites were studied. The results indicated that a more homogeneous dispersion of nanotubes and a stronger interfacial interaction in FKM/MWCNTs-A composites were achieved than in FKM/MWCNTs-COOH ones. As a result, the thermal, electrical and mechanical properties of the FKM/MWCNTs-A composites were higher than that of the FKM/MWCNTs-COOH composites due to the participation of MWCNTs-A in the crosslinking process to form dual crosslinking networks in the FKM matrix.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Carbon Nanotubes in Composites · Polymer Nanocomposites and Properties · Fiber-reinforced polymer composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (56)
Show source-provided references
1. A review of DNA functionalized/grafted carbon nanotubes and their characterization10.1016/j.snb.2006.06.014 ↗
2. The present status and key problems of carbon nanotube based polymer composites10.3144/expresspolymlett.2007.39 ↗
3. Carbon nanotube-polymer composites: chemistry, processing, mechanical and electrical properties10.1016/j.progpolymsci.2009.09.003 ↗
4. Elastomeric composites based on carbon nanomaterials10.1088/0957-4484/26/11/112001 ↗
5. Attaching proteins to carbon nanotubes via diimide-activated amidation10.1021/nl010095i ↗
6. Chemical functionalization by a fluorinated trichlorosilane of multi-walled carbon nanotubes10.1088/0957-4484/15/7/011 ↗
7. DNA-functionalized single-walled carbon nanotubes10.1088/0957-4484/13/5/311 ↗
8. Endowing carbon nanotubes with biological and biomedical properties by chemical modifications10.1016/j.addr.2013.07.006 ↗
9. Evaluation of mild acid oxidation treatments for MWCNT functionalization10.1016/j.carbon.2009.06.044 ↗
10. Functionalized carbon nanotubes: properties and applications10.1021/ar010160v ↗
11. Functionalized multi-walled carbon nanotubes as affinity ligands10.1088/0957-4484/18/11/115614 ↗
12. Enzyme immobilisation on amino-functionalised multi-walled carbon nanotubes: structural and biocatalytic characterisation10.1371/journal.pone.0073642 ↗
13. Carbon nanotube/reduced graphene oxide hybrid for simultaneously enhancing the thermal conductivity and mechanical properties of styrene-butadiene rubber10.1016/j.carbon.2017.07.057 ↗
14. Supramolecular modification of multi-walled carbon nanotubes with β-cyclodextrin for better dispersibility10.1007/s11051-015-2866-z ↗
15. Highly efficient fluorescent multi-walled carbon nanotubes functionalized with diamines and amides10.1039/c2jm31192e ↗
16. Progress in the Raman spectra analysis of covalently functionalized multiwalled carbon nanotubes: unraveling disorder in graphitic materials10.1039/C5CP06519D ↗
17. Enhanced dispersion for electrical percolation behavior of multi-walled carbon nanotubes in polymer nanocomposites using simple powder mixing and in situ polymerization with surface treatment of the fillers10.1016/j.compscitech.2013.09.013 ↗
18. Mechanical properties of surface-functionalized SWCNT/epoxy composites10.1016/j.carbon.2007.11.051 ↗
19. B-staged epoxy/single-walled carbon nanotube nanocomposite thin films for composite reinforcement10.1002/app.29375 ↗
20. Raman microscopy of residual strains in carbon nanotube/epoxy composites10.1016/j.carbon.2010.01.018 ↗
21. Partially cured epoxy/SWCNT thin films for the reinforcement of vacuum-assisted resin-transfer-molded composites10.1016/j.carbon.2010.02.027 ↗
22. Nylon toughened epoxy/SWCNT composites10.1007/s10853-010-4921-6 ↗
23. Poly(propylene) nanocomposites containing various carbon nanostructures10.1002/macp.201100364 ↗
24. Lowly loaded carbon nanotubes induced high electrical conductivity and giant magnetoresistance in ethylene/1-octene copolymers10.1016/j.polymer.2016.09.056 ↗
25. Dispersion stability of functionalized MWCNT in the epoxy-amine system and its effects on mechanical and interfacial properties of carbon fiber composites10.1016/j.matdes.2016.01.062 ↗
26. Functionalized effect on carbon nanotube/epoxy nano-composites
27. Ethylenediamine functionalization effect on the thermos-mechanical properties of epoxy nanocomposites reinforced with multiwall carbon nanotubes
28. Synthesis and electrochemical probing of water-soluble poly(sodium 4-styrenesulfonate-co-acrylic acid)-grafted multiwalled carbon nanotubes10.1088/0957-4484/19/8/085716 ↗
29. Extreme-performance rubber nanocomposites for probing and excavating deep oil resources using multi-walled carbon nanotubes10.1002/adfm.200801136 ↗
30. Perfluoroelastomer and fluoroelastomer seals for semiconductor wafer processing equipment10.1016/S0022-1139(03)00102-7 ↗
31. Tube-like natural halloysite/fluoroelastomer nanocomposites with simultaneous enhanced mechanical, dynamic mechanical and thermal properties10.1016/j.eurpolymj.2011.06.007 ↗
32. Vulcanization behavior and mechanical properties of organoclay fluoroelastomer nanocomposites10.1002/app.35624 ↗
33. Thermal, mechanical and morphological properties of surface-modified montmorillonite-reinforced Viton rubber nanocomposites10.1002/pi.4518 ↗
34. Influence of clay on the vulcanization kinetics of fluoroelastomer nanocomposites10.1016/j.polymer.2004.01.052 ↗
35. A novel processing method namely fast evaporation mixing to prepare fluoroelastomer/montmorillonite composites10.1016/j.compscitech.2016.12.012 ↗
36. The m-SiCNW/FKM nanocomposites: fabrication, characterization and properties10.1039/C5RA27843K ↗
37. Allyl-functionalization enhanced thermally stable graphene/fluoroelastomer nanocomposites10.1016/j.polymer.2014.06.063 ↗
38. Graphene oxide-integrated high-temperature durable fluoroelastomer for petroleum oil sealing10.1016/j.compscitech.2013.12.010 ↗
39. Mechanical, thermal conductive, and dielectric properties of fluoroelastomer/reduced graphene oxide composites in situ prepared by solvent thermal reduction10.1002/pc.22831 ↗
40. Advanced properties of multiwalled carbon nanotube elastomer composites10.1179/17535557A15Y.000000015 ↗
41. Fluoroelastomer-MWNT nanocomposites-1: dispersion, morphology, physico-mechanical, and thermal properties10.1002/pc.20521 ↗
42. Improving the thermal properties of fluoroelastomer (Viton GF-600S) using acidic surface modified carbon nanotube10.1590/0104-1428.2044 ↗
43. Microstructural and thermal properties of fluoroelastomer/carbon nanotube composites10.1016/j.compositesb.2013.10.054 ↗
44. Microstructural and thermal properties of fluoroelastomer/acidic surface modified carbon nanotube nanocomposites10.1002/pc.23532 ↗
45. Multiwalled carbon nanotubes and fluoroelastomer antistatic nanocomposite for automotive fuel system components10.1007/s11814-015-0227-3 ↗
46. Strategy of tailoring the interface between multiwalled carbon nanotube and fluoroelastomer10.1002/pc.22938 ↗
47. Mechanism of amine crosslinking of fluoroelastomer. I. Solution Studies10.1002/pol.1960.1204514610 ↗
48. Heat aging in fluoroelastomers10.1002/app.1964.070080331 ↗
49. Network characterization of “Viton” ahv fluoroelastomer
50. New insight on the interfacial interaction between multiwalled carbon nanotubes and elastomers10.1016/j.compscitech.2017.02.012 ↗
51. Surface amination of carbon nanoparticles for modification of epoxy resins: plasma-treatment vs. wet-chemistry approach10.1016/j.eurpolymj.2016.10.004 ↗
52. Effect of functionalized carbon nanotubes on the thermal conductivity of epoxy composites10.1016/j.carbon.2009.08.047 ↗
53. Improving thermal conductivity while retaining high electrical resistivity of epoxy composites by incorporating silica-coated multi-walled carbon nanotubes10.1016/j.carbon.2010.09.047 ↗
54. Molecular dynamics simulation of interfacial thermal conductance between silicon and amorphous polyethylene10.1063/1.2824864 ↗
55. Modified and unmodified multiwalled carbon nanotubes in high performance solution-styrene-butadiene and butadiene rubber blends10.1016/j.polymer.2008.09.031 ↗
56. Large reduction in electrical contact resistance of flexible carbon nanotube/silicone rubber composites by trifluoroacetic acid treatment10.1016/j.compscitech.2017.03.004 ↗